Assessment of the acid drainage neutralization capacity and the toxic metals lixiviation of tailing from Guanajuato mining district,Mexico   总被引：1，自引：0，他引：1  

María Elena García-Arreola  Luisa María Flores-Vélez  Marcos Loredo-Tovías  Alfredo Aguillón-Robles  Rubén Alfonso López-Doncel  Irene Cano-Rodríguez  Sonia Hortensia Soriano-Pérez 《Environmental Earth Sciences》2018,77(9):355

In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.  相似文献   

Magma evolution beneath Bequia,Lesser Antilles,deduced from petrology of lavas and plutonic xenoliths   总被引：1，自引：0，他引：1  

Michal?Camejo-HarryEmail authorView author&#;s OrcID profile  Elena?Melekhova  Jon?Blundy  William?Attridge  Richard?Robertson  Thomas?Christopher 《Contributions to Mineralogy and Petrology》2018,173(10):77

Extrusive and intrusive igneous rocks represent different parts of a magmatic system and ultimately provide complementary information about the processes operating beneath volcanoes. To shed light on such processes, we have examined and quantified the textures and mineral compositions of plutonic and cumulate xenoliths and lavas from Bequia, Lesser Antilles arc. Both suites contain assemblages of iddingsitized olivine, plagioclase, clinopyroxene and spinel with rare orthopyroxene and ilmenite. Mineral zoning is widespread, but more protracted in lavas than xenoliths. Plagioclase cores and olivine have high anorthite (An?≤?98) and low forsterite (Fo?≤?84) compositions respectively, implying crystallisation from a hydrous mafic melt that was already fractionated. Xenolith textures range from adcumulate to orthocumulate with variable mineral crystallisation sequences. Textural criteria are used to organize the xenoliths into six groups. Amphibole, notably absent from lavas, is a common feature of xenoliths, together with minor biotite and apatite. Bulk compositions of xenoliths deviate from the liquid line of descent of lavas supporting a cumulate origin with varying degrees of reactive infiltration by evolved hydrous melts, preserved as melt inclusions in xenolith crystals. Volatile saturation pressures in melt inclusions indicate cumulate crystallization over a 162–571 MPa pressure range under conditions of high dissolved water contents (up to 7.8 wt% H₂O), consistent with a variety of other thermobarometric estimates. Phase assemblages of xenoliths are consistent with published experimental data on volatile-saturated low-magnesium and high-alumina basalts and basaltic andesite from the Lesser Antilles at pressures of 200–1000 MPa, temperatures of 950–1050 °C and dissolved H₂O contents of 4–7 wt%. Once extracted from mid-crustal mushes, residual melts ascend to higher levels and undergo H₂O-saturated crystallization in shallow, pre-eruptive reservoirs to form phenocrysts and glomerocrysts. The absence of amphibole from lavas reflects instability at low pressures, whereas its abundance in xenoliths testifies to its importance in mid-crustal differentiation processes. A complex, vertically extensive (6 to at least 21 km depth) magmatic system is inferred beneath Bequia. Xenoliths represent fragments of the mush incorporated into ascending magmas. The widespread occurrence of evolved melts in the mush, but the absence of erupted evolved magmas, in contrast to islands in the northern Lesser Antilles, may reflect the relative immaturity of the Bequia magmatic system.  相似文献   

Trace‐element signatures of apatites in granitoids from the Mt Isa Inlier,northwestern Queensland     

E. A. Belousova  S. Walters  W. L. Griffin  S. Y. O'Reilly 《Australian Journal of Earth Sciences》2013,60(4):603-619

The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser‐ablation inductively coupled plasma‐mass spectrometry (ICP‐MS) microprobe. The results indicate that the distribution of trace elements (especially rare‐earth elements (REE), Sr, Y, Mn and Th) in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace‐element concentrations of apatite are correlated with parameters such as the SiO₂ content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn²⁺substitutes directly for Ca²⁺. The La/Ce ratio of apatite is well‐correlated with the whole‐rock K²O and Na²O contents, as well as with the oxidation state and ASI. Because apatite trace‐element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints.  相似文献   

Reconstructions of spring/summer precipitation for the Eastern Mediterranean from tree-ring widths and its connection to large-scale atmospheric circulation     

Ramzi Touchan  Elena Xoplaki  Gary Funkhouser  Jürg Luterbacher  Malcolm K. Hughes  Nesat Erkan  Ünal Akkemik  Jean Stephan 《Climate Dynamics》2005,25(1):75-98

This study represents the first large-scale systematic dendroclimatic sampling focused on developing chronologies from different species in the eastern Mediterranean region. Six reconstructions were developed from chronologies ranging in length from 115 years to 600 years. The first reconstruction (1885–2000) was derived from principal components (PCs) of 36 combined chronologies. The remaining five, 1800–2000, 1700–2000, 1600–2000, 1500–2000 and 1400–2000 were developed from PCs of 32, 18, 14, 9, and 7 chronologies, respectively. Calibration and verification statistics for the period 1931–2000 show good levels of skill for all reconstructions. The longest period of consecutive dry years, defined as those with less than 90% of the mean of the observed May–August precipitation, was 5 years (1591–1595) and occurred only once during the last 600 years. The longest reconstructed wet period was 5 years (1601–1605 and 1751–1755). No long term trends were found in May–August precipitation during the last few centuries. Regression maps are used to identify the influence of large-scale atmospheric circulation on regional precipitation. In general, tree-ring indices are influenced by May–August precipitation, which is driven by anomalous below (above) normal pressure at all atmospheric levels and by convection (subsidence) and small pressure gradients at sea level. These atmospheric conditions also control the anomaly surface air temperature distribution which indicates below (above) normal values in the southern regions and warmer (cooler) conditions north of around 40°N. A compositing technique is used to extract information on large-scale climate signals from extreme wet and dry summers for the second half of the twentieth century and an independent reconstruction over the last 237 years. Similar main modes of atmospheric patterns and surface air temperature distribution related to extreme dry and wet summers were identified both for the most recent 50 years and the last 237 years. Except for the last few decades, running correlation analyses between the major European-scale circulation patterns and eastern Mediteranean spring/summer precipitation over the last 237 years are non-stationary and insignificant, suggesting that local and/or sub-regional geographic factors and processes are important influences on tree-ring variability over the last few centuries.  相似文献   

Response of littoral chironomid communities and organic matter to late glacial lake—level,vegetation and climate changes at Lago dell’Accesa (Tuscany,Italy)     

Laurent Millet  Boris Vannière  Valérie Verneaux  Michel Magny  Jean Robert Disnar  Fatima Laggoun-Défarge  Anne Véronique Walter-Simonnet  Gilles Bossuet  Elena Ortu  Jacques-Louis de Beaulieu 《Journal of Paleolimnology》2007,38(4):525-539

This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological, environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages, organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany, Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development. Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group level, may be necessary to increase the sensibility of the indicators to lake-level changes.  相似文献   

Response of alpine chironomid communities (Lake Chuna, Kola Peninsula, northwestern Russia) to atmospheric contamination   总被引：1，自引：0，他引：1  

Boris Ilyashuk  Elena Ilyashuk 《Journal of Paleolimnology》2001,25(4):467-475

A short sediment core from the deepest part of an alpine lake (Lake Chuna, Kola Peninsula, northwestern Russia), covering about the past 200 yrs of sediment accumulation, was analysed for chironomid head capsule remains. The lake has been receiving acidic precipitation and heavy metals loading from the atmosphere since the 1940's. A total of 22 chironomid taxa were recorded. The most important taxa were typical elements of oligotrophic lakes, i.e.Micropsectra insignilobus, Paratanytarsus penicillatus, Stictochironomus spp. and Heterotrissocladius marcidus. Based on the cluster analyses results for the reconstructed environmental variables and chironomid communities, three developmental stages were distinguished from the lake history: (1) Natural ontogeny stage (before ~1945); (2) Initial stage of anthropogenic ontogeny (~1945-~1982); and (3) Anthropogenic ontogeny stage (~1982-~1996). During the first period, the changes in the chironomid fauna were characterized as an anthropogenically undisturbed community, with M. insignilobus dominating (46-66%). The changes during the second period reflected the initial phase of anthropogenic succession associated with the beginning of acidification and heavy metal pollution. The main species showed opposite distributional patterns in this period; the abundance of the group M. insignilobus/Stictochironomus spp. decreased, whereas the abundance of P. penicillatus/H. marcidus increased. The third period was characterized by a major shift in the faunal assemblages, from M. insignilobus to other dominant species including P. penicillatus (19-30%). The increases of Orthocladiinae relative abundance and total organic content in the uppermost sediment layers may be explained by a decrease in lake productivity. The decreases of cold-stenothermal taxa Stictochironomus spp. and M. insignilobus in the uppermost sediment layers can be explained by the global warming during the 20th century. The lake ecosystem is likely to be affected by both inputs of airborne contaminants and climate changes.  相似文献   

Quantifying the response of phytoplankton photosynthesis to ultraviolet radiation: Biological weighting functions versus in situ measurements in two Swiss lakes     

Patrick J. Neale  Elena Litchman  Cristina Sobrino  Cristiana Callieri  Giuseppe Morabito  Vivian Montecino  Yannick Huot  Peter Bossard  Christine Lehmann  Daniel Steiner 《Aquatic Sciences - Research Across Boundaries》2001,63(3):265-285

  相似文献   

Human-induced Changes in the Groundwater Chemical Composition within an Oil Field Area     

Belousova  A. P. 《Water Resources》2001,28(1):84-93

The effect of highly saline oil-field water on soils and potable groundwater is considered. Three phases of the hydrochemical evolution of groundwater quality affected by transborder pollution and field development that has deteriorated potable groundwater in the two topmost aquifers are identified.  相似文献   

Paleolithic archeology and the paleogeographical study of loess-paleosol sequences in Eastern Europe     

Elena I. Kurenkova  Yuri N. Gribchenko  Ludmila V. Grekhova 《GeoJournal》1995,36(2-3):229-235

The paper is concerned with problems of the study of Paleolithic sites in the loess regions of the Russian Plain. It is of great significance to correlate prehistorical settlement with Upper Pleistocene cycles of loess and soil formation — not solely in the reconstruction of paleoenvironments. From the cultural layers at various sites paleontological finds and objects were collected for radiocarbon dating. A complex analysis of archeological objects embedded in the loess-paleosol sequence helps us date Upper Pleistocene loess formation cycles. The data acquired from the investigation of the lithological properties of loess and their modification through time and their dependence on relief characteristics permitted a correlation between the various paleoenvironments and the dust accumulation cycles, which played a decisive role in the selection of the most habitable sites.  相似文献   

On very-low-frequency atmospherics at Roburent,Northern Italy     

M. Bossolasco  A. Caneva  I. Dagnino  A. Elena  G. Flocchini 《Pure and Applied Geophysics》1972,100(1):174-184

Summary The diurnal and seasonal variation of the VLF sferics pulse rate recorded at Roburent, Northern Italy, on 27 kHz since 1966 is derived. By analyzing the sunrise effect, the minimum distance of the thunderstorm centers providing at that time an unperturbed behaviour of the sferics pulse rate is obtained: this distance varies in azimuth and with the seasons and lies between 600 and 1300 km. In the time of the equinoxes, however, it is more stable between 700 and 900 km. The role of the groundwave propagation, generated by thunderstorm center within a radius of less than 500 km, is emphasized.

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Zusammenfassung Der Tagesgang und der Jahresgang der Sferics-Impulshäufigkeit werden abgeleitet. Diese Sferics-Häufigkeit ist seit 1966 auf 27 kHz in Roburent, in Nord-Italien, registriert worden. Der Mindestabstand der Gewitterherde, welche zur Zeit des Sonnenaufgangs ein ungestörte Bild der Impulshäufigkeit geben, wird mit Hilfe des Sonnenaufgangseffekts abgeleitet: der Abstand liegt — abhängig von der Jahreszeit und der Einfallsrichtung — zwischen 600 und 1300 km; jedoch bewegt er sich in dem engeren Rahmen zwischen 700 und 900 km zur Zeit der Tag-und Nachtgleichen. Betont wird die Rolle der Bodenwelle, welche von Gewitterherden in einem Abstand von weniger als 500 km erzeugt wird.

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Contribution No. 241 of the Istituto Geofisico e Geodetico, Università di Genova,Genoa, Italy. This work has been supported by a grant from the Consiglio Nazionale delle Ricerche (Comitato Nazionale per le Scienze Fisiche), Roma.  相似文献