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31.
Understanding the forces that influence the distribution of land use and land-use change (LUC) is an essential step in developing effective strategies for managing these issues. We examined the influence of landscape position on spatial patterns in land-use distribution within the Little Tennessee River Basin (LTRB) of the southern Appalachian Mountains. We show that landscape position, defined with respect to both natural and anthropogenic spatial variables, provides for the identification of statistically significant differences in the distribution of common forms of land use in the study region. Using the same variables, significant differences in the landscape positions subject to land-use change in the LTRB are also examined. These results suggest landscape position exerts a strong influence on the distribution of different forms of land use and the likeliness of given area undergoing LUC. The approach presented here, of considering land use as a function of landscape position that responds to both natural and anthropogenic forces, may prove useful in aiding the development of future strategies to address the consequences of land use in many regions.  相似文献   
32.
A method for the determination of nickel in water was developed. The procedure involves preconcentration of nickel by using dispersive liquid–liquid microextraction. The Ni(II) ions were extracted in chloroform in the form of complex with the reagent 2‐(2′‐benzothiazolylazo)‐p‐cresol. Ethanol was used as the disperser solvent. After injection of the extracting mixture in a solution of nickel, a cloudy mixture was observed. A quick centrifugation induces phase separation and thus the settling of rich phase. The nickel content in the rich phase is measured by flame atomic absorption spectrometry. Under optimal conditions, the limit of detection and quantification obtained were 1.4 and 4.7 µg L?1, respectively. Some parameters used to characterize preconcentration systems, such as enrichment factor and consumption index were calculated and resulted in 29 and 0.34 mL, respectively. After optimization of variables and determination of analytical characteristics, the method was used for the analysis of certified reference materials (BCR‐713: wastewater, effluent and BCR‐414: plankton) and real water samples.  相似文献   
33.
Noble gases were studied in six wells, located on a 4.5 km south to north section across the Larderello field. Depth of wells, flow and gas/steam ratios are known to increase from south to north. Exploitation progressed in the same direction. The following noble gas patterns are observable: (a) Atmospheric Ar, Kr and Xe reflect productions of gas-depleted water at Colombaia 2 and progressively more gas-enriched steam towards the Gabbro wells. (b) Radiogenic4He and40Ar are observed in increasing concentrations from south to north. (c) The radiogenic and atmospheric gases reveal a positive correlation, indicating that the recharging water enters deep into the system, and gets well mixed with the radiogenic gases prior to the steam separation. (d) Gas contents and relative abundances of radiogenic argon decrease with production, thus supplying markers for the degree of exploitation in a well and a guide for optimum well spacing. (e) Excess neon over argon is observed and discussed in terms of crustal origin versus possible fractionation of atmospheric noble gases due to pertial steam separation.  相似文献   
34.
40Ar/39Ar geochronology of muscovite and biotite grains genetically related to gold and Be–Ta–Li pegmatites from the Seridó Belt (Borborema province, NE Brazil) yield well-defined, reliable plateau ages. This information, combined with data about paragenetic and field relationships, reveals Cambro-Ordovician mineralization ages (520 and 500–506 Ma) for the orogenic gold deposits in the Seridó Belt. Biotite ages of 525±2 Ma, which represent the mean weighted results of the incremental heating analysis of six biotite single crystals, record the time of pegmatite emplacement and reactivation of Brasiliano/Pan-African strike-slip shear zones. These results, along with previous structural evolution studies, suggest that shear zones formed during the Brasiliano/Pan-African event were reactivated in the Upper Cambrian–Lower Ordovician. Mineralization occurs late in the history of the orogen.  相似文献   
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36.
Atmospheric Ne, Ar, Kr and Xe are observed in fluids occurring in deep basins. Modifications of their abundance patterns reveal modes of recharge and brine formation, phase separations during boiling, and association of natural gas with water or oil. Radiogenic 4He and 40Ar serve as age indicators of entrapped fluids, effective over a significant portion of the geological time scale. Simultaneous application of δ13C, atmospheric noble gases and radiogenic 4He and 40Ar, is recommended to identify: (a) recent bacterial natural gas formation, not accompanied by oil, and (b) natural gas formed along with oil in a mature source rock.  相似文献   
37.
The broad-scale distribution of terrestrial ecosystem complexes is determined in large part by climate and can be altered by climatic change due to natural causes or due to human activities such as those leading to increasing atmospheric CO2 concentration. Classifications that recognize the dependence of natural vegetation on climate provide one means of constructing maps to display the impact of climatic change on the geography of major vegetation zones. A world map of the Holdridge Life-Zone Classification, developed from approximately 8,000 meteorological records, is compared with a Holdridge Map with average temperature increments simulated by a. model of climate under elevated atmospheric CO2 concentration. The largest changes are indicated at high latitudes, where the simulated temperature increase is largest and the temperature intervals defining life zones are smallest. Boreal Forest Zones are replaced by either Cool Temperate Forest or Cool Temperate Steppe, depending on average precipitation. Changes in the tropics are smaller; however, in some regions, Subtropical Moist Forest is replaced by Tropical Dry Forest.Research supported by the National Science Foundation's Ecosystem Studies Program under Interagency Agreement Nos. DEB81-15316 and DEB83-15185.  相似文献   
38.
The easternmost domain of the Borborema Province, northeastern Brazil, presents widespread, extensional-related high-temperature metamorphism during the Brasiliano (=Pan-African) orogeny. This event reached the upper amphibolite to granulite facies and provoked generalized migmatization of Proterozoic metapelitic rocks of the Seridó Group and tonalitic to granodioritic orthogneisses of the Archean to Paleoproterozoic basement. We report new geochronological data based on electron microprobe dating of monazite from metapelitic migmatite and leuconorite within the high-T shear zones that make up the eastern continuation of the huge E–W Patos shear belt. These data were also constrained by using the Sm–Nd isotopic systematic on garnet from a syntectonic alkaline granite and two garnet-bearing leucosomes. The results suggest an age of about 578 to 574 Ma for the peak of the widespread high-T metamorphism. This event is best recorded by Sm–Nd garnet-whole rock ages. The U–Th–Pb isotopes on monazite of the metapelitic migmatite show a younger thermal event at 553 ± 10 Ma. When compared to the Sm–Nd garnet-whole rock ages, the U–Th–Pb electron probe monazite ages seem to record an event of slightly lower temperatures after the peak of the high-T metamorphism. This may reflect the difference in the isotopic behavior of the geochronological methods employed. Otherwise, the U–Th–Pb ages on monazites could indicate an event not yet very well defined. In anyway, this paper reveals the partial or even complete re-opening and resetting of the U–Th–Pb isotopic system produced by the action of low-T Ca-rich fluid.  相似文献   
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40.
Linking quickflow response to subsurface state can improve our understanding of runoff processes that drive emergent catchment behaviour. We investigated the formation of non-linear quickflows in three forested headwater catchments and also explored unsaturated and saturated storage dynamics, and likely runoff generation mechanisms that contributed to threshold formation. Our analyses focused on two reference watersheds at the Coweeta Hydrologic Laboratory (CHL) in western North Carolina, USA, and one reference watershed at the Susquehanna Shale Hills Critical Zone Observatory (SHW) in Central Pennsylvania, USA, with available hourly soil moisture, groundwater, streamflow, and precipitation time series over several years. Our study objectives were to characterise (a) non-linear runoff response as a function of storm characteristics and antecedent conditions, (b) the critical levels of shallow unsaturated and saturated storage that lead to hourly flow response, and (c) runoff mechanisms contributing to rapidly increasing quickflow using measurements of soil moisture and groundwater. We found that maximum hourly rainfall did not significantly contribute to quickflow production in our sites, in contrast to prior studies, due to highly conductive forest soils. Soil moisture and groundwater dynamics measured in hydrologically representative areas of the hillslope showed that variable subsurface states could contribute to non-linear runoff behaviour. Quickflow generation in watersheds at CHL were dominated by both saturated and unsaturated pathways, but the relative contributions of each pathway varied between catchments. In contrast, quickflow was almost entirely related to groundwater fluctuations at SHW. We showed that co-located measurements of soil moisture and groundwater supplement threshold analyses providing stronger prediction and understanding of quickflow generation and indicate dominant runoff processes.  相似文献   
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