DMS and SO2 at Baring Head, New Zealand: Implications for the Yield of SO2 from DMS     

Warren J. de Bruyn  Mike Harvey  Jill M. Cainey  Eric S. Saltzman 《Journal of Atmospheric Chemistry》2002,41(2):189-209

Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO₂) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO₂ diurnalcycles, consistent with the photochemical production of SO₂ from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO₂ from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO₂ yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO₂ yield is lower in the range of 20–40%.  相似文献   

Melt loss and the preservation of granulite facies mineral assemblages   总被引：29，自引：3，他引：29  

R. W. White  R. Powell 《Journal of Metamorphic Geology》2002,20(7):621-632

The loss of a metamorphic fluid via the partitioning of H₂O into silicate melt at higher metamorphic grade implies that, in the absence of open system behaviour of melt, the amount of H₂O contained within rocks remains constant at temperatures above the solidus. Thus, granulite facies rocks, composed of predominantly anhydrous minerals and a hydrous silicate melt should undergo considerable retrogression to hydrous upper amphibolite facies assemblages on cooling as the melt crystallizes and releases its H₂O. The common occurrence of weakly retrogressed granulite facies assemblages is consistent with substantial melt loss from the majority of granulite facies rocks. Phase diagram modelling of the effects of melt loss in hypothetical aluminous and subaluminous metapelitic compositions shows that the amount of melt that has to be removed from a rock to preserve a granulite facies assemblage varies markedly with rock composition, the number of partial melt loss events and the P–T conditions at which melt loss occurs. In an aluminous metapelite, the removal of nearly all of the melt at temperatures above the breakdown of biotite is required for the preservation of the peak mineral assemblage. In contrast, the proportion of melt loss required to preserve peak assemblages in a subaluminous metapelite is close to half that required for the aluminous metapelite. Thus, if a given proportion of melt is removed from a sequence of metapelitic granulites of varying composition, the degree of preservation of the peak metamorphic assemblage may vary widely.  相似文献   

Paleoecology of a Middle Wisconsin Deposit from Southern California     

R. Scott Anderson  Mitchell J. Power  Susan J. Smith  Kathleen Springer  Eric Scott 《Quaternary Research》2002,58(3):310

Analysis of a buried deposit in the Diamond Valley of southern California has revealed well-preserved pollen, wood, and diatom remains. Accelerator mass spectrometry dates of 41,200±2100 and 41,490±1380 ¹⁴C yr B.P. place this deposit in marine isotope stage 3. Diatoms suggest a shallow lacustrine environment. Pollen data suggest that several plant communities were present near the site, with grassland, scrub, chaparral, forest, and riparian communities represented. Comparison with modern pollen suggests similarities with montane forests in the nearby San Bernardino and San Jacinto ranges, indicating vegetation lowering by at least 900 m elevation and temperatures 4°–5°C cooler than today. An increase in high-elevation conifer pollen documents climatic cooling near the profile top. Early-profile diatoms are typical of warm water with high alkalinity and conductivity, whereas later diatoms suggest a higher flow regime and input of cooler water into the system. We suggest that the sequence is part of the cooling phase of an interstadial Dansgaard–Oeschger cycle. Records of the middle Wisconsin period are rare in southern California, but the Diamond Valley site is similar to records from Tulare Lake in the San Joaquin Valley and the ODP Site 893A record from Santa Barbara Basin. It is probable that the Diamond Valley assemblage is a local expression of a vegetation type widespread in the ranges and basins of southwestern California during the middle Wisconsin.  相似文献   

Environmental response to a large, explosive rhyolite eruption: sedimentology of post-1.8 ka pumice-rich Taupo volcaniclastics in the Hawke''s Bay region, New Zealand     

B. Segschneider  C. A. Landis  V. Manville  J. D. L. White  C. J. N. Wilson 《Sedimentary Geology》2002,150(3-4):275-299

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Dennis Curry, 1912-2001     

Eric Robinson 《Proceedings of the Geologists' Association. Geologists' Association》2002,113(1):89-90

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Common-Reflection-Surface Stack for Converted Waves     

Bergler  Steffen  Duveneck  Eric  Höcht  German  Zhang  Yonghai  Hubral  Peter 《Studia Geophysica et Geodaetica》2002,46(2):165-175

The finite-offset (FO) common-reflection-surface (CRS) stack has been shown to be able to handle not only P-P or S-S but also arbitrarily converted reflections. It can provide different stack sections such as common-offset (CO), common-midpoint (CMP) and common-shot (CS) sections with significantly increased signal-to-noise ratio from the multi-coverage pre-stack seismic data in a data-driven way. It is our purpose in this paper to demonstrate the performance of the FO CRS stack on data involving converted waves in inhomogeneous layered media. In order to do this we apply the FO CRS stack for common-offset to a synthetic seismic data set involving P-P as well as P-S converted primary reflections. We show that the FO CRS stack yields convincing improvement of the image quality in the presence of noisy data and successfully extracts kinematic wavefield attributes useful for further analyses. The extracted emergence angle information is used to achieve a complete separation of the wavefield into its P-P and P-S wave components, given the FO CRS stacked horizontal and vertical component sections.  相似文献   

新形势下林区的就业机会与渠道     

Sara J.Scherr  Andy White  David Kaimowitz  王学全 《湿地科学与管理》2002,(4):33-38

我国实施“天然林保护工程”以来,林区人民积极转产分流,寻找新的就业门路和生计,为走出困境、改善生活做出了不懈的努力。为了进一步开阔视野,拓展思路,借鉴他国的经验,我们选刊了“国际森林趋势组织”的几篇关于寻找新的林区就业渠道和森林环境服务市场开发方面的研究文章,以期对我国的林业改革与建设有所启示。(注:这些文章已经“森林趋势组织”的执行主管Mivhael Jenkins先生同意译成中文在本刊刊登,本刊作了部分删节和改动。原文及参考文献请参阅森林趋势组织的网页:http://www. forest-trends. org)  相似文献   

The interpretation of reaction textures in Fe‐rich metapelitic granulites of the Musgrave Block,central Australia: constraints from mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3     

R. W. White  Roger Powell  G. L. Clarke 《Journal of Metamorphic Geology》2002,20(1):41-55

Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO₂ and Fe₂O₃ on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2.  相似文献   

Seismic evidence for deep low-velocity anomalies in the transition zone beneath West Antarctica   总被引：1，自引：0，他引：1  

Anne Sieminski  Eric Debayle  Jean-Jacques Lévêque 《Earth and Planetary Science Letters》2003,216(4):645-661

We present a three-dimensional (3D) SV-wave velocity model of the upper mantle beneath the Antarctic plate constrained by fundamental and higher mode Rayleigh waves recorded at regional distances. The good agreement between our results and previous surface wave studies in the uppermost 200 km of the mantle confirms that despite strong differences in data processing, modern surface wave tomographic techniques allow to produce consistent velocity models, even at regional scale. At greater depths the higher mode information present in our data set allows us to improve the resolution compared to previous regional surface wave studies in Antarctica that were all restricted to the analysis of the fundamental mode. This paper is therefore mostly devoted to the discussion of the deeper part of the model. Our seismic model displays broad domains of anomalously low seismic velocities in the asthenosphere. Moreover, we show that some of these broad, low-velocity regions can be more deeply rooted. The most remarkable new features of our model are vertical low-velocity structures extending from the asthenosphere down to the transition zone beneath the volcanic region of Marie Byrd Land, West Antarctica and a portion of the Pacific-Antarctic Ridge close to the Balleny Islands hotspot. A deep low-velocity anomaly may also exist beneath the Ross Sea hotspot. These vertical structures cannot be explained by vertical smearing of shallow seismic anomalies and synthetic tests show that they are compatible with a structure narrower than 200 km which would have been horizontally smoothed by the tomographic inversion. These deep low-velocity anomalies may favor the existence of several distinct mantle plumes, instead of a large single one, as the origin of volcanism in and around West Antarctica. These hypothetical deep plumes could feed large regions of low seismic velocities in the asthenosphere.  相似文献   

Data Assimilation (4D-VAR) for Shallow-Water Flow: The Case of the Chicoutimi River     

Eric Bélanger  Alain Vincent  Alexandre Fortin 《Visual Geosciences》2003,8(1):1-17

This is a web presentation of the work presented at the 10th Annual Conference of the CFD Society of Canada, “CFD 2002”, at the University of Windsor on June 9-11, 2002. This discussion paper presents the four-dimensional variational data assimilation (4D-VAR) technique as a tool to forecast floods. This discussion will be limited to hydrological forecast. We assume that the weather, here a large rainstorm, had already been forecasted by the meteorological services. In the 4D-VAR technique, we need to minimize, in the sense of Lagrange, a cost function which measures the difference between the forecast and the observations. The physical equations acts as a set of constraints. Here, the model is the shallow-water equations modified to include sediment transport. The minimum was found by using the steepest descent algorithm. This is made possible because the gradient of the cost function can be calculated analytically by using the adjoint equations of the model. To illustrate the 4D-VAR technique, the bypass of a simple theoretical dam as well as the more complex overflowing of the Chicoutimi River at the Chute-Garneau dam (during the 1996 flood) are investigated.  相似文献