Distribution and Enrichment of Heavy Metals in Recent Sediments of Safaga Bay,Egypt     

M. Abd El Wahab  S. Helal 《Marine Georesources & Geotechnology》2013,31(4):364-375

The present study was undertaken for assessing the level of heavy metals such as iron, manganese, zinc, copper, nickel, cadmium, lead, and cobalt in recent sediment samples of Safaga Bay, Egypt. Concentration of heavy metals in sediments shows significant variability and ranges from 863.37 to 1144.93 ppm for Fe, 64.29–586.8 ppm for Mn, 2.7–12.68 ppm for Zn, 3.01–7.2 ppm for Pb, 1.53–3.29 ppm for Ni, 0.55–1.57 ppm for Co, 0.16–1.37 ppm for Cu, and 0.22–0.4 ppm for Cd.

Sediment pollution assessments were carried out using an enrichment factor and geoaccumulation index. The calculation of enrichment factor showed that Cd is enriched by 4.1 due to phosphate sources in Safaga Bay. The Geoaccumulation index results revealed that there are positive and negative correlations between Fe, Zn, Mn, Pb, Ni, Cu, Co, and Cd indicating that these metals have complicated geochemical behaviors.  相似文献   

Review of geotechnique and natural hazards     

Mohammed I. El‐sabh  Tad S. Murty 《Marine Geodesy》2013,36(4):339-343

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Uranium-rich opal from the Nopal I uranium deposit, Peña Blanca, Mexico: Evidence for the uptake and retardation of radionuclides     

Michael Schindler  Mostafa Fayek  Frank C. Hawthorne 《Geochimica et cosmochimica acta》2010,74(1):187-202

The Nopal I uranium deposit of the Sierra Peña Blanca, Mexico, has been the focus of numerous studies because of its economic importance and its use as a natural analog for nuclear-waste disposal in volcanic tuff. Secondary uranyl minerals such as uranophane, Ca[(UO₂)(SiO₃OH)]₂(H₂O)₅, and weeksite, (K,Na)₂[(UO₂)₂(Si₅O₁₃)](H₂O)₃, occur in the vadose zone of the deposit and are overgrown by silica glaze. These glazes consist mainly of opal A, which contains small particles of uraninite, UO₂, and weeksite. Close to a fault between brecciated volcanic rocks and welded tuff, a greenish silica glaze coats the altered breccia. Yellow silica glazes from the center of the breccia pipe and from the high-grade pile coat uranyl-silicates, predominantly uranophane and weeksite. All silica glazes are strongly zoned with respect to U and Ca, and the distribution of these elements indicates curved features and spherical particles inside the coatings. The concentrations of U and Ca correlate in the different zones and both elements inversely correlate with the concentration of Si. Zones within the silica glazes contain U and Ca in a 1:1 ratio with maximum concentrations of 0.08 and 0.15 at.% for the greenish and yellow glazes, respectively, suggesting trapping of either Ca₁U₁-aqueous species or -particles in the colloidal silica. X-ray photoelectron spectroscopy (XPS), Fourier-transform infra-red spectroscopy (FTIR), and oxygen-isotope ratios measured by secondary-ion mass spectrometry (SIMS) indicate higher U⁶⁺/U⁴⁺ ratios, higher proportions of Si-OH groups and lower δ¹⁸O values for the greenish silica glaze than for the yellow silica glaze. These differences in composition reflect increasing brecciation, porosity, and permeability from the center of the breccia pipe (yellow silica glaze) toward the fault (green silica glaze), where the seepage of meteoric water and Eh are higher.  相似文献   

Hydrothermal alteration of plagioclase in granitic rocks from Proterozoic basement of SE Sweden     

S. Morad  M. A. K. El‐Ghali  M. A. Caja  M. Sirat  K. Al‐Ramadan  H. Mansurbeg 《Geological Journal》2010,45(1):105-116

Petrographic examinations and electron microprobe analyses of Proterozoic granitic rocks, SE Sweden aimed to characterize and unravel the mechanisms and conditions of plagioclase alterations. These alterations include saussuritization, albitization and replacement of plagioclase by K‐feldspar. The hydrothermal alterations, which are inferred to have occurred at ca. 250–400°C, resulted in concomitant formation of Al‐rich titanite, epidote, calcite, pumpellyite, prehnite and iron oxides. Replacement of plagioclase by K‐feldspar occurs in red‐stained zones, which have developed close to thin fractures owing to the precipitation of tiny Fe‐oxide pigment particles within the altered plagioclase, whereas saussuritized plagioclase has less systematic spatial relationships to these fractures. Albitization of plagioclase occurred in rocks that are poor in biotite compared to rocks that suffered extensive saussuritization. The chemical and textural characterization of various types of plagioclase alterations allows elucidation of the granitic hydrothermal systems. Features of feldspar alteration in the granitic rocks are similar to those encountered in feldspathic sandstones and should hence be considered in studies on diagenetic changes of siliciclastic successions during basin evolution. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Analytical solution for distributed torsional low strain integrity test for pipe pile     

Yunpeng Zhang  Guosheng Jiang  Wenbing Wu  M. Hesham El Naggar  Hao Liu  Minjie Wen  Kuihua Wang 《国际地质力学数值与分析法杂志》2022,46(1):47-67

Low strain integrity tests (LSITs) are the most popular non-destructive methods for pile testing. However, traditional LSITs have encountered unprecedented challenges as the need for long pile and existing pile testing keeps multiplying. Compared to traditional longitudinal excitations, the torsional wave is less influenced by the velocity attenuation effect and can be subjected at the pile shaft for existing piles. Distributed torsional LSIT is proposed in this article with the presentation of the corresponding analytical solutions that exhibiting the velocity responses along the pile shaft. The solution is verified with previous simplified theoretical and rigorous finite element method (FEM) answers. At the end, the application of this method is exhibited through the identification of necking and concrete segregation defects on pipe piles, which shows the advantage of this method on long pile testing.  相似文献