Mobile sediment in an urbanizing karst aquifer: implications for contaminant transport   总被引：1，自引：0，他引：1  

B. J. Mahler  L. Lynch  P. C. Bennett 《Environmental Geology》1999,39(1):25-38

 Here we investigate geochemical characteristics of sediment in different compartments of a karst aquifer and demonstrate that mobile sediments in a karst aquifer can exhibit a wide range of properties affecting their contaminant transport potential. Sediment samples were collected from surface streams, sinkholes, caves, wells, and springs of a karst aquifer (the Barton Springs portion of the Edwards (Balcones Fault Zone) Aquifer, Central Texas) and their mineralogy, grain-size distribution, organic carbon content, and specific surface area analyzed. Statistical analysis of the sediments separated the sampling sites into three distinct groups: (1) streambeds, sinkholes, and small springs; (2) wells; and (3) caves. Sediments from the primary discharge spring were a mix of these three groups. High organic carbon content and high specific surface area gives some sediments an increased potential to transport contaminants; the volume of these sediments is likely to increase with continued urbanization of the watershed. Received: 13 April 1998 · Accepted: 6 October 1998  相似文献   

Effects of the improper modeling of viscous damping on the first-mode and higher-mode dominated responses of base-isolated buildings     

Hamidreza Anajafi  Ricardo A. Medina  Erin Santini-Bell 《地震工程与结构动力学》2020,49(1):51-73

In many finite element platforms, a classical global damping matrix based on the elastic stiffness of the system (including isolators) is usually developed as part of the solution to the equations of motion of base-isolated buildings. The conducted analytical and numerical investigations illustrate that this approach can lead to the introduction of unintended damping to the first and higher vibration modes and the spurious suppression of the respective structural responses. A similar shortcoming might be observed even when a nonclassical damping model (ie, an assembly of the superstructure and isolation system damping sub-matrices) is used. For example, the use of Rayleigh damping approach to develop the superstructure damping sub-matrix can lead to the undesired addition of damping to the isolated mode arising from the mass-proportional component of the superstructure damping. On the other hand, the improper use of nonclassical stiffness-proportional damping (eg, determining the proportional damping coefficient, β_k , based on the first mode) can result in assigning significant damping to the higher-modes and the unintended mitigation of the higher-mode responses. Results show that a nonclassical stiffness-proportional model in which β_k is determined based on the second modal period of a base-isolated building can reasonably specify the intended damping to the higher modes without imparting undesirable damping to the first mode. The nonclassical stiffness-proportional damping can be introduced to the numerical model through explicit viscous damper elements attached between adjacent floors. In structural analysis software such as SAP2000®, the desired nonclassical damping can be also modeled through specifying damping solely to the superstructure material.  相似文献   

Acheulean artifact accumulation and early hominin land use,Garden Route Casino Road,Pinnacle Point,South Africa     

Erin Thompson 《Geoarchaeology》2009,24(4):402-428

An Early Stone Age Acheulean lithic assemblage collected along a 1.5‐km transect at the Garden Route Casino near Pinnacle Point, Mossel Bay, South Africa, was examined in order to assess the relative degree to which assemblage variability is impacted by post‐occupational processes and/or terrain. It was found that post‐occupational variables do vary across the study area, and they affect the positions of artifacts to different degrees. Terrain structure was determined to have minimal effect on artifact movement. Three analysis sections were identified as having artifacts that were likely close to their original positions and compositions. Future interpretations of differential land use can now be tempered with considerations of the post‐occupational processes that formed the recovered assemblage. © 2009 Wiley Periodicals, Inc.  相似文献   

Simulation of the subsurface mobility of carbon nanoparticles at the field scale     

Erin Cullen  Denis M. O’Carroll  Ernest K. Yanful  Brent Sleep 《Advances in water resources》2010

The production and use of nanomaterials will inevitably lead to their disposal in the natural environment. To assess the risk that these materials pose to human and ecosystem health an understanding of their mobility and ultimate fate is essential. To date, however, relatively little research has been conducted on the fate of nanoparticles in subsurface systems. In this study the subsurface mobility of two carbon nanoparticles: nano-fullerenes (nC₆₀) and multi-walled carbon nanotubes (MWCNTs) is assessed. A two-dimensional finite element model was used to simulate the movement of these nanoparticles under a range of hydrologic and geological conditions, including a heterogeneous permeability field. The numerical model is based on colloid filtration theory (CFT) with a maximum retention capacity term. For the conditions evaluated the carbon nanotubes are much more mobile than nC₆₀ due to the smaller collector efficiency associated with carbon nanotubes. However, the mobility of nC₆₀ increased significantly when a maximum retention capacity term was included in the model. Model results also demonstrate that, for the systems examined, nanoparticles were predicted to be less mobile in heterogeneous systems compared to the homogeneous systems with the same average hydraulic properties.  相似文献   

Multidegrees‐of‐freedom effective force testing: a feasibility study and robust stability assessment     

Narutoshi Nakata  Erin Krug 《地震工程与结构动力学》2013,42(13):1985-2002

This paper presents a feasibility study of multidegrees‐of‐freedom effective force testing (MDOF‐EFT). The study is intended to facilitate the development of a force feedback controller and investigation of performance as well as robustness of MDOF‐EFT. First, the dynamics of MDOF‐EFT systems are analytically investigated. Analytical transfer functions of the control plant, the valve‐to‐force relations, showed that the plant is dynamically coupled and the natural frequencies of test structures are the transmission zeros of the plant. Using a set of model parameters from a previous study, a case study that includes controller design, numerical simulations and robust stability assessment is performed. A decoupling loop shaping (DLS) controller consisting of a pseudo inverse of the plant and second‐order loop shaping controllers is adopted as the force feedback controller. It is shown that the DLS controller provides a stable control system while successfully decoupling the control loops and compensating the control‐structure interaction. Numerical simulations demonstrate that the DLS controller enables tracking of static and dynamic forces for multiple actuators. Robust stability of MDOF‐EFT with the DLS controller is assessed using Monte Carlo simulation. The stochastic simulation results show that the DLS controller is stable and robust, providing sufficient stability margins for uncertain models with maximum 50% errors in the estimated system parameters. This paper demonstrates that MDOF‐EFT is feasible with the DLS controller and can be implemented in experimental laboratories. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Generation of zonal flow by resonant Rossby-Haurwitz wave interactions     

J. Burzlaff  E. DeLoughry  P. Lynch 《地球物理与天体物理流体动力学》2013,107(2):165-177

Starting out with two interacting Rossby-Haurwitz waves, the generation of zonal flow is discussed. It is shown that zonal flow cannot be generated by first or second order interactions between two such waves, unless they are exchanging energy with a third wave within a resonant triad. The generation of zonal flow at second order through resonant triad interactions is subsequently established and studied.  相似文献   

Influences of Salinity and Light Availability on Abundance and Distribution of Tidal Freshwater and Oligohaline Submersed Aquatic Vegetation     

Erin C. Shields  Kenneth A. Moore  David B. Parrish 《Estuaries and Coasts》2012,35(2):515-526

Submersed aquatic vegetation (SAV) communities have undergone declines worldwide, exposing them to invasions from non-native species. Over the past decade, the invasive species Hydrilla verticillata has been documented in several tributaries of the lower Chesapeake Bay, Virginia. We used annual aerial mapping surveys from 1998 to 2007, integrated with spatial analyses of water quality data, to analyze the patterns and rates of change of a H. verticillata-dominated SAV community and relate them to varying salinity and light conditions. Periods of declining SAV coverage corresponded to periods where salinities exceeded 7 and early growing season (April to May) Secchi depths were <0.4 m. Increases were driven by the expansion of H. verticillata along with several other species into the upper estuary, where some areas experienced an 80% increase in cover. Field investigations revealed H. verticillata dominance to be limited to the upper estuary where total suspended solid concentrations during the early growing season were <15 mg l⁻¹ and salinity remained <3. The effect of poor early growing season water clarity on annual SAV growth highlights the importance of water quality during this critical life stage. Periods of low clarity combined with periodic salinity intrusions may limit the dominance of H. verticillata in these types of estuarine systems. This study shows the importance of the use of these types of biologically relevant episodic events to supplement seasonal habitat requirements and also provides evidence for the potential important role of invasive species in SAV community recovery.  相似文献   

Excess air during aquifer storage and recovery in an arid basin (Las Vegas Valley, USA)     

D. Kip Solomon  Erin Cole  Joseph F. Leising 《Hydrogeology Journal》2011,19(1):187-194

The Las Vegas Valley Water District in Nevada, USA, has operated an artificial recharge (AR) program since 1989. In summer 2001, observations of gas exsolving from tap water prompted a study that revealed total dissolved gas (TDG) pressures approaching 2?atm with a gas composition that it is predominantly air. Measurements of TDG pressure at well heads and in the distribution system indicated two potential mechanisms for elevated TDG pressures: (1) air entrainment during AR operations, and (2) temperature changes between the winter recharge season and the summer withdrawal season. Air entrainment during pumping was investigated by intentionally allowing the forebay (upstream reservoir) of a large pumping station to drawdown to the point of vortex formation. This resulted in up to a 0.7?atm increase in TDG pressure. In general, the solubility of gases in water decreases as the temperature increases. In the Las Vegas Valley, water that acquired a modest amount of dissolved gas during winter artificial recharge operations experienced an increase in dissolved gas pressure (0.04?atm/°C) as the water warmed in the subsurface. A combination of air entrainment during AR operations and its amplification by temperature increase after recharge can account for most of the observed amounts of excess gas at this site.  相似文献   

Biocalcification in the Eastern Oyster (<Emphasis Type="Italic">Crassostrea virginica)</Emphasis> in Relation to Long-term Trends in Chesapeake Bay pH     

George G. Waldbusser  Erin P. Voigt  Heather Bergschneider  Mark A. Green  Roger I. E. Newell 《Estuaries and Coasts》2011,34(2):221-231

Anthropogenic carbon dioxide (CO₂) emissions reduce pH of marine waters due to the absorption of atmospheric CO₂ and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed 23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures. Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the decrease in biocalcification.  相似文献   

Sulfide Oxidation across Diffuse Flow Zones of Hydrothermal Vents     

Amy Gartman  Mustafa Y��cel  Andrew S. Madison  David W. Chu  Shufen Ma  Christopher P. Janzen  Erin L. Becker  Roxanne A. Beinart  Peter R. Girguis  George W. Luther III 《Aquatic Geochemistry》2011,17(4-5):583-601

The sulfide (H₂S/HS^?) that is emitted from hydrothermal vents begins to oxidize abiotically with oxygen upon contact with ambient bottom water, but the reaction kinetics are slow. Here, using in situ voltammetry, we report detection of the intermediate sulfur oxidation products polysulfides [ $ {\text{S}}_{\text{x}}^{2 - } $ ] and thiosulfate [ $ {\text{S}}_{ 2} {\text{O}}_{ 3}^{ 2- } $ ], along with contextual data on sulfide, oxygen, and temperature. At Lau Basin in 2006, thiosulfate was identified in less than one percent of approximately 10,500 scans and no polysulfides were detected. Only five percent of 11,000 voltammetric scans taken at four vent sites at Lau Basin in May 2009 show either thiosulfate or polysulfides. These in situ data indicate that abiotic sulfide oxidation does not readily occur as H₂S contacts oxic bottom waters. Calculated abiotic potential sulfide oxidation rates are <10^?3 ??M/min and are consistent with slow oxidation and the observed lack of sulfur oxidation intermediates. It is known that the thermodynamics for the first electron transfer step for sulfide and oxygen during sulfide oxidation in these systems are unfavorable, and that the kinetics for two electron transfers are not rapid. Here, we suggest that different metal catalyzed and/or biotic reaction pathways can readily produce sulfur oxidation intermediates. Via shipboard high-pressure incubation experiments, we show that snails with chemosynthetic endosymbionts do release polysulfides and may be responsible for our field observations of polysulfides.  相似文献