Devitrite (Na2Ca3Si6O16)—structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses     

Volker Kahlenberg  Daniela Girtler  Erik Arroyabe  Reinhard Kaindl  Daniel M. Többens 《Mineralogy and Petrology》2010,100(1-2):1-9

Single crystals of devitrite (Na₂Ca₃Si₆O₁₆) were synthesized as pale-yellow transparent needle shaped crystals using a Na₂MoO₄-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K₂MoO₄-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-K_α radiation, 2θ_max.?=?25.34°, R_int?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) ų, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO₆-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations.  相似文献   

Transient twenty-first century changes in daily-scale temperature extremes in the United States     

Martin Scherer  Noah S. Diffenbaugh 《Climate Dynamics》2014,42(5-6):1383-1404

A key question for climate mitigation and adaptation decisions is how quickly significant changes in temperature extremes will emerge as greenhouse gas concentrations increase, and whether that emergence will be uniform between hot and cold extremes and across different geographic areas. We use a high-resolution, multi-member ensemble climate model experiment over the United States (U.S.) to investigate the transient response of the annual frequency, duration and magnitude of 8 daily-scale extreme temperature indices during the twenty-first century of the A1B emissions scenario. We evaluate the time of emergence of a permanent exceedance (PE) above the colder part of the historical (1980–2009) extremes distribution, and the time of emergence of a new norm (NN) centered on the historical maxima (for hot extremes) or minima (for cold extremes). We find that during the twenty-first century, hot extremes permanently exceed the historical distribution’s colder half over large areas of the U.S., and that the hot extremes distribution also becomes centered on or above the historical distribution’s maxima. The changes are particularly robust for the exceedance of the annual 95th percentile of daily maximum temperature over the West and the Northeast (with the earliest emergence of a PE by 2030 and of a NN by 2040), for warm days over the Southwest (with the earliest emergence of a PE by 2020 and of a NN by 2030), and tropical nights over the eastern U.S. (with the earliest emergence of a PE by 2020 and of a NN by 2030). Conversely, no widespread emergence of a PE or a NN is found for most cold extremes. Exceptions include frost day frequency (with a widespread emergence of a PE below the historical median frequency by 2030 and of a NN by 2040 over the western U.S.), and cold night frequency (with an emergence of a PE below the historical median frequency by 2040 and of a NN by 2060 in virtually the entire U.S.). Our analysis implies a transition over the next half century to a climate of recently unprecedented heat stress in many parts of the U.S., along with cold extremes that, although less frequent, remain at times as long and as severe as are found in the current climate.  相似文献   

A contribution to regional stratigraphic correlations of the Afro-Brazilian depression – The Dom João Stage (Brotas Group and equivalent units – Late Jurassic) in Northeastern Brazilian sedimentary basins     

Juliano Kuchle  Claiton Marlon dos Santos Scherer  Christian Correa Born  Renata dos Santos Alvarenga  Felipe Adegas 《Journal of South American Earth Sciences》2011,31(4):358-371

The Dom João Stage comprises an interval with variable thickness between 100 and 1200 m, composed of fluvial, eolian and lacustrine deposits of Late Jurassic age, based mainly on the lacustrine ostracod fauna (although the top deposits may extend into the Early Cretaceous). These deposits comprise the so-called Afro-Brazilian Depression, initially characterized as containing the Brotas Group of the Recôncavo Basin (which includes the Aliança and the Sergi Formations) and subsequently extended into the Tucano, Jatobá, Camamu, Almada, Sergipe, Alagoas and Araripe Basins in northeastern Brazil, encompassing the study area of this paper. The large occurrence area of the Dom João Stage gives rise to discussions about the depositional connectivity between the basins, and the real extension of sedimentation. In the first studies of this stratigraphic interval, the Dom João Stage was strictly associated with the rift phase, as an initial stage (decades of 1960–70), but subsequent analyses considered the Dom João as an intracratonic basin or pre-rift phase – without any relation to the active mechanics of a tectonic syn-rift phase (decades of 1980–2000). The present work developed an evolutionary stratigraphic and tectonic model, based on the characterization of depositional sequences, internal flooding surfaces, depositional systems arrangement and paleoflow directions. Several outcrops on the onshore basins were used to build composite sections of each basin, comprising facies, architectural elements, depositional systems, stratigraphic and lithostratigraphic frameworks, and paleocurrents. In addition to that, over a hundred onshore and offshore exploration wells were used (only 21 of which are showed) to map the depositional sequences and generate correlation sections. These show the characteristics and relations of the Dom João Stage in each studied basin, and they were also extended to the Gabon Basin. The results indicate that there were two main phases during the Dom João Stage, in which distinctive sedimentary environments were developed, reflecting depositional system arrangements, paleoflow directions were diverse, and continuous or compartmented basins were developed.  相似文献   

Towards a 4D topographic view of the Norwegian sea margin   总被引：1，自引：1，他引：0  

Morten Smelror  John Dehls  Jrg Ebbing  Eiliv Larsen  Erik R. Lundin   ystein Nordgulen  Per Terje Osmundsen  Odleiv Olesen  Dag Ottesen  Christophe Pascal  Thomas F. Redfield  Leif Rise 《Global and Planetary Change》2007,58(1-4):382

The present-day topography/bathymetry of the Norwegian mainland and passive margin is a product of complex interactions between large-scale tectonomagmatic and climatic processes that can be traced back in time to the Late Silurian Caledonian Orogeny. The isostatic balance of the crust and lithosphere was clearly influenced by orogenic thickening during the Caledonian Orogeny, but was soon affected by post-orogenic collapse including overprinting of the mountain root, and was subsequently affected by a number of discrete extensional events eventually leading to continental break-up in Early Eocene time. In the mid-Jurassic the land areas experienced deep erosion in the warm and humid climate, forming a regional paleic surface. Rift episodes in the Late Jurassic and Early Cretaceous, with differential uplift along major fault zones, led to more pronounced topographic contrasts during the Cretaceous, and thick sequences of clastic sediments accumulated in the subsiding basins on the shelf. Following renewed extension in the Late Cretaceous, a new paleic surface developed in the Paleocene. Following break-up the margin has largely subsided thermally, but several Cenozoic shortening events have generated positive contraction structures. On the western side of the on-shore drainage divide, deeper erosion took place along pre-existing weakness zones, creating the template of the present day valleys and fjords. In the Neogene the mainland and large portions of the Barents Sea were uplifted. It appears that this uplift permitted ice caps to nucleate and accumulate during the Late Pliocene northern hemisphere climatic deterioration. The Late Pliocene to Pleistocene glacial erosion caused huge sediment aprons to be shed on to the Norwegian Sea and Barents Sea margins. Upon removal of the ice load the landmass adjusted isostatically, and this still continues today.  相似文献   

Numerical determination of pressure-dependent effective thermal conductivity in Berea sandstone     

Mirko Siegert  Marcel Gurris  Claudia Finger  Erik H. Saenger 《Geophysical Prospecting》2022,70(1):152-172

In this paper, the methods of digital rock physics are applied to determine pressure-dependent effective thermal conductivity in rock samples. Simulations are performed with an in-house three-dimensional finite volume code. In the first step, four numerical models are derived from a given tomographic scan of Berea sandstone. Consequently, simulations of the thermal conductivity at ambient conditions are performed and validated with experimental data. In a second step, a new workflow for the determination of the pressure-dependent thermal conductivity in rock samples is elaborated, tested and calibrated. Results originating from the derived workflow show very good agreement with experimental data.  相似文献   

Spalling Experiments on Large Hard Rock Specimens     

Lars?JacobssonEmail author  Karin?Appelquist  Jan?Erik?Lindkvist 《Rock Mechanics and Rock Engineering》2015,48(4):1485-1503

Specimens of coarse-grained Äspö diorite were axially compressed to observe stress-induced spalling. The specimens had a novel design characterized by two manufactured large radius notches on opposite sides. The tangential stress occurring in the notches aimed to represent the tangential loading around a circular opening. Fracture stages were monitored by acoustic emission measurements. Rock chips were formed similar to those found in situ, which indicates a similar fracture process. Slabs were cut out from the specimens and impregnated using a fluorescent material to visualize the cracks. The cracks were subsequently examined by the naked eye and by means of microscopy images, from which fracture paths could be identified and related to different minerals and their crystallographic orientations. The microscopy analyses showed how the stress field and the microstructure interact. Parallel cracks were formed 2–4 mm below the surface, sub-parallel to the direction of the maximum principal stress. The crack initiation, the roles of minerals such as feldspar, biotite and quartz and their grain boundaries and crystallographic directions are thoroughly studied and discussed in this paper. Scale effects, which relate to the stress gradient and microstructure, are discussed.  相似文献   

The most frequent interfaces in olivine aggregates: the GBCD and its importance for grain boundary related processes     

Katharina?MarquardtEmail author  Gregory?S.?Rohrer  Luiz?Morales  Erik?Rybacki  Hauke?Marquardt  Brian?Lin 《Contributions to Mineralogy and Petrology》2015,170(4):40

Rocks consist of crystal grains separated by grain boundaries that impact the bulk rock properties. Recent studies on metals and ceramics showed that the grain boundary plane orientation is more significant for grain boundary properties than other characteristics such as the sigma value or disorientation (in the Earth’s science community more frequently termed misorientation). We determined the grain boundary character distribution (GBCD) of synthetic and natural polycrystalline olivine, the most abundant mineral of Earth’s upper mantle. We show that grain boundaries of olivine preferentially contain low index planes, in agreement with recent findings on other oxides (e.g. MgO, TiO₂, Al₂O₃ etc.). Furthermore, we find evidence for a preferred orientation relationship of 90° disorientations about the [001] direction forming tilt and twist grain boundaries, as well as a preference for the 60° disorientation about the [100] axis. Our data indicate that the GBCD, which is an intrinsic property of any mineral aggregate, is fundamental for understanding and predicting grain boundary related processes.  相似文献   

Recent progress in the operational forecasting of summer severe weather     

Paul Joe  Cliff Crozier  Norman Donaldson  Dave Etkin  Erik Brun  Steve Clodman 《大气与海洋》2013,51(2):249-302

Abstract

Summer severe weather (SSW) can strike suddenly and unexpectedly with disastrous consequences for human activity. Considerable progress has been made in the past ten years in the operational forecasting of SSW. Traditionally, SSW was defined to consist of tornadoes, strong winds, hail, lightning and heavy rain. Hazardous types of strong winds have recently been expanded to include microbursts, macrobursts and surfacing rear inflow jet damage behind mesoscale convective systems. Doppler radar was used to relate surface damage to the appropriate atmospheric phenomena, first diagnostically and then prognostically. This improvement in classification has fedback to and improved the forecast process. Concurrent progress has been made in the use of synoptic observations. The concept of helical wind profiles and improved knowledge of the role of dry mid‐level air has improved the forecasting of tornadoes and strong gusty winds. Moisture flux convergence, derived from surface measurements, shows great promise in identifying areas of storm initiation. Satellite imagery has been used to identify dynamical atmospheric boundaries. Numerical modelling of the interaction of environmental wind profiles and individual thunderstorms has greatly contributed to the understanding of SSW. Studies of spatial and temporal patterns of lightning, both specific cases and climatology, contribute to the forecasting of severe storms. Polarization radar results have shown progress in separating the signals of hail from those of rain and in the improved measurement of heavy rainfalls. Radar observation of clear air boundaries and their interactions show potential for the forecasting of thunderstorm initiation. Though not traditionally considered part of SSW, hurricanes that evolve into extra‐tropical storms share many of the same hazardous features. The progress in computing, communications and display technologies has also made substantial contributions to operational forecasting and to the dissemination of weather warnings.  相似文献   

The Euro-Atlantic Circulation Response to the Madden-Julian Oscillation Cycle of Tropical Heating: Coupled GCM Intervention Experiments     

Priyanka Yadav  David M. Straus  Erik T. Swenson 《大气与海洋》2013,51(3):161-181

Abstract

Intervention experiments using the Coupled Forecast System model, version 2 (CFSv2), have been performed in which various Madden-Julian Oscillation (MJO) evolutions were added to the model’s internally generated heating: Slow Repeated Cycles, Slow Single Cycle, Fast Repeated Cycles, and Fast Single Cycle. In each experiment, one of these specified MJO evolutions of tropical diabatic heating was added in multiple ensemble reforecasts of boreal winter (1 November to 31 March for 31 winters: 1980–2010). Since in each experiment, multiple re-forecasts were made with the identical heating evolution added, predictable component analysis is used to identify modes with the highest signal-to-noise ratio. Traditional MJO-phase analysis of total model heating (dominated by internally generated heating) shows that the MJO-related heating structure compares well with heating estimated from observed fast and slow episodes; however, the model heating is larger by a factor of two. The evolution of Euro-Atlantic circulation regimes indicates a clear response due to the added heating, with a robust increase in the frequency of occurrence of the negative phase of the North Atlantic Oscillation (NAO?) after the heating crosses into the Pacific and a somewhat less robust increase in the positive phase of the NAO (NAO+) following Indian Ocean heating. In the Fast Cycle experiments, the model response is somewhat muted compared with the Slow Cycle experiments. The Scandinavian Blocking regime becomes more frequent prior to the NAO? regime. The two leading modes in the predictable component analysis of 300?hPa height (Z300), synoptic scale feedback (DZ300), and planetary wave diabatic heating in all experiments form an oscillatory pair with high statistical significance. The oscillatory pair represents the cyclic response to the particular MJO signal (Fast or Slow, Single, or Repeated Cycles) in each case. The period is about 64 days for the Slow Cycle and 36 days for the Fast Cycle, consistent with the imposed periods. The time series of one of the leading modes of Z300 is highly anti-correlated with the frequency of occurrence of the NAO– in the Repeated Cycle experiments. A clear cycle involving the Z300 and DZ300 leading modes is identified.  相似文献   

Technology transfer by CDM projects     

Erik Haites  Maosheng Duan  Stephen Seres 《Climate Policy》2013,13(3):327-344

Abstract

Technology development and transfer is an important feature of both the United Nations Framework Convention on Climate Change (UNFCCC) and its Kyoto Protocol. Although the Clean Development Mechanism (CDM) does not have an explicit technology transfer mandate, it may contribute to technology transfer by financing emission reduction projects using technologies currently not available in the host countries. This article analyses the claims about technology transfer made by CDM project participants in their project design documents. Roughly one-third of all CDM projects, accounting for almost two-thirds of the annual emission reductions, involve technology transfer. Technology transfer varies widely across project types and is more common for larger projects and projects with foreign participants. Equipment transfer is more common for larger projects, while smaller projects involve transfers of both equipment and knowledge or of knowledge alone. Technology transfer does not appear to be closely related to country size or per-capita GDP, but a host country can influence the extent of technology transfer involved in its CDM projects.  相似文献