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21.
Caroline‐Emmanuelle Morisset James S. Scoates Dominique Weis André Rahier 《Geostandards and Geoanalytical Research》2014,38(2):159-176
The high abundances of the high field‐strength elements in ilmenite and rutile make these minerals particularly suitable for hafnium isotopic investigations. We present a technique for separating Hf by ion exchange chemistry from high‐TiO2 (> 40% m/m) minerals to achieve precise Hf isotopic composition analyses by MC (multiple collector)‐ICP‐MS. Following digestion and conversion to chlorides, the first elution column is used to separate iron and the rare earth elements, the second column is designed to separate most of the titanium from Hf, an evaporation step using HClO4 is then performed to remove any trace of HF in preparation for the third column, which is needed to eliminate any remaining trace of titanium. The modified chemistry helped to improve the yields from < 10 to > 78% as well as the analytical precision of the processed samples (e.g., sample 2033‐A1, 176Hf/177Hf = 0.282251 ± 25 before vs. 0.282225 ± 6 after). The technique was tested on a case study in which the Hf isotopic ratios of ilmenite and rutile (analysed prior to the chemistry improvement) were determined and permitted to evaluate that the origin of rutile‐bearing ilmenite deposits is from the same or similar magma than their, respectively, associated Proterozoic anorthosite massifs (Saint‐Urbain and Lac Allard) of the Grenville Province in Québec, Canada. 相似文献
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Sediments along the Loire River (central France) were investigated by means of Pb isotopes determined on the labile sediment fraction, or acid-extractable matter (AEM). The combination of trace elements and Pb isotopes allows deciphering the origin of the elements (i.e. natural or anthropogenic) and their history, in the sediment from two small watersheds (one draining basalt, the other one granite–gneiss), both in present-day suspended matter in Loire River water, and in sediment from the Loire estuary. Crustal weathering, as confirmed by the Pb-isotope ratios for most sample points, is the main source of Pb in the upstream part of the Loire River, as well as that transported in the middle part of the basin and in the estuary. Among anthropogenic sources, the use of Pb-isotopic compositions shows an influence of agriculturally-derived Pb inputs and a major input of Pb derived from gasoline, particularly in the estuary due to harbor activities. 相似文献
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Fournier J Levesque E Pouvreau S Pennec ML Moullac GL 《Marine pollution bulletin》2012,65(10-12):463-470
Pearl culture industry represents one of the dominant business sector of French Polynesia. However, it still entirely relies on unpredictable spat collection success. Our aim was to assess the influence of natural plankton concentration fluctuations on maturation and spawning of the black lip pearl oyster Pinctada margaritifera, during a 4months survey conducted in Ahe atoll lagoon. Plankton concentration was assessed by chlorophyll a extraction and by microscope counts while gonadic index, gonado-visceral dry weights and histology were used to measure pearl oysters reproduction activity. We found that (i) plankton concentration fluctuations were mainly related to wind regime, (ii) gametogenesis rate was mainly related to plankton concentration, (iii) spawning occurred when maximal gonad storage was reached, (iv) plankton concentration was the main spawning synchronizing factor. These results contribute explaining P. margaritifera spat collection variability in French Polynesian atoll lagoon. 相似文献
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Contourites in the Gulf of Cadiz: a cautionary note on potentially ambiguous indicators of bottom current velocity 总被引：1，自引：1，他引：0
Thierry Mulder Rim Hassan Emmanuelle Ducassou Sébastien Zaragosi Eliane Gonthier Vincent Hanquiez Elodie Marchès Samuel Toucanne 《Geo-Marine Letters》2013,33(5):357-367
Facies associations in cores collected in the deep part of the Gulf of Cadiz, which is under the influence of the lower branch of the Mediterranean Outflow Water, are investigated in terms of the classical contourite model using grain-size analyses and thin sections of indurated sediment. Cores include both low-energy (contourite drift) and high-energy (channel) environments. The thin sections and grain-size distributions show that clayey fine silts and sandy coarse silts are the most common facies associations in the studied contourite sequences, while coarse-grained, gravelly contourites are less common. Grain-size distributions are unimodal in the fine-grained and bi- or trimodal in the coarser-grained contourites. This change in grain-size composition is related both to the partial removal of the fine-grained fraction and to the replenishment of the coarser-grained one. In addition, most of the contacts between individual facies are sharp rather than transitional. This suggests that the contourite sequence is only in part related to changes in bottom current velocity and flow competency, but may also be related to the supply of a coarser terrigeneous particle stock, provided by either increased erosion of indurated mud along the flanks of confined contourite channels (mud clasts), or by increased sediment supply by rivers (quartz grains) and downslope mass transport on the continental shelf and upper slope. The classical contourite facies association may therefore not be solely controlled by current velocity, but may be the product of a variety of depositional histories. The classical contourite depositional sequence should therefore be interpreted with greater care and in the light of the regional sedimentological background. In addition, the wisdom of exclusively using mean or modal particle size for the interpretation of depositional contourite processes is questioned. Instead, it is proposed that the vertical evolution of grain-size populations in the facies successions forming contourite sequences be assessed. 相似文献
25.
Emmanuelle Buecher 《Journal of Sea Research》1999,41(4):95
The vertical and temporal distribution of two calycophoran siphonophores, Chelophyes appendiculata (Eschscholtz, 1829) and Abylopsis tetragona (Otto, 1823) in the Bay of Villefranche (northwestern Mediterranean) was investigated by an analysis of three different planktonic time series. A daily series (1993–1995) showed seasonal peaks of the nectophores of C. appendiculata during spring and particularly in late summer, while the abundance of A. tetragona remained similar throughout the year. A weekly series (1994–1995) showed that C. appendiculata (nectophores and eudoxids) became concentrated above the thermal discontinuity, in the most stratified and warm waters, whereas A. tetragona was collected in large numbers below this discontinuity. A 27-year survey (1966–1993) showed long-term fluctuations of these siphonophore populations, which became abundant in the Bay starting from 1980 and especially after 1984, when the water column grew warm and hypersaline, corresponding to a less rainy period. Temporal (seasonal and long-term) and bathymetric (between 10 and 60 m depth) successions of these two siphonophores were noted in this shallow coastal bay. 相似文献
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Emmanuelle S. Chardon Dirk Bosbach Ian C. Lyon Jürgen Römer David J. Vaughan Roy A. Wogelius 《Geochimica et cosmochimica acta》2008,72(2):288-297
Feldspar minerals are thermodynamically unstable in the near-surface environment and their surfaces are well known to react readily with aqueous solutions, leading to incongruent dissolution at low pH values, but congruent dissolution at neutral and high pH values. Interactions with mineral surfaces are an important control on the environmental transport of trace elements and detrital feldspars are abundant in soils and sediments. However, the interactions of metal ions in solution with the reacting feldspar surface have not been widely explored. The interactions of Pb(II), U(VI) and Np(V) ions with the feldspar surface have therefore been studied. Lead is taken up by the microcline surface at pH 6 and 10, but no uptake could be measured at pH 2. There was measurable uptake of Pb(II) on the plagioclase surface at pH 2, 6 and 10. Uptake always increased with pH. In most conditions, Pb(II) reacts through cation exchange process although, at high pH, a discrete phase, probably hydrocerrusite, is observed by atomic force microscopy (AFM) to precipitate on the plagioclase surface. Supersaturation with hydrocerrusite in these conditions is expected from thermodynamic calculations. Uptake of uranyl ion , generally through surface complex formation, could only be measured at pH 6 and 10. At pH 6 and an initial U(VI) concentration above 21.0 μM, precipitation of becquerelite (Ca[(UO2)3O2(OH)3]2·8H2O), identified by AFM and characterised by grazing incidence X-ray diffraction and X-ray photoelectron spectroscopy, is observed on plagioclase. The U(VI) concentration range in which becquerelite precipitation begins (dissolved U(VI) 1-5 μM) is consistent with that predicted from thermodynamic modelling. On plagioclase feldspar, secondary ion mass spectrometry showed diffusion of uranium into the altered surface layer. Uptake of the neptunyl ion (Np(V)) was found at pH 6 and 10 for microcline and at pH 2, 6 and 10 for plagioclase, and was generally lower than uptake of U(VI). By combining batch sorption experiments with imaging and surface analysis, and thermodynamic modelling, it has been possible to gain a mechanistic insight into the reactions of the feldspar surface with metal ions in solution. 相似文献
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Philippe E. Raison Claudiu C. Pavel Regis Jardin Emmanuelle Suard Richard G. Haire Karin Popa 《Physics and Chemistry of Minerals》2010,37(8):555-559
The thermal expansion of cubic pyrochlore Ce2Zr2O7 has been measured from room temperature to 898 K on polycrystalline material in conjunction with structural analyses using
neutron diffraction. This compound has a thermal expansion coefficient in line with the other comparable lanthanoide pyrochlore
oxides. The coefficient can be expressed as α(T) = 8.418 × 10−6 + 0.9861 × 10−9 × T. The structural refinements performed for each measured temperature showed a comparable linear evolution of the Ce–O/Zr–O
distances (within 0.57%). 相似文献
30.
The current use of untreated river water for drinking purposes by the population of French Guiana has important impacts on public health. Consequently, groundwater is of major importance as a possible alternative drinking water supply to reduce these impacts. Since French Guiana belongs to the Guyana Shield, sustainable water management can be expected to depend increasingly on water from fissured aquifers in hard rocks. Groundwater samples were collected from shallow drill holes in the densely populated coastal area, and deeper wells in the basement (around Cayenne and along the Maroni and Oyapock rivers). This study reports on major and trace elements for which Na+ and Ca2+ excess with regard to Cl reflect the role of water-rock interaction, as well as Sr and Nd isotopes that reflect the role of the different lithologies. δ18O and δD in waters give constraints on the water cycle (recharge and evaporation processes). 相似文献