Anatomically preserved plants in siderite concretions in the shale split of the Foord Seam: mineralogy, geochemistry, genesis (Upper Carboniferous, Canada)     

Erwin L. Zodrow  Christopher J. Cleal 《International Journal of Coal Geology》1999,41(4):248

A shale split in the well-studied Foord Seam (Upper Carboniferous), Stellarton Basin, Nova Scotia, provides a rare opportunity to study little known siderite concretions with anatomically preserved plants from a limnic basin. Siderite concretions occur throughout the split, commonly as sheet-like, inter-connected lepidodendrid logs, or less frequently as spherical masses; they are typically vuggy. A sample of 14 stratigraphically oriented concretions in the split shows that primary siderite varies from 45% to 80% (wt.%) due to selective replacement by 5% to 40% ferroan dolomite or ankerite in plant tissues. These two minerals show large Mg/Fe and Mg/Ca variability and are Fezoned. Clay content ranges from trace to 20%, and quartz from 5% to 10%. Partial cell-wall destruction by erosion and changeable oxic/anoxic conditions, prior to siderite permineralization, resulted in preservation mainly of the more resistant plant tissues. On average, carbon from siderite is isotopically heavier (+4.8±1.9 0/00) than that from ‘dolomite' (−7.2±1.1 0/00). The distribution of and the positive correlation between δ¹³C and δ¹⁸O probably reflects the two fractionation processes associated with methanogenesis and ‘dolomitization', respectively, in the genetic history of the siderite concretions in the split. Siderite concretions formed diagenetically early from bicarbonate under reducing conditions in a slightly alkaline freshwater environment that precluded calcite deposition.  相似文献   

Effect of hydrocarbon-contaminated fluctuating groundwater on magnetic properties of shallow sediments     

Nawrass N. Ameen  Nicole Klueglein  Erwin Appel  Eduard Petrovský  Andreas Kappler  Carsten Leven 《Studia Geophysica et Geodaetica》2014,58(3):442-460

We investigate magnetic phase (trans)formation in the presence of petroleum hydrocarbons and its relation to bacterial activity, in particular in the zone of remediation driven fluctuating water levels at a former military air base in the Czech Republic. In a previous study an increase of magnetite concentration from the groundwater table towards the top of the groundwater fluctuation zone (GWFZ) was reported, however with limited reliability as there was no control on small-scale effects. To recognize statistically significant magnetic signatures versus depth, we obtained multiple sediment cores from three locations in January 2011 and April 2012, penetrating the unsaturated zone, the GWFZ and the uppermost one meter below the groundwater level (～2.3 m depth at the time of sampling). Magnetic concentration variation versus depth was determined by measuring magnetic susceptibility (MS) and remanence parameters. Small-scale features were identified and eliminated by statistical processing of multiple cores. A trend of increasing MS values from the lowermost position of the groundwater table upward was verified and highest magnetic concentration was found at the top of the GWFZ. Magnetic mineralogy indicates that newly formed fine-grained magnetite in the single domain to small pseudo-single domain range is responsible for the MS enhancement confirming previous results. There is no correlation with the depth variation of hydrocarbon (HC) concentrations; however, total organic carbon is linked to MS and may represent a degradation product of HC that is bioavailable for microorganisms. Bacterial activity is likely responsible for magnetite formation as indicated by most probable number (MPN) results of iron-metabolizing bacteria. The comparison of our results with an earlier study conducted at the same site revealed that magnetic concentration clearly decreased since remediation was terminated in 2008, possibly due to dissolution of magnetite.  相似文献   

Unusual nickel mineralisation at Nullagine,Western Australia     

E. H. Nickel  J. A. Hallberg  R. Halligan 《Australian Journal of Earth Sciences》2013,60(1-2):61-71

Nickel mineralisation occurs in shears in Archaean serpentinised peridotite near Nullagine, Western Australia. The principal nickel minerals are millerite, polydymite and pecoraite, which occur chiefly as concentrations of nodular grains, mostly between 1 and 5 mm in diameter. The polydymite represents a replacement of millerite, and is in turn partly replaced by gaspéite. The pecoraite grains generally contain several percent chromium, and are frequently rimmed by millerite‐containing magnetite. A similar type of nodule consists of nullaginite (Ni₂(OH)₂CO₃). Other major minerals in the shears include various types of serpentine and magnesite, coarse chlorite, and apatite. The assemblage is cut by late veinlets of gaspéite, pecoraite, otwayite (Ni₂(OH)₂CO₃.H₂O), and nullaginite. Trace amounts of barite, cinnabar, parkerite, shandite, breithauptite, and nickeloan greenockite are also present.

The bulk of the mineralisation is attributed to the effects of hydrothermal and/or metasomatic activity along shears in the serpentine. Concretionary magnesite in some of the shears is believed to be the result of Tertiary weathering. The late veinlets of nickel minerals and the replacement of millerite and polydymite are attributed to supergene effects.  相似文献   

The end of the Ediacara biota: Extinction,biotic replacement,or Cheshire Cat?     

Marc Laflamme  Simon A.F. Darroch  Sarah M. Tweedt  Kevin J. Peterson  Douglas H. Erwin 《Gondwana Research》2013,23(2):558-573

The Ediacaran–Cambrian transition signals a drastic change in both diversity and ecosystem construction. The Ediacara biota (consisting of various metazoan stem lineages in addition to extinct eukaryotic clades) disappears, and is replaced by more familiar Cambrian and Paleozoic metazoan groups. Although metazoans are present in the Ediacaran, their ecological contribution is dwarfed by Ediacaran-type clades of uncertain phylogenetic affinities, while Ediacaran-type morphologies are virtually non-existent in younger assemblages. Three alternative hypotheses have been advanced to explain this dramatic change at, or near, the Ediacaran–Cambrian boundary: 1) mass extinction of most Ediacaran forms; 2) biotic replacement, with early Cambrian organisms eliminating Ediacaran forms; and 3) a Cheshire Cat model, with Ediacaran forms gradually disappearing from the fossil record (but not necessarily going extinct) as a result of the elimination of unique preservational settings, primarily microbial matgrounds, that dominated the Ediacaran. To evaluate these proposed explanations for the biotic changes observed at the Ediacaran–Cambrian transition, environmental drivers leading to global mass extinction are compared to biological factors such as predation and ecosystem engineering. We explore temporal and biogeographic distributions of Ediacaran taxa combined with evaluations of functional guild ranges throughout the Ediacaran. The paucity of temporally-resolved localities with diverse Ediacaran assemblages, combined with difficulties associated with differences in taphonomic regimes before, during, and after the transition hinders this evaluation. Nonetheless, the demonstration of geographic and niche range changes offers a novel means of assessing the downfall of Ediacara-type taxa at the hands of emerging metazoans, which we hypothesize to be most likely due to the indirect ecological impact metazoans had upon the Ediacarans. Ultimately, the combination of studies on ecosystem construction, biostratigraphy, and biogeography showcases the magnitude of the transition at the Ediacaran–Cambrian boundary.  相似文献   

Differential developmental toxicity of naphthoic acid isomers in medaka (Oryzias latipes) embryos   总被引：1，自引：0，他引：1  

Michael W. Carney  Kyle Erwin  Ron Hardman  Bonny Yuen  David C. Volz  David E. Hinton  Seth W. Kullman   《Marine pollution bulletin》2008,57(6-12):255

Polycyclic aromatic hydrocarbons (PAHs) are widespread persistent pollutants that readily undergo biotic and abiotic conversion to numerous transformation products in rivers, lakes and estuarine sediments. Here we characterize the developmental toxicity of four PAH transformation products each structural isomers of hydroxynaphthoic acid: 1H2NA, 2H1NA, 2H3NA, and 6H2NA. Medaka fish (Oryzias latipes) embryos and eleutheroembryos were used to determine toxicity. A 96-well micro-plate format was used to establish a robust, statistically significant platform for assessment of early life stages. Individual naphthoic acid isomers demonstrated a rank order of toxicity with 1H2NA > 2H1NA > 2H3NA > 6H2NA being more toxic. Abnormalities of circulatory system were most pronounced including pericardial edema and tube heart. To determine if HNA isomers were AhR ligands, spatial-temporal expression and activity of CYP1A was measured via in vivo EROD assessments. qPCR measurement of CYP1A induction proved different between isomers dosed at respective concentrations affecting 50% of exposed individuals (EC50s). In vitro, all ANH isomers transactivated mouse AhR using a medaka CYP1A promoter specific reporter assay. Circulatory abnormalities followed P450 induction and response was consistent with PAH toxicity. A 96-well micro-plates proved suitable as exposure chambers and provided statistically sound evaluations as well as efficient toxicity screens. Our results demonstrate the use of medaka embryos for toxicity analysis thereby achieving REACH objectives for the reduction of adult animal testing in toxicity evaluations.  相似文献   

In situ bioremediation of 1,2-dichloroethane under anaerobic conditions     

Mark Dyer  Erwin van Heiningen  Jan Gerritse 《Geotechnical and Geological Engineering》2000,18(4):313-334

Historic spillages of chlorinated hydrocarbons at a vinyl chloride plant in the Rotterdam–Botlek area in The Netherlands has lead to deep-seated pollution of the underlying aquifer. The principal pollutant is 1,2-dichloroethane (1,2-DCA). As a temporary measure, the contamination is being contained using a pump and treat system. In the long term, in-situ bioremediation has been proposed using a biologically active zone where pollutants would be dechlorinated by microorganisms that simultaneously degrade other carbon sources. In order to investigate the suitability of this new technology, a programme of laboratory tests was carried out. The laboratory programme involved a series of anaerobic soil column tests, where the selection and delivery of different carbon substrates that stimulated 1,2-DCA dechlorination were investigated. The soil columns were prepared using soil and groundwater samples from boreholes. Groundwater was flushed through the columns under anaerobic conditions. A comparison was made between the transformation of 1,2-DCA without a carbon substrate and in the presence of sugars (molasses) and alcohol (methanol) respectively. In addition, different modes of delivery were investigated. In the case of molasses, the material was injected into the column as a plug to simulate grout injection in the field, whereas methanol was delivered as a constant flow dissolved in the influent. Both carbon substrates resulted in the biotransformation of 1,2-DCA. However, fermentation of molasses produced secondary effects that led to a drop in pH and an excessive production of carbon dioxide, which temporarily blocked the flow of groundwater.  相似文献   

南海东沙东北部甲烷缺氧氧化作用的生物标志化合物及其碳同位素组成   总被引：5，自引：0，他引：5  

于晓果  韩喜球  李宏亮  金肖兵  龚建明  ErwinSUESS  黄永样  吴能友  苏新 《海洋学报》2008,30(3):77-84

南海东沙东北部碳酸盐岩和泥质沉积物中的生物标志化合物组合及其碳同位素组成分析表明,研究区内甲烷缺氧氧化作用(anaerobic oxidation of methane-AOM)发育.研究区内碳酸盐岩中含丰富的AOM标志化合物,2,6,11,15-四甲基十六烷(Crocetane-Cr.)、2,6,10,15,19-五甲基番茄烷(Pentamethylicosane-PMI)和2,6,10,15,19,23-六甲基二十四烷(Squalane-Sq角鲨烷)的13C亏损强烈(δ13C值介于-74.2‰~-119.0‰PDB之间),表明碳酸盐岩形成于AOM,同时反映该研究区曾发生过强烈、持续的富CH₄流体释放活动.柱状泥质沉积物中,AOM生物标志化合物在硫酸岩-甲烷过渡带(SMI-Sulfate-Methane Interface)边界附近相对丰度高,SMI之上样品中含量低,或未检出,表明现代环境在SMI附近有大量嗜甲烷微生物生长,使得深部上升的甲烷被大量消耗,很少有甲烷逸出海底.AOM生物标志化合物可用来指示SMI边界.不同站位、不同岩性AOM生物标志化合物组成(包括碳同位素组成)的差异反映了嗜甲烷古细菌组成的不同.  相似文献   

Geological setting, mining and reduction of mercury vapor contamination in the gold-silver district of Vetas-Calofornia （Santander, Colombia）     

Erwin Wolff Carreno Juan Manuel Pinzon Angel Rodolfo Contreras Moreno Christoph Bernardy 《《幕》》2005,28(4):252-256

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The ecological implications of a Yakutian mammoth's last meal   总被引：1，自引：0，他引：1  

Bas van Geel  Andr Aptroot  Claudia Baittinger  Hilary H. Birks  Ian D. Bull  Hugh B. Cross  Richard P. Evershed  Barbara Gravendeel  Erwin J.O. Kompanje  Peter Kuperus  Dick Mol  Klaas G.J. Nierop  Jan Peter Pals  Alexei N. Tikhonov  Guido van Reenen  Peter H. van Tienderen 《Quaternary Research》2008,69(3):361-376

Part of a large male woolly mammoth (Mammuthus primigenius) was preserved in permafrost in northern Yakutia. It was radiocarbon dated to ca. 18,500 ¹⁴C yr BP (ca. 22,500 cal yr BP). Dung from the lower intestine was subjected to a multiproxy array of microscopic, chemical, and molecular techniques to reconstruct the diet, the season of death, and the paleoenvironment. Pollen and plant macro-remains showed that grasses and sedges were the main food, with considerable amounts of dwarf willow twigs and a variety of herbs and mosses. Analyses of 110-bp fragments of the plastid rbcL gene amplified from DNA and of organic compounds supplemented the microscopic identifications. Fruit-bodies of dung-inhabiting Ascomycete fungi which develop after at least one week of exposure to air were found inside the intestine. Therefore the mammoth had eaten dung. It was probably mammoth dung as no bile acids were detected among the fecal biomarkers analysed. The plant assemblage and the presence of the first spring vessels of terminal tree-rings of dwarf willows indicated that the animal died in early spring. The mammoth lived in extensive cold treeless grassland vegetation interspersed with wetter, more productive meadows. The study demonstrated the paleoecological potential of several biochemical analytical techniques.  相似文献   

Remote Sensing of Three-dimensional Winds with Elastic Lidar: Explanation of Maximum Cross-correlation Method     

William T. Buttler  Cecilia Soriano  Jose M. Baldasano  George H. Nickel 《Boundary-Layer Meteorology》2001,101(3):305-327

Maximum cross-correlation provides a method toremotely de-ter-mine high-lyre-solved three-dimensional fields of horizontalwinds with e-las-tic li-darthrough-out large volumes of the planetaryboundary layer (PBL). This paperdetails the technique and shows comparisonsbetween elastic lidar winds, remotelysensed laser Doppler velocimeter (LDV) windprofiles, and radiosonde winds.Radiosonde wind data were acquired at Barcelona,Spain, during the BarcelonaAir-Quality Initiative (1992), and the LDVwind data were acquired at SunlandPark, New Mexico during the 1994 Border AreaAir-Quality Study. Comparisonsshow good agreement between the differentinstruments, and demonstrate the methoduseful for air pollution management at thelocal/regional scale. Elastic lidar windscould thus offer insight into aerosol andpollution transport within the PBL. Lidarwind fields might also be used to nudge orimprove initialization and evaluation ofatmospheric meteorological models.  相似文献