Using GPS multipath to measure soil moisture fluctuations: initial results   总被引：13，自引：2，他引：11  

Kristine M. Larson  Eric E. Small  Ethan Gutmann  Andria Bilich  Penina Axelrad  John Braun 《GPS Solutions》2008,12(3):173-177

Measurements of soil moisture are important for studies of climate and weather forecasting, flood prediction, and aquifer recharge studies. Although soil moisture measurement networks exist, most are sparsely distributed and lack standardized instrumentation. Measurements of soil moisture from satellites have extremely large spatial footprints (40–60 km). A methodology is described here that uses existing networks of continuously-operating GPS receivers to measure soil moisture fluctuations. In this technique, incoming signals are reflected off and attenuated by the ground before reception by the GPS receiver. These multipath reflections directly affect signal-to-noise ratio (SNR) data routinely collected by GPS receivers, creating amplitude variations that are a function of ground reflectivity and therefore soil moisture content. After describing this technique, multipath reflection amplitudes at a GPS site in Tashkent, Uzbekistan are compared to estimates of soil moisture from the Noah land surface model. Although the GPS multipath amplitudes and the land surface model are uncalibrated, over the 70-day period studied, they both rise sharply following each rainfall event and slowly decrease over a period of ∼10 days.  相似文献   

Distribution of authigenic albites in a limestone succession of the Helvetic Domain, eastern Switzerland     

Pauline Rais  Beat Louis-Schmid  Stefano M. Bernasconi  Eric Reusser  Helmut Weissert 《Swiss Journal of Geoscience》2008,101(1):99-106

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Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes     

Eric Grosjean  Daniel Grosjean 《Journal of Atmospheric Chemistry》1996,24(2):141-156

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.  相似文献   

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes     

Eric A. Betterton 《Journal of Atmospheric Chemistry》1993,17(4):307-324

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.  相似文献   

Experimental investigation and application of the equilibrium rutile + orthopyroxene = quartz + ilmenite     

Jodie L. Hayob  Steven R. Bohlen  Eric J. Essene 《Contributions to Mineralogy and Petrology》1993,115(1):18-35

Equilibria in the Sirf (Silica-Ilmenite-Rutile-Ferrosilite) system: $${\text{SiO}}_{\text{2}} + ({\text{Mg,Fe}}){\text{TiO}}_{\text{3}} {\text{ + (Mg,Fe)SiO}}_{\text{3}} $$ have been calibrated in the range 800–1100° C and 12–26 kbar using a piston-cylinder apparatus to assess the potential of the equilibria for geobarometry in granulite facies assemblages that lack garnet. Thermodynamic calculations indicate that the two end-member equilibria involving quartz + geikielite = rutile + enstatite, and quartz + ilmenite = rutile + ferrosilite, are metastable. We therefore reversed equilibria over the compositional range Fs_40–70, using Ag₈₀Pd₂₀ capsules with \(f_{{\text{O}}_{\text{2}} } \) buffered at or near iron-wüstite. Ilmenite compositions coexisting with orthopyroxene are \(X_{{\text{MgTiO}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.06 to 0.15 and \(X_{{\text{Fe}}_{\text{2}} {\text{O}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.00 to 0.01, corresponding toK _D values of 13.3, 10.2, 9.0 and 8.0 (±0.5) at 800, 900, 1000 and 1100° C, respectively, whereK _D =(XMg/XFe)^Opx/(XMg/XFe)^Ilm. Pressures have been calculated using equilibria in the Sirf system for granulites from the Grenville Province of Ontario and for granulite facies xenoliths from central Mexico. Pressures are consistent with other well-calibrated geobarometers for orthopyroxeneilmenite pairs from two Mexican samples in which oxide textures appear to represent equilibrium. Geologically unreasonable pressures are obtained, however, where oxide textures are complex. Application of data from this study on the equilibrium distribution of iron and magnesium between ilmenite and orthopyroxene suggests that some ilmenite in deep crustal xenoliths is not equilibrated with coexisting pyroxene, while assemblages from exposed granulite terranes have reequilibrated during retrogression. The Sirf equilibria are sensitive to small changes in composition and may be used for determination of activity/composition (a/X) relations of orthopyroxene if an ilmenite model is specified. A symmetric regular solution model has been used for orthopyroxene in conjunction with activity models for ilmenite available from the literature to calculatea/X relations in orthopyroxene of intermediate composition. Data from this study indicate that FeSiO₃?MgSiO₃ orthopyroxene exhibits small, positive deviations from ideality over the range 800–1100°C.  相似文献   

Diamondiferous eclogites from Yakutia,Siberia: evidence for a diversity of protoliths   总被引：1，自引：1，他引：0  

Eric A. Jerde  Lawrence A. Taylor  Ghislaine Crozaz  Nikolai V. Sobolev  Vladimir N. Sobolev 《Contributions to Mineralogy and Petrology》1993,114(2):189-202

Major-element and REE compositions of 14 diamondiferous eclogites from the Udachnaya kimberlite in Yakutia, Siberia have been determined by electron microprobe and secondary ion mass spectrometer (SIMS). Based on previous clinopyroxene classification schemes (e.g., Taylor and Neal 1989), all of these eclogite xenoliths belong to Group B/C, although some of the garnet compositions and mineral REE abundances are inconsistent with the indicated groups. This demonstrates the inadequacy of the classification scheme based on African eclogites for application to Siberian samples. Because of the coarse grain size of the Udachnaya nodules, meaningful modal abundances could not be obtained. However, reconstructed REE compositions using various garnet: clinopyroxene ratios demonstrate relative insensitivity to changes in mode for common eclogitic assemblages. Many of these reconstructed REE compositions show LREE depletions. Some depletions are consistent with an origin (either directly or through partial melting) as normal or Type-I ocean floor basalt. Others, however, require material of eclogitic or pyroxenitic affinities to undergo partial melting; this facilitates the depletion of LREE while leaving the HREE at nearly original levels. Many of the eclogites of South Africa are consistent with a protolith of anomalous or Type II ocean floor basalt. This fundamental difference between the two regions is the likely cause of the inconsistencies with the chemicallybased classification.  相似文献   

Propagation and absorption of cyclotron maser radiation in solar microwave spike bursts     

Z. Kuncic  P. A. Robinson 《Solar physics》1993,145(2):317-338

It has been argued that the loss-cone-driven electron cyclotron maser instability can account for the properties of millisecond microwave spike bursts observed during some solar flares. However, as it propagates outward from the corona, maser radiation undergoes gyroresonance absorption when its frequency is a harmonic of the local electron-cyclotron frequency. Existing analytical models using slab geometries predict that this absorption should be sufficiently strong to prevent the radiation from being seen at the observed levels, except under highly restrictive conditions or for unrealistic plasma parameters. A more comprehensive analysis is presented here to determine if and when maser radiation can escape to produce microwave spike bursts. This analysis employs numerical raytracing and incorporates propagation and absorption of fundamental maser emission in a realistic model of a coronal flux loop. It is found that ranges of physical conditions do exist under which maser radiation can escape to an observer and that these conditions are much more limiting for fundamental emission in the extraordinary ()-mode than in the ordinary (o)-mode. Detailed investigation implies that escaping radiation in the -mode is highly directional and chiefly observable toward the center of the solar disk, while escapingo-mode radiation is found to emerge from the corona over a much wider range of directions, with some cases corresponding to radiation observable near the solar limb.  相似文献   

Confirmation of radio absorption by the intergalactic medium     

Eric J. Lerner 《Astrophysics and Space Science》1993,207(1):17-26

The conventional interpretation of the cosmic background radiation (CBR) as a relic of the Big Bang assumes that the intergalactic medium is highly transparent to radio frequency radiation. Previous work (Lerner, 1990) used the well-known correlation of IR and radio luminosities of spiral galaxies to test this assumption. That analysis, using 237 Shapley-Ames galaxies showed that radio luminosity (L _R ) for a given IR-luminosity, declines with distance, implying that the IGM strongly absorbs radio frequency radiation. That absorption has now been confirmed using a sample of 301 IR-bright galaxies. Using two independent methods of determining the correlation of IR and radio luminosities of spiral and interacting galaxies, the sample shows that for a givenL _IR ,L _R D ^{–0.32±0.04} over a range of distances from 0.7-300 Mpc. (H ₀ = 75 km s^–1 Mpc^–1). The correlation is significant at the 8 or 10^–14 level. Absorption by the IGM is the only reasonable explanation for this correlation. The existence of such absorption implies that neither the isotropy nor the spectrum of the CBR are primordial and that neither is evidence for a Big Bang.  相似文献   

Plasma processing of interstellar PAHs into solar system kerogen     

Wdowiak TJ  Lee W  Cronin J  Beegle LW  Robinson MS 《Planetary and Space Science》1995,43(10-11):1175-1182

Processes resulting in the formation of hydrocarbons of carbonaceous chondrites and the identity of the interstellar molecular precursors involved are an objective of investigations into the origin of the solar system and perhaps even life on earth. We have combined the resources and experience of an astronomer and physicists doing laboratory simulations with those of a chemical expert in the analysis of meteoritic hydrocarbons, in a project that investigated the conversion of polycyclic aromatic hydrocarbons (PAHs) formed in stellar atmospheres into alkanes found in meteorites. Plasma hydrogenation has been found in the University of Alabama at Birmingham Astrophysics Laboratory to produce from the precursor PAH naphthalene, a new material having an IR absorption spectrum (Lee, W. and Wdowiak, T.J., Astrophys. J. 417, L49-L51, 1993) remarkably similar to that obtained at Arizona State University of the benzene-methanol extract of the Murchison meteorite (Cronin, J.R. and Pizzarello, S., Geochim. Cosmochim. Acta 54, 2859-2868, 1990). There are astrophysical and meteoritic arguments for PAH species from extra-solar sources being incorporated into the solar nebula, where plasma hydrogenation is highly plausible. Conversion of PAHs into alkanes could also have occurred in the interstellar medium. The synthesis of laboratory analogs of meteoritic hydrocarbons through plasma hydrogenation of PAH species is underway, as is chemical analysis of those analogs. The objective is to clarify this heretofore uninvestigated process and to understand its role during the origin of the solar system as a mechanism of production of hydrocarbon species now found in meteorites. Results have been obtained in the form of time-of-flight spectroscopy and chemical analysis of the lab analog prepared from naphthalene.  相似文献   

Discovery and rediscovery of Trojan asteroids     

Eric W. Elst 《Earth, Moon, and Planets》1995,71(3):275-277

During 1987–1994, observational campaigns with different telescopes at several observatories have been initiated by the author in order to discover new Trojans. The importance of Trojan asteroids comes from celestial mechanics, where they represent the physical solution of the famous Lagrange triangular problem. Their importance lies also in the fact, that they may have some relation with comets. Furthermore, the Trojan belt may be as large as the belt of asteroids. Moreover, recently families have been discovered between the already well known Trojans. Enough reasons to continue to search for these interesting objects.  相似文献