Interfacial energy effects and the evolution of pore size distributions during quartz precipitation in sandstone     

Simon Emmanuel  Jay J. Ague 《Geochimica et cosmochimica acta》2010,74(12):3539-18706

Pore size is usually thought to control the rate of crystal growth in porous geological media by determining the ratio of mineral surface area to fluid volume. However, theory suggests that in micron-scale to nanometer scale pores, interfacial energy (surface energy) effects can also become important. Interfacial energy typically increases the solubility of very small crystals growing in tiny pores, and when the fluid is close to equilibrium - as is often the case in geological systems - mineral precipitation could occur in relatively large pores, while in very small adjacent pores crystal growth might be suppressed. Such a mechanism would effectively restrict the reactive surface area of the porous medium, thereby reducing the bulk reaction rate. We investigated the pore size distributions in naturally cemented sandstone adjacent to an isolated stylolite and found that quartz precipitation was inhibited in pores smaller than 10 μm in diameter. Furthermore, we demonstrate that kinetic formulations which assume constant solubility cannot reproduce the observed pore size patterns in mineralized samples; by contrast, excellent fits with the data are obtained when interfacial energy effects are taken into account. Reaction rates in geological media determined in field studies can be orders of magnitude lower than those measured in laboratory experiments, and we propose that reduced reaction rates in porous media with micron and submicron-scale porosity could account for much of the apparent paradox.  相似文献   

Improved Wildcat Modelling of Mineral Prospectivity     

Emmanuel John M. Carranza 《Resource Geology》2010,60(2):129-149

Wildcat modelling of mineral prospectivity has been proposed for greenfields geologically-permissive terranes where mineral targets have not yet been discovered but a geological map is available as a source of spatial data of predictors of mineral prospectivity. This paper (i) revisits the initial way of assigning wildcat scores (S_c) to predictors of mineral prospectivity and (ii) proposes an improvement by transforming S_c into improved wildcat scores (IS_c) by using a logistic function. This was shown in wildcat modelling of prospectivity for low-sulphidation epithermal-Au (LSEG) deposits in Aroroy district (Philippines). Based on knowledge of characteristics of and controls on LSEG mineralization in the Philippines, the spatial predictors of LSEG prospectivity used in the study are proximity to porphyry plutonic stocks, faults/fractures and fault/fracture intersections. The S_c and IS_c of spatial predictors are input separately to principal components analysis to extract a favourability function that can be interpreted as a wildcat model of LSEG prospectivity. The predictive capacity of the wildcat model of LSEG prospectivity based on the IS_c of geological predictors is roughly 70% higher than that of the wildcat model of LSEG prospectivity based on the S_c of geological predictors. A slight increase of predictive capacity of wildcat modelling of LSEG prospectivity is also achieved when the IS_c of geological predictors are integrated with the IS_c of geochemical anomalies, but not with the S_c of geochemical anomalies. The proposed improvement is significant because if the study district were a greenfields exploration area, then a wildcat model of LSEG prospectivity based on the old wildcat methodology would have caused several LSEG targets to be missed.  相似文献   

Nuclear spin temperature of ammonia in Comet 9P/Tempel 1 before and after the Deep Impact event     

Hideyo Kawakita  Emmanuel Jehin  Jean Manfroid 《Icarus》2007,187(1):272-275

The Deep Impact mission succeeded in excavating inner materials from the nucleus of Comet 9P/Tempel 1 on 2005 July 04 (at 05:52 UT). Comet 9P/Tempel 1 is one of Jupiter family short period comets, which might originate in the Kuiper belt region in the solar nebula. In order to characterize the comet and to support the mission from the ground-based observatory, optical high-dispersion spectroscopic observations were carried out with the echelle spectrograph (UVES) mounted on the 8-m telescope VLT (UT2) before and after the Deep Impact event. Ortho-to-para abundance ratios (OPRs) of cometary ammonia were determined from the NH₂ emission spectra. The OPRs of ammonia on July 3.996 UT and 4.997 UT were derived to be 1.28±0.07 (nuclear spin temperature: Tspin=24±2 K) and 1.26±0.08 (Tspin=25±2 K), respectively. There is no significant change between before and after the impact. Actually, most materials ejected from the impact site could have moved away from the nucleus on July 4.997 UT, about 17 h after the impact. However, a small fraction of the ejected materials might remain in the slit of UVES instrument at that time because an excess of about 20% in the NH₂ emission flux is observed above the normal activity level was found [Manfroid, J., Hutsemékers, D., Jehin, E., Cochran, A.L., Arpigny, C., Jackson, W.M., Meech, K.J., Schulz, R., Zucconi, J.-M., 2007. Icarus. This issue]. If the excess of NH₂ on July 04.997 UT was produced from icy materials excavated by the Deep Impact, then an upper-limit of the ammonia OPR would be 1.75 (Tspin>17 K) for those materials. On the other hand, the OPR of ammonia produced from the quiescent sources was similar to that of the Oort cloud comets observed so far. This fact may imply that physical conditions where cometary ices formed were similar between Comet 9P/Tempel 1 and the Oort cloud comets.  相似文献   

An open-source web service for creating quadrilateral grids based on the rHEALPix Discrete Global Grid System     

David Bowater  Emmanuel Stefanakis 《International Journal of Digital Earth》2020,13(9):1055-1071

ABSTRACT

The foundation of modern Digital Earth frameworks is the Discrete Global Grid System (DGGS). To standardize the DGGS model, the Open Geospatial Consortium (OGC) recently created the DGGS Abstract Specification, which also aims to increase usability and interoperability between DGGSs. To support these demands and aid future research, open implementations are necessary. However, several OGC conformant DGGSs are not available for researchers to use. This has motivated us to develop an open-source web service that allows users to create quadrilateral grids based on the rHEALPix DGGS. In this paper, we describe the implementation of the web service, including issues and limitations, and demonstrate how discrete global grids and regional grids can be created. Lastly, we present examples that show how vector data sets can be modeled and integrated at different levels of resolution – a key benefit of the DGGS model.  相似文献   

Richardson number profiles through shear instability wave regions observed in the lower planetary boundary layer     

C. B. Emmanuel 《Boundary-Layer Meteorology》1973,5(1-2):19-27

Remote sensing of the lower planetary boundary layer in the vicinity of a meteorological tower on many occasions reveals the existence of shear instability (Kelvin-Helmholtz) waves. In general, such waves are found within shallow strata which are marked by strong thermal stability and large vertical wind shear. The independent and concurrent measurements of the vector wind and temperature, made on a 152-m high tower, allow the construction of wind and temperature profiles. From such measurements, the Richardson number profile is constructed as well as the instability regime according to Drazin's criterion. The results show that regions of shear-instability waves as depicted by the remote sensor (an acoustic sounder) agree well with Drazin's instability regime, and that within such regions the Richardson number is indeed 0.25.  相似文献   

The formation and breakdown of Kelvin-Helmholtz billows     

C. J. Readings  D. Atlas  C. B. Emmanuel  Yih-Ho Pao  S. A. Thorpe 《Boundary-Layer Meteorology》1973,5(1-2):233-240

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An example of very consistent brittle deformation over a wide intracontinental area: The late Pan-African fracture system of the Tuareg and Nigerian shield     

Emmanuel Ball 《Tectonophysics》1980,61(4):363-379

Brittle deformation during the latter part of the Pan-African orogeny in the Hoggar and Nigeria was characterized by a conjugate strike slip fault system, consisting of NE—SW dextral and NW—SE sinistral trending sets of faults. This system is considered to be the result of a horizontal maximum stress axis $\text{σ}{}_1$ orientated E—W.In the crystalline basement, the faults have offset the N—S trending Pan-African mylonitic shear zones, and have cut the late orogenic granites (Taourirt) and ring complexes of Adrar des Iforas.In the western Hoggar, folding of the post-orogenic molassic “série pourprée” considered as Cambrian in age (Caby, 1970), is probably associated with the same stress regime. A similar fault system also affects the Phanerozoic sedimentary cover of the North-Saharian platform, the Ténéré desert, and the Djado basin. Later reactivation of this fault system by phanerozoic epeirogenic events, and recent uplift is demonstrated.The geometry of this late Pan-African brittle deformation is very consistent over a large area and may reflect the stress field operative during indentation of a “plastic” Pan-African shield, by a more rigid West-African craton.  相似文献   

Sources of very high heavy metal content in soils of volcanic island (La Réunion)     

Emmanuel D&#x;lsch  Herv Saint Macary  Virginie Van de Kerchove 《Journal of Geochemical Exploration》2006,88(1-3):194

The objective of this study was to conduct an inventory of heavy metal concentrations (Cd, Cr, Cu, Hg, Ni, Pb and Zn) in the soils of La Réunion. 39 sampling sites were selected to cover the distribution of soils of the island. The results show that soils of La Réunion are rich in heavy metals: most of them exceed the French standard values beyond which sewage sludge spreading is not authorized. To identify the sources of heavy metals, we used: (i) the relationship between the heavy metal content in soils and the origin of the volcanic parent material; (ii) the comparison of heavy metal content between cultivated and uncultivated soils; and (iii) the heavy metal distribution in soil profiles. Cd and Pb evolution in soil profiles indicate an impact of human activities. High Hg concentrations in soils can be explained by the volcanic activity of the island. For Cr, Cu, Ni and Zn, we demonstrate that high concentrations in soils are mainly determined by the natural pedo-geochemical background.  相似文献   

Using Rock‐Eval 6 pyrolysis for tracking fossil organic carbon in modern environments: implications for the roles of erosion and weathering     

Yoann Copard  Christian Di‐Giovanni  Thomas Martaud  Patrick Albric  Jean‐Emmanuel Olivier 《地球表面变化过程与地形》2006,31(2):135-153

This work relates to the debate on the fossil organic carbon (FOC) input in modern environments and its possible implication for the carbon cycle, and suggests the use of Rock‐Eval 6 pyrolysis as a relevant tool for tracking FOC in such environments. Considering that such a delivery is mainly due to supergene processes affecting the continental surface, we studied organic matter in different reservoirs such as bedrocks, alterites, soils and rivers in two experimental catchments at Draix (Alpes de Haute Provence, France). Samples were subjected to geochemical (Rock‐Eval 6 pyrolysis) investigations and artificial bacterial degradations. After comparing the geochemical fingerprint of samples, geochemical markers of FOC were defined and tracked in the different reservoirs. Our results confirm the contribution of FOC in modern soils and rivers and display the various influences of weathering and erosional processes on the fate of FOC during its exchange between these pools. In addition, the contrasting behaviour of these markers upon the supergene processes has also highlighted the refractory or labile characters of the fossil organic matter (FOM). Bedrock to river fluxes, controlled by gully erosion, are characterized by a qualitative and quantitative preservation of FOM. Bedrock to alterite fluxes, governed by chemical weathering, are characterized by FOC mineralization without qualitative changes in deeper alterites. Alterite to soils fluxes, controlled by (bio)chemical weathering, are characterized by strong FOC mineralization and qualitative changes of FOM. Thus weathering and erosional processes induce different FOM evolution and affect the fate of FOC towards the global carbon cycle. In this study, gully erosion would involve maintenance of an ancient sink for the global carbon cycle, while (bio)chemical processes provide a source of CO₂. Finally, this study suggests that Rock‐Eval 6 pyrolysis can be considered as a relevant tool for tracking FOC in modern environments. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Optimized Computation of Transfer Coefficients in Surface Layer with Different Momentum and Heat Roughness Lengths     

Emmanuel Guilloteau 《Boundary-Layer Meteorology》1998,87(1):147-160

A new method for computing the surface transfer coefficients is proposed, based on state-of-the-art empirical flux-profile relationships. The influence of the roughness length ratio is first demonstrated with the classical iterative calculation method. Then a non-iterative algorithm is developed, taking into account the difference between momentum and heat roughness lengths.The new method is validated by comparison with the reference iterative computation. The large gain-in computer processing time (CPU) time gain for the calculation of surface fluxes in Eulerian grid models is finally assessed.  相似文献