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91.
92.
Nuria Castell Ariel F. Stein Enrique Mantilla Rosa Salvador Millán Millán 《Journal of Atmospheric Chemistry》2009,63(1):73-91
Understanding the chemical links between ozone (O3) and its two main precursors, nitrogen oxides (NOx) and volatile organic compounds (VOC), is important for designing effective
photochemical smog reduction strategies. This chemical relationship will determine which precursor (NOx or VOC) emission reduction
will be more effective for decreasing the ozone formation. Under certain conditions, ozone levels decrease as a result of
a reduction in NOx emissions but do not respond significantly to changes in VOC emissions (NOx-sensitive condition), while
under other conditions ozone concentrations decrease in response to reductions in VOCs and may even increase when NOx emissions
are reduced (VOC-sensitive conditions). Indicator species can be used to assess the sensitivity of ozone to changes in the
emissions of its precursors. These indicators are species or species ratios involved in ozone photochemistry which reflect
the primary chemical process through which the ozone was formed. In this work we use the MM5-CAMx model system to explore
the behaviour of various indicator species during two meteorological situations featuring different atmospheric conditions
in a complex terrain area. The results show that indicators based on nitrogen compounds (i.e,. NOy and NOz) are suitable for
defining the transition range from VOC- to NOx-sensitive chemistry, and that despite the uncertainties associated with the
use of chemical indicators, the ratios O3/NOy and O3/NOz may provide a simple and useful way to summarize the response of ozone to changes in NOx and VOC emissions in Southwestern
Spain. 相似文献
93.
Gail M. Ashley Doris Barboni Manuel Dominguez-Rodrigo Henry T. Bunn Audax Z.P. Mabulla Fernando Diez-Martin Rebeca Barba Enrique Baquedano 《Quaternary Research》2010,74(3):304-314
The 1959 discovery of the hominin fossil Zinjanthropus boisei brought the world's attention to the rich records at Olduvai Gorge, Tanzania. Subsequent excavations of archaeological level 22 (FLK Zinj) Bed I uncovered remains of Homo habilis and a high-density collection of fossils and Oldowan stone tools. The occurrence of this unusual collection of bones and tools at this specific location has been controversial for decades. We present paleoecological data that provide new insights into the origin of FLK Zinj. Our recent excavations 200 m north of the site uncovered a 0.5-m-thick tufa mound draped by Tuff IC, in the same stratigraphic horizon as level 22. Stable isotope analyses indicate that the carbonates were deposited by a freshwater spring. Phytolith analysis of the waxy clay under Tuff IC revealed abundant woody dicotyledon and palm phytoliths, indicating that the site was wooded to densely wooded. The time equivalency and close physical proximity of the two environments indicate the two are related. This study has provided the first documented evidence of springs in Bed I and these data have important implications for the interpretation of hominin behavior in meat acquisition and the ongoing debate on scavenging versus hunting. 相似文献
94.
<正>One new genus and five new species of the family Evaniidae are described from the Early Cretaceous (Albian)Spanish amber of Penacerrada-Ⅰ(Province of Burgos),San Just and Arroyo de la Pascueta(both in the Province of Teruel):Cretevania alonsoi sp.nov.,C.montoyai sp.nov.,C.alcalai sp.nov.,C.rubusensis sp.nov.,and Iberoevania roblesi gen.and sp.nov.Taxonomic changes include Cretevania pristina(Zhang and Zhang,2000) comb.nov.,C.exquisita(Zhang,Rasmtsyn,Wang and Zhang,2007)comb.nov.,C.vesca(Zhang,Rasnitsyn,Wang and Zhang,2007)comb.nov.,and C.cyrtocerca(Deans,2004)comb.nov.,as a result of the reinterpretation of the genera Procretevania and Eovernevania.The new well preserved specimens of the genus Cretevania,together with the characters shown by the type specimens of the synonymized genera,give new information about their anatomical characters of taxonomical importance,and the genus Cretevania Rasnitsyn,1975 is re-diagnosed.The holotypes of the Russian species in amber have been revised.A cladistic analysis of fossil and extant groups of the superfamily Evanioidea is included.Cretevania had a wide palaeogeographic distribution,with the highest diversity known from Spain.The 13 known Cretevania species show a high interspecific variation mainly in wing characteristics,and a wide range of body and wing size. 相似文献
95.
Santiago Torres Enrique García-Berro Jordi Isern 《Monthly notices of the Royal Astronomical Society》2007,378(4):1461-1470
The disc white dwarf luminosity function is an important tool for studying the solar neighbourhood, since it allows the determination of several Galactic parameters, the most important one being the age of the Galactic disc. However, only the method has been employed so far for observationally determining the white dwarf luminosity function, whereas for other kind of luminosity functions several other methods have been frequently used. Moreover, the procedures to determine the white dwarf luminosity function are not free of biases. These biases have two different origins: they can either be of statistical nature or a consequence of the measurement errors. In a previous paper we carried out an in-depth study of the first category of biases for several luminosity function estimators. In this paper we focus on the biases introduced by the measurement errors and on the effects of the degree of contamination of the input sample used to build the disc white dwarf luminosity function by different kinematical populations. To assess the extent of these biases we use a Monte Carlo simulator to generate a controlled synthetic population and analyse the behaviour of the disc white dwarf luminosity function for several assumptions about the magnitude of the measurement errors and for several degrees of contamination, comparing the performances of the most robust luminosity function estimators under such conditions. 相似文献
96.
Caracas, Venezuela, Site Effect Determination with Microtremors 总被引:1,自引:0,他引:1
A.-M. Duval S. Vidal J.-P. Méneroud A. Singer F. De Santis C. Ramos G. Romero R. Rodriguez A. Pernia N. Reyes C. Griman 《Pure and Applied Geophysics》2001,158(12):2513-2523
—?Caracas 1967 earthquake caused heavy damage to multi-story buildings. In 1995, 184 microtremor measurement points were performed over the city. The measurement grid was more or less dense and covered the main part of the alluvial basin as well as surrounding rock basement. For each point, the horizontal record spectrum was divided by the vertical one (H/V ratio). Subsequently, the strongest value (Ao) of this ratio in a given frequency band was kept, as well as the frequency (Fo) where it occurred. Spatial interpolations of Ao and Fo were performed among all points of Palos Grandes district. A map was plotted representing a single surface where Ao is relief and Fo is represented by grey gradation. An alluvion thickness (H) map can be compared with this result. Damaged buildings are located on the same map. Fo decreases until 0.6?Hz when alluvion thickness (H) increases. Fo values fit with frequencies previously predicted from computation and with 1967 earthquake observations. Moreover, interpolation surfaces show that amplification (Ao) of H/V on microtremor is quite low above rock but is high on the south part of the basin. The maximum occurs over the non-urbanized zone. However the other area, where Ao is higher than 5, roughly corresponds to the location of the four collapsed buildings. Furthermore, the estimated natural frequency of these buildings was around Fo. Graphics showing H, Fo and Ao evolution through the basin were composed. Links between all these values are noticeable. Fo is claimed to be very similar to the resonance frequency of soil. As for Ao, it could be a fairly relevant sign of damage seriousness. Microtremor technique is an economic tool and it allows measurement grid as dense as desired. H/V ratio processing followed by interpolation of maximum values provides precise and useful information about expected site effect. 相似文献
97.
Sulfur isotope analyses were made on 14 alunites from volcanic and sedimentary rocks widely different in chemistry and age from southern Tuscany and northern Latium, central Italy. The 34S values range from +0.7 to +9.6, and appear not to be related to the nature of the host rock. Geological and isotopic evidence suggests that all the alunites formed by supergenic oxidation of sulfides. Sulfides occurring with alunites in the volcanic rocks of Latium can be divided into an isotopically light group of probably magmatic origin (34S=–1.5 to +3.4) and a heavy one with 34S=+6.0 to +10.3, tentatively interpreted as deposited by hydrothermal fluids that leached sulfides of similar 34S/32S from the deep basement. Such an interpretation is consistent with recent studies indicating that in the perityrrhenian belt of Latium exists a continuation, at depth, of the Tuscan stratigraphic series, rich in sulfides with 34 from +6 to +12. 相似文献
98.
Teresa DeDiego- Forbis Robert Douglas Donn Gorsline Enrique Nava-Sanchez Larry Mack Jay Banner 《Quaternary International》2004,120(1):29
Late Pleistocene age terrace deposits are exposed in the narrow cliffed coastal plain of Bahia Coyote, Baja California Sur, resting unconformably on the lagoonal-shallow water volcaniclastics of the early Miocene Cerro Colorado Member of the El Cien Formation. The terrace is dissected by widely spaced arroyos and partically covered by alluvial fans in the inner and central areas. The marine deposits vary in thickness from 0.5 to 10 m and were laid down in pre-existing erosional channels and depressions in the Pleistocene landscape. The sequence begins with a cobble conglomerate with oyster shells, overlain by poorly bedded molluscan-rich bioclastic sands and coral rubble, beds of massive Porites in growth position and coral-rhodolith sands and marls. Beach sands and gravels and coastal dunes cap the sequence.Samples of Porites panamensis selected for U/Th dating are well-preserved aragonite (>95%). Preliminary results yield U/Th ages of 109–209 ka but the corals have initial δ 234U values in excess of modern seawater values. This indicates open-system behavior and uncertainty associated with the ages. A corrected age for the top of the massive Porites unit suggests that the corals grew during the last interglacial, marine isotope stage (MIS) 5e sea level high stand.Assuming global sea level during MIS 5e was ca. 4–5 m above present-day sea level (McCulloch and Esat, 2000) and the growth position of the corals was 1–5 m below sea level, the terraces have been uplifted between 12 and 25 m (12–15 cm/kyr). This is consistent with other terrace-based uplift rates for the central Baja California peninsula, north of the La Paz fault. 相似文献
99.
Loss on ignition: a qualitative or quantitative method for organic matter and carbonate mineral content in sediments? 总被引:5,自引:7,他引:5
Juan I. Santisteban Rosa Mediavilla Enrique López-Pamo Cristino J. Dabrio M. Blanca Ruiz Zapata M. José Gil García Silvino Castaño Pedro E. Martínez-Alfaro 《Journal of Paleolimnology》2004,32(3):287-299
Since the publication of the paper of , loss on ignition (LOI) has been widely used as a method to estimate the amount of organic matter and carbonate mineral content (and indirectly of organic and inorganic carbon) in sediments. The relationships between LOI at 550 °C (LOI550) and organic carbon (OC) content and between LOI at 950 °C (LOI950) and inorganic carbon (IC) content are currently accepted as a standard. However, the comparison of 150 analyses of samples of diverse lithologies, collected from a single core, reveals that these relationships are affected by sediment composition (presence of clays, salts, and the variable content of organic carbon). This results in an incremental error on the estimation of carbon content from LOI values that invalidates the use of LOI values as a quantitative method for estimating carbon content. Conversely, the general trends of LOI550 and LOI950 show a good correlation with carbon content (both organic and inorganic) allowing use of LOI as a qualitative test for carbon content. Similarly, in our case, LOI at 105 °C (LOI105) is a good qualitative proxy for the trends in gypsum content. 相似文献
100.
A new base‐isolation mechanism corresponding to a variance of the stepping A‐shaped frame is proposed and its seismic performance is investigated numerically for strong ground accelerations with peak values in the range from 0.5 to 1g. In its simplest two‐dimensional form, the system consists of a frame with two telescoping legs pinned at the apex at a sharp angle. The legs are attached to the foundation through a spring and a damper acting in parallel. Both the springs and viscous dampers have bilinear characteristics that make them very stiff in compression but very soft in tension. As the structure rocks sideways, the length of the loaded leg remains essentially constant while the length of the unloaded leg increases. When the ground acceleration changes direction, the process is reversed. The resulting system has three main characteristics: (i) as the structure steps on a rigid leg, the maximum acceleration that can be transmitted to the superstructure is limited to a value which is approximately independent of the amplitude of the ground motion; (ii) there is a systematic lifting of the superstructure with kinetic energy being systematically transformed into potential energy during the strong phase of the ground motion; and (iii) the system is slowly self‐centering at the end of the earthquake. The seismic performance of the system is evaluated for a tall bridge pier and for a smaller frame that could be used in a multi‐story building. The results obtained for the 1940 El Centro ground motion scaled to 1g and for the near‐field Rinaldi ground motion recorded during the Northridge earthquake show that substantial reductions of the absolute acceleration can be obtained with reasonable relative displacements of the superstructure and small strokes in the isolation devices. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献