Subsurface countercurrent in the Bosporus already known to 6th century A. D. Byzantine fishermen     

Prof. Dr. Manfred Korfmann  Prof. Dr. Jehuda Neumann 《Ocean Dynamics》1985,38(4):189-190

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A comparison of bowen ratio and eddy correlation sensible and latent heat flux measurements above deciduous forest     

Alan G. Barr  K. M. King  T. J. Gillespie  G. Den Hartog  H. H. Neumann 《Boundary-Layer Meteorology》1994,71(1-2):21-41

Sensible and latent heat flux densities (H and E) were measured above a mature, 18 m deciduous forest during July and August, 1988, using the Bowen ratio-energy balance (BREB) and eddy correlation (EC) methods. EC estimates ofH and E underestimated day-time surface available energy by 11%. EC also partitioned available energy differently than BREB. for/L<0.0, EC favouredH and BREB favoured E. Practical and theoretical limitations of the BREB and EC methods above forests are discussed. The most plausible causes for the failure of EC to close the surface energy balance are a low frequency loss of flux and the failure of a single point measurement to account for the spatial dispersive flux. The most plausible causes of the EC-BREB energy partitioning anomaly are the invalidity of the BREB similarity assumption and the violation of flux-gradient diffusion assumptions in the near-field diffusion region.  相似文献   

Early diagenetic processes during Mn-carbonate formation: evidence from the isotopic composition of authigenic Ca-rhodochrosites of the Baltic Sea   总被引：1，自引：0，他引：1  

Thomas Neumann  Uwe HeiserMarkus A Leosson  Michael Kersten 《Geochimica et cosmochimica acta》2002,66(5):867-879

The formation of authigenic Ca-rich rhodochrosite (ACR) in sapropelic sediments of the Gotland Basin, Baltic Sea, is governed by deepwater renewal processes whereby saline water from the North Atlantic flushes the brackish anoxic Baltic Deeps. The carbon and oxygen isotopic compositions of these Mn-carbonates suggest that ACR formation takes place just below the sediment surface and that dissolved compounds from the deepwater column, such as water and bicarbonate molecules, were incorporated in ACR during authigenesis. Porewaters near the sediment surface display δ¹⁸O values of −5.4‰ (VSMOW) and are generally depleted in ¹⁸O, compared to the oxygen isotopic composition of water in equilibrium with Mn-carbonate solid solutions (ACR δ¹⁸O values are −4.6‰). This suggests that early burial diagenetic processes significantly modify the initial isotopic composition of water during Mn-carbonate formation. The reduction of sulfate having δ¹⁸O values of +8.4‰ accounts for a permanent enrichment of porewater ¹⁸O and observed δ¹⁸O values at depth equal to −4.6‰. However, this process does not explain the observed disequilibrium in the oxygen isotopic composition between water and ACR close to the sediment surface where Mn-carbonate formation takes place. Based on isotopic mass balance calculations, we suggest that MnO₂ with δ¹⁸O values of +8.9‰ released oxygen enriched in ¹⁸O into the anoxic porewaters close below the sediment surface. This process should occur after oxygenation events during deepwater renewal when MnO₂ accumulates at the surface of anoxic sediments. Manganese carbonates formed in these waters display δ¹⁸O values of ∼1.0‰ heavier than values expected solely from the initial deepwater composition. This quantitatively explains the discrepancy between paleosalinities calculated from ACR δ¹⁸O based on Mn-carbonate/water isotopic equilibrium fractionation and direct observations for the same period. Our results emphasize the important role of microbial MnO₂ reduction during rhodochrosite authigenesis and suggest that Mn(II) activity, rather than alkalinity, is the limiting component for sedimentary Mn-carbonate formation.  相似文献   

Observations of urban and suburban environments with global satellite scatterometer data   总被引：1，自引：0，他引：1  

S.V. Nghiem  D. Balk  E. Rodriguez  G. Neumann  A. Sorichetta  C. Small  C.D. Elvidge 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(4):367-380

A global and consistent characterization of land use and land change in urban and suburban environments is crucial for many fundamental social and natural science studies and applications. Presented here is a dense sampling method (DSM) that uses satellite scatterometer data to delineate urban and intraurban areas at a posting scale of about 1 km. DSM results are analyzed together with information on population and housing censuses, with Landsat Enhanced Thematic Mapper Plus (ETM+) imagery, and with Defense Meteorological Satellite Program (DMSP) night-light data. The analyses include Dallas-Fort Worth and Phoenix in the United States, Bogotá in Colombia, Dhaka in Bangladesh, Guangzhou in China, and Quito in Ecuador. Results show that scatterometer signatures correspond to buildings and infrastructures in urban and suburban environments. City extents detected by scatterometer data are significantly smaller than city light extents, but not all urban areas are detectable by the current SeaWinds scatterometer on the QuikSCAT satellite. Core commercial and industrial areas with high buildings and large factories are identified as high-backscatter centers. Data from DSM backscatter and DMSP nighttime lights have a good correlation with population density. However, the correlation relations from the two satellite datasets are different for different cities indicating that they contain complementary information. Together with night-light and census data, DSM and satellite scatterometer data provide new observations to study global urban and suburban environments and their changes. Furthermore, the capability of DSM to identify hydrological channels on the Greenland ice sheet and ecological biomes in central Africa demonstrates that DSM can be used to observe persistent structures in natural environments at a km scale, providing contemporaneous data to study human impacts beyond urban and suburban areas.  相似文献   

Comparative assessment of CORINE2000 and GLC2000: Spatial analysis of land cover data for Europe   总被引：3，自引：0，他引：3  

K. Neumann  M. Herold  A. Hartley  C. Schmullius   《International Journal of Applied Earth Observation and Geoinformation》2007,9(4):425-437

Given the current lack of interoperability between global and regional land cover products, efforts are underway to link the new European global land cover map (GLOBCOVER) with the existing global land cover 2000 map (GLC2000) and European CORINE mapping initiative. Since both datasets apply different mapping standards, key for a successful implementation is a thorough understanding of the heterogeneities among both datasets. Thus, this paper provides an assessment of compatibilities and differences between the CORINE2000 and GLC2000 datasets. The comparative assessment considers inconsistencies between the thematic legends (using the UN land cover classification system-LCCS), class specific accuracies, and the spatial resolution and heterogeneity of the datasets. The results are summarized with implications for the development of the new GLOBCOVER datasets.  相似文献   

N-MORB crust beneath Fuerteventura in the easternmost part of the Canary Islands: evidence from gabbroic xenoliths     

Else-Ragnhild?NeumannEmail author  Riccardo?Vannucci  Massimo?Tiepolo 《Contributions to Mineralogy and Petrology》2005,150(2):156-173

Gabbro xenoliths reported in this paper were collected in northern Fuerteventura, the Canary Island located closest to the coast of Africa. The xenoliths are very fresh and consist of Ti–Al-poor clinopyroxene + plagioclase (An_87–67) + olivine (Fo_72–86) ± orthopyroxene. Clinopyroxene and orthopyroxene are constantly and markedly depleted in light rare earth elements (LREE) relative to heavy REE (HREE), as expected for cumulus minerals formed from highly refractory N-MORB-type melts. In contrast, whole-rock Primordial Mantle-normalized trace element patterns range from mildly S-shaped (mildly depleted in Pr–Sm relative to both the strongly incompatible elements Rb–La and the HREE) to enriched. Estimates show that the trace element compositions of the rocks and their minerals are compatible with formation as N-MORB gabbro cumulates, which have been infiltrated at various extents (≤1% to >5%) by enriched alkali basaltic melts. The enriched material is mainly concentrated along grain boundaries and cracks through mineral grains, suggesting that the infiltration is relatively recent, and is thus associated with the Canary Islands magmatism. Our data contradict the hypothesis that a mantle plume was present in this area during the opening of the Atlantic Ocean. No evidence of continental material that might reflect attenuated continental crust in the area has been found. Gabbro xenoliths with REE and trace element compositions similar to those exhibited by the Fuerteventura gabbros are also found among gabbro xenoliths from the islands of La Palma (western Canary Islands) and Lanzarote. The compositions of the most depleted samples from these islands are closely similar, implying that there was no significant change in chemistry during the early stages of formation of the Atlantic oceanic crust in this area. Strongly depleted gabbros similar to those collected in Fuerteventura have also been retrieved in the MARK area along the central Mid-Atlantic Ridge. The presence of N-MORB oceanic crust beneath Fuerteventura implies that the continent–ocean transition in the Canary Islands area must be relatively sharp, in contrast to the situation both further north along the coast of Morocco, and along the Iberian peninsula.  相似文献   

Application of Gibbs Energy Minimization to ModelEarly-Diagenetic Solid-Solution Aqueous-Solution EquilibriaInvolving Authigenic Rhodochrosites in Anoxic BalticSea Sediments     

Dmitrii A. Kulik  Michael Kersten  Uwe Heiser  Thomas Neumann 《Aquatic Geochemistry》2000,6(2):147-199

The natural early-diagenetic environment ``anoxicporewater – authigenic mineral phases' has beencharacterized in sediment of the Gotland Deep,Baltic Sea, by a closed-system model. Occurrence ofcarbonate precipitates as thin almost pure whitelaminae was considered as a natural experiment forlong-term equilibration between these phases andporewater. Plots of distribution coefficientsindicate that metastable equilibrium exists betweenporewater and the authigenic Ca-rich rhodochrositephases below 7 cm depth. A thermodynamic model ofporewater geochemistry at in situ P = 25 barand T = 5 °C was developed using the Gibbsenergy minimization (GEM) approach. The values of isobaric-isothermal potentials of Mn, Ca, Fe, Mg,Sr, Ba, C, and O, calculated from the porewatercomposition, were used in a new ``dual thermodynamic'calculation approach to estimate solid activitycoefficients of the end-members in the non-idealsolid solution (Mn, Ca, Mg, Sr, Ba, Fe)CO₃,i.e., at full major and minor multi-componentcomplexity. The regular Margules interactionparameters for the composing binaries estimated bythis model were _Mn-Ca = 1.9 ± 0.5,_Mn-Mg = 0.6,_Ca-Mg = 3.7,_Mn-Fe = 0.2,_Ca-Fe = 2.8,_Mn-Sr = 9.7,_Ca-Sr = 2.15,_Mn-Ba = 4.0,_Ca-Ba = 1.4,validating the theoretical predictions given byLippmann in his pioneering 1980's paper. Thestrictly thermodynamic equilibrium model is not onlyable to match both the measured porewater andcarbonate solid-solution composition, but also topredict that the porewater pH, pe, alkalinity, anddissolved Mn, Fe, and S concentrations arecontrolled by the authigenic mineral bufferingassemblage mackinawite-greigite-rhodochrosite. Ourmodel is only compatible with the idea of ACRformation with typical composition (X_Mnbetween 70–75%) in the topmost sediment layerwhich, however, needs a major source ofMn_aq ^II. This is provided by reduction ofparticulate Mn oxides precipitated in significantamounts in the water column upon major inflow eventsin the Baltic Sea. The model enables also to set upscenarios of changing environmental conditions, e.g.,to predict the non-linear response of the carbonatesolid-solution composition to changes in Mn loading,alkalinity and salinity of the sediment-watersystem. The results suggest that the major andespecially minor element contents (Sr, Mg, Ba) inauthigenic carbonates can be applied as anenvironmental paleoproxy.  相似文献   

Evaluation of redox-active iron sites in smectites using middle and near infrared spectroscopy   总被引：1，自引：0，他引：1  

Anke Neumann  Thomas B. Hofstetter 《Geochimica et cosmochimica acta》2011,75(9):2336-2355

Redox processes of structural Fe in clay minerals play an important role in biogeochemical cycles and for the dynamics of contaminant transformation in soils and aquifers. Reactions of Fe(II)/Fe(III) in clay minerals depend on a variety of mineralogical and environmental factors, which make the assessment of Fe redox reactivity challenging. Here, we use middle and near infrared (IR) spectroscopy to identify reactive structural Fe(II) arrangements in four smectites that differ in total Fe content, octahedral cationic composition, location of the negative excess charge, and configuration of octahedral hydroxyl groups. Additionally, we investigated the mineral properties responsible for the reversibility of structural alterations during Fe reduction and re-oxidation. For Wyoming montmorillonite (SWy-2), a smectite of low structural Fe content (2.8 wt%), we identified octahedral AlFe(II)-OH as the only reactive Fe(II) species, while high structural Fe content (>12 wt%) was prerequisite for the formation of multiple Fe(II)-entities (dioctahedral AlFe(II)-OH, MgFe(II)-OH, Fe(II)Fe(II)-OH, and trioctahedral Fe(II)Fe(II)Fe(II)-OH) in iron-rich smectites Ölberg montmorillonite, and ferruginous smectite (SWa-1), as well as in synthetic nontronite. Depending on the overall cationic composition and the location of excess charge, different reactive Fe(II) species formed during Fe reduction in iron-rich smectites, including tetrahedral Fe(II) groups in synthetic nontronite. Trioctahedral Fe(II) domains were found in tetrahedrally charged ferruginous smectite and synthetic nontronite in their reduced state while these Fe(II) entities were absent in Ölberg montmorillonite, which exhibits an octahedral layer charge. Fe(III) reduction in iron-rich smectites was accompanied by intense dehydroxylation and structural rearrangements, which were only partially reversible through re-oxidation. Re-oxidation of Wyoming montmorillonite, in contrast, restored the original mineral structure. Fe(II) oxidation experiments with nitroaromatic compounds as reactive probes were used to link our spectroscopic evidence to the apparent reactivity of structural Fe(II) in a generalized kinetic model, which takes into account the presence of Fe(II) entities of distinctly different reactivity as well as the dynamics of Fe(II) rearrangements.  相似文献   

Erratum     

S. Orr  S. P. Neumann 《Stochastic Hydrology and Hydraulics》1994,8(4):318

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MIDI – the 10 μm instrument on the VLTI     

Ch. Leinert  U. Graser  F. Przygodda  L.B.F.M. Waters  G. Perrin  W. Jaffe  B. Lopez  E.J. Bakker  A. Böhm  O. Chesneau  W.D. Cotton  S. Damstra  J. de Jong  A.W. Glazenborg-Kluttig  B. Grimm  H. Hanenburg  W. Laun  R. Lenzen  S. Ligori  R.J. Mathar  J. Meisner  S. Morel  W. Morr  U. Neumann  J.-W. Pel  P. Schuller  R.-R. Rohloff  B. Stecklum  C. Storz  O. von der Lühe  K. Wagner 《Astrophysics and Space Science》2003,286(1-2):73-83

After more than five years of preparation, the mid-infrared interferometric instrument MIDI has been transported to Paranal where it will undergo testing and commissioning on theVery Large Telescope Interferometer VLTI from the end of 2002through large part of this year 2003. Thereafter it will be available as a user instrument to perform interferometric observations over the8 μm–13 μm wavelength range, with a spatial resolution of typically 20 milliarcsec, a spectral resolution of up to 250, and an anticipated point source sensitivity of N = 3–4 mag or 1–2.5 Jy for self –fringe tracking, which will be the only observing mode during the first months of operation. We describe the layout of the instrument, laboratory tests, and expected performance, both for broadband and spectrally resolved observing modes. We also briefly outline the planned guaranteed time observations. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献