The Effects of Ground Water Sampling Devices on Water Quality: A Literature Review     

Louise V. Parker 《Ground Water Monitoring & Remediation》1994,14(2):130-141

This paper reviews both field and laboratory studies that tested or compared the ability of various types of sampling devices to deliver representative ground water samples. Several types of grab samplers, positive displacement devices, and suction-lift devices were evaluated, Gas-lift and inertial-lift pumps were also evaluated. This study found that most of these devices can. under certain circumstances, alter the chemistry of ground water samples, das-lift pumps, older types of submersible centrifugal pumps, and suction-lift devices are not recommended when sampling for sensitive constituents such as volatile organics and inorganics, or inorganics that are subject to oxidation/precipitation reactions. In general, of the devices reviewed in this paper, bladder pumps gave the best recovery of sensitive constituents. However, better performance could be achieved for several devices if improved operational guidelines were developed by additional testing, especially at lower flow rates. Clearly, further research is warranted. Future studies should focus on pumping rate, flow control mechanisms, and dedication or decontamination of sampling devices.  相似文献   

Effect of Concentration on Sorption of Dissolved Organics by PVC, PTFE, and Stainless Steel Well Casings     

Louise V. Parker  Thomas A. Ranney 《Ground Water Monitoring & Remediation》1994,14(3):139-149

This report examines sorption of low ppb levels of organic solutions by polytetra- fluoroethylene (PTFE), rigid polyvinyl chloride (PVC), and stainless steel 304 and 316 well casings. Nineteen organics were selected, including several munitions and chlorinated solvents. Compounds were selected to offer a range of physical properties, such as solubility in water, octanol/water partition coefficient, and molecular structure. When these results were compared with the results from a similar study conducted at ppm levels, the rate and extent of sorption by PTFE and PVC were the same as seen previously for almost all analytes. There were no losses of any compounds associated with stainless steel. At these low levels (ppm and ppb), the rate of diffusion within the polymer (PVC and PTFE) is independent of concentration. Only with PTFE are the rates rapid enough to be of concern when monitoring for some contaminants in ground water. Tetrachloroethylene was the compound PTFE sorbed the most rapidly. The study showed that PVC well casings are suitable for monitoring low levels (ppm and ppb) of organics.  相似文献   

Application of objective analysis to metallic traces in the atmospheric aerosol     

Christophe Migon  Bernard Gentili 《Journal of Atmospheric Chemistry》1993,16(3):277-284

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Influence of bottom topography roughness on the jet and inertial recirculation of a mid-latitude gyre     

Bernard Barnier  Christian Le Provost 《Dynamics of Atmospheres and Oceans》1993,18(1-2)

Several numerical experiments are conducted to examine the influence of mesoscale, bottom topography roughness on the inertial circulation of a wind-driven, mid-latitude ocean gyre. The ocean model is based on the quasi-geostrophic formulation, and is eddy-resolving as it features high vertical and horizontal resolutions (six layers and a 10 km grid). An antisymmetrical double-gyre wind stress curl forces the baroclinic modes and generates a strong surface jet. In the case of a flat bottom, inertia and inverse energy cascade force the barotropic mode, and the resulting circulation features strong, barotropic, inertial gyres. The sea-floor roughness inhibits the inertial circulation in the deep layers; the barotropic component of the flow is then forced by eddy-topography interactions, and its energy concentrates at the scales of the topography. As a result, the baroclinicity of the flow is intesified: the barotropic mode is reduced with regard to the baroclinic modes, and the bottom flow (constrained by the mesoscale sea-floor roughness) is decoupled from the surface flow (forced by the gyre-scale wind). Rectified, mesoscale bottom circulation induces an interfacial form stress at the thermocline, which enhances horizontal shear instability and opposes the eastward penetration of the jet. The mean jet is consequently shortened, but the instantaneous jet remains very turbulent, with meanders of large meridional extent. The sea-floor roughness modifies the energy pathways, and the eddies have an even more important role in the establishment of the mean circulation: below the thermocline, rectification processes are dominant, and eddies transfer energy toward permanent mesoscale circulations strongly correlated with topography, whereas above the thermocline mean flow and eddy generation are influenced by the mean bottom circulation through interfacial stress. The topography modifies the vorticity of the barotropic and highest baroclinic modes. Vorticity accumulates at the small topographic scales, and the vorticity content of the highest modes, which is very weak in the flat-bottom case, increases significantly. Few changes occur in surface-intensified modes. In the deep layers of the model, the inverse correlation between relative vorticity and topography at small scales ensures the homogenization of the potential vorticity, which mainly retains the largest scales of the bottom flow and the scale of β.  相似文献   

Book reviews     

Kacper R. Rybicki  Brian J. Mitchell  Louise H. Kellogg  Andrea Borgia  Allan M. Rubin  Douglas R. Schmitt  Douglas R. Schmitt  Edo Nyland  Zbigniew Fajklewicz  David Stevenson  Janusz L. Borkowski 《Pure and Applied Geophysics》1990,133(1):179-180

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Volatile fluxes from volcanoes   总被引：1，自引：0，他引：1  

Marie-Françoise Le Cloarec  Bernard Marty 《地学学报》1991,3(1):17-27

Volatile fluxes from Mid Ocean Ridge (MOR) and subaerial volcanism have been estimated or re-evaluated using several natural tracers-³He, ²¹⁰Po, SO₂-and chemical ratios of volatile species in lavas and volcanic gases.
These estimates confirm the net predominance of anthropogenic fluxes over volcanic fluxes for CO₂, SO₂ and trace metals.
They also suggest that, while most of the volatiles transferred during MOR volcanism come from the mantle, volatiles stored at the surface of the Earth supply an appreciable fraction of subaerial fluxes and can be the dominant source for some of them.
The surface inventory of volatile species cannot result from steady-state degassing with constant rate and needs much greater fluxes in the past or other volatile supply processes. This inventory is the result of several of the following processes: capture of the solar nebula and its subsequent partial escape, impact degassing of accreting bodies, and, from Archean to present mantle, degasssing through volcanism and associated phenomena, with recycling into the mantle through subduction.  相似文献   

Acid Neutralization by Gulf Coast Sediments     

Linn E. Fink  Winton G. Aubert  William J. Bernard 《Ground water》1991,29(4):489-494

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The Behavior of Dense, Nonaqueous Phase Liquids in Fractured Clay and Rock   总被引：2，自引：0，他引：2  

Bernard H. Kueper  David B. McWhorter 《Ground water》1991,29(5):716-728

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Carboxylic monoacids in the air of mayombe forest (Congo): Role of the forest as a source or sink     

Jean Servant  Georges Kouadio  Bernard Cros  Robert Delmas 《Journal of Atmospheric Chemistry》1991,12(4):367-380

In the tropical rain forests of the Congo during the dry season, from June to September 1987, carboxylic acid partial pressures (P _gas) in the air above the canopy, at ground level, and at the boundary layer, were estimated from water samples such as fog and rainwater. The concentrations of these acids were also measured in the sap of tree leaves. Tree leaves act as a sink or as a source if the acid P _gas is greater of lower than the acid concentrations in molecular form in sap. For each of these soluble gases, there is a value of P _gas where the exchange is nul. This is called the compensation point. Values of the compensation point for some tree leaves were evaluated according to Henry's law. Henry's law coefficients at ppm levels were redetermined for formic (HCOOH), acetic (CH₃COOH), propionic (CH₃CH₂COOH), and isobutyric (CH₃CH(CH₃)COOH) acids.By comparison of P _gas and compensation points, it is concluded that the forest was a potential source for these acids. The soil-or the litter-acts as a significant source of a carboxylic acid of C₃ or C₄ atoms in the aliphatic chain. This carboxylic acid, not yet fully characterized, could play an important role in the rain acidity in forested zones of the equatorial areas.The direct emission of these carboxylic acids by vegetation was the main source in the boundary layer above the forest. The average emissions were 3.1×10⁹, 7.8×10⁹, and 8.4×10⁹ molecules cm^-2 s^-1 for HCOOH, CH₃COOH, and CH₃CH₂COOH, respectively. The savanna is an exogenous source of HCOOH and CH₃CH₂COOH during moderately rainy days for 30% of the time. The ozonolysis of isoprene seems to be a small source of HCOOH.  相似文献   

(White) papering over the regional problem: unemployment in Geelong and the federal government response     

Louise Johnson  Steve Wright 《The Australian geographer》1994,25(2):121-125

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