Analytical Procedures for the Measurement of Boron Isotope Compositions by Ion Microprobe in Meteorites and Mantle Rocks   总被引：3，自引：1，他引：3  

Marc Chaussidon  François Robert  Denis Mangin  Pascal Hanon  Estelle F. Rose 《Geostandards and Geoanalytical Research》1997,21(1):7-17

An analytical procedure has been developed to measure in situ the ¹¹ B/¹⁰ B ratio in terrestrial basaltic rocks and meteoritic chondrules having B concentration of less than 1 μg g^?1 using a small radius ims3f ion microprobe. The central difficulties for these measurements are (i) the removal of the trace amount of B contamination introduced in the sample during polishing, (ii) the precise calibration of instrumental mass fractionation of B isotopes and (iii) the low count rates of ¹⁰ B and ¹¹ B. Contamination experiments conducted with isotopically labelled B enriched in ¹⁰ B showed that ultrasonic cleaning in bi-distilled water (< 1 ng g^?1 B) and pre-sputtering of the analysed area decrease B contamination to the level of 0.01 μg g^?1. Analyses of isotope standards spanning a range of ¹¹ B/¹⁰ B between 3.93 and 4.20 showed that instrumental mass fractionation was constant within? during one session of analyses. Repeated analyses of a standard glass showed a reproducibility of instrumental mass fractionation between February 1991 and October 1996 of 1.3. Taking into account all sources of error, boron isotope measurements are accurate to within 5 for meteoritic samples having B contents in the range 0.1 to 1 μg g^?1. A slightly better accuracy of 1.5 can be achieved for basaltic glasses which can be sputtered with very intense primary beams.  相似文献   

Orbital imprint on Holocene palaeohydrological variations in west‐central Europe as reflected by lake‐level changes at Cerin (Jura Mountains,eastern France)     

Michel Magny  Gilles Bossuet  Pascale Ruffaldi  Aurélie Leroux  Jacques Mouthon 《第四纪科学杂志》2011,26(2):171-177

This paper presents a lake‐level record for the Holocene at Lake Cerin (Jura Mountains, eastern France). It is based on a range of sedimentological techniques validated in previous studies, with a combination of systematic lithostratigraphic investigations of the infillings accumulated in the lacustrine basin, and sediment analyses of two selected cores. The chronology is based on 10 radiocarbon dates and pollen stratigraphy. On a millennial scale, the Cerin lake‐level record shows three distinct successive phases characterised by higher lake‐level conditions until ca. 9000 cal. a BP, followed by a maximal lowering at ca. 9000–8500 cal. a BP, and a progressive rise until the present. This rise was punctuated by centennial‐scale fluctuations, with major events around 4000, 2800 and after 1500 cal. a BP. Considered on a multimillennial scale, the general pattern of palaeohydrological changes reconstructed at Cerin reflects the impact of orbitally driven summer insolation. This is in agreement with other regional and extra‐regional palaeoclimatic records, although every record shows peculiarities in timing and shape depending on the proxy used for reconstruction. In this general context, centennial to multicentennial oscillations appear to have been second‐order events in comparison with the major influence of the orbital factor. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Connection between micrometeorites and Wild 2 particles: From Antarctic snow to cometary ices     

E. Dobricǎ  C. Engrand  J. Duprat  M. Gounelle  H. Leroux  E. Quirico  J.‐N. Rouzaud 《Meteoritics & planetary science》2009,44(10):1643-1661

Abstract— We discuss the relationship between large cosmic dust that represents the main source of extraterrestrial matter presently accreted by the Earth and samples from comet 81P/Wild 2 returned by the Stardust mission in January 2006. Prior examinations of the Stardust samples have shown that Wild 2 cometary dust particles contain a large diversity of components, formed at various heliocentric distances. These analyses suggest large‐scale radial mixing mechanism(s) in the early solar nebula and the existence of a continuum between primitive asteroidal and cometary matter. The recent collection of CONCORDIA Antarctic micrometeorites recovered from ultra‐clean snow close to Dome C provides the most unbiased collection of large cosmic dust available for analyses in the laboratory. Many similarities can be found between Antarctic micrometeorites and Wild 2 samples, in terms of chemical, mineralogical, and isotopic compositions, and in the structure and composition of their carbonaceous matter. Cosmic dust in the form of CONCORDIA Antarctic micrometeorites and primitive IDPs are preferred samples to study the asteroid‐comet continuum.  相似文献   

Titanium in phengite: a geobarometer for high temperature eclogites   总被引：1，自引：1，他引：0  

Estelle Auzanneau  M. W. Schmidt  D. Vielzeuf  J. A. D Connolly 《Contributions to Mineralogy and Petrology》2010,159(1):1-24

Phengite chemistry has been investigated in experiments on a natural SiO₂–TiO₂-saturated greywacke and a natural SiO₂–TiO₂–Al₂SiO₅-saturated pelite, at 1.5–8.0 GPa and 800–1,050°C. High Ti-contents (0.3–3.7 wt %), Ti-enrichment with temperature, and a strong inverse correlation of Ti-content with pressure are the important features of both experimental series. The changes in composition with pressure result from the Tschermak substitution (Si + R²⁺ = Al^IV + Al^VI) coupled with the substitution: Al^VI + Si = Ti + Al^IV. The latter exchange is best described using the end-member Ti-phengite (KMgTi[Si₃Al]O₁₀(OH)₂, TiP). In the rutile-quartz/coesite saturated experiments, the aluminoceladonite component increases with pressure while the muscovite, paragonite and Ti-phengite components decrease. A thermodynamic model combining data obtained in this and previous experimental studies are derived to use the equilibrium MgCel + Rt = TiP + Cs/Qz as a thermobarometer in felsic and basic rocks. Phengite, rutile and quartz/coesite are common phases in HT-(U)HP metamorphic rocks, and are often preserved from regression by entrapment in zircon or garnet, thus providing an opportunity to determine the T–P conditions of crystallization of these rocks. Two applications on natural examples (Sulu belt and Kokchetav massif) are presented and discussed. This study demonstrates that Ti is a significant constituent of phengites that could have significant effects on phase relationships and melting rates with decreasing P or increasing T in the continental crust.  相似文献   

Reaction of OH Radicals with Acetone: Determination of the Branching Ratio for the Abstraction Pathway at 298 K and 1 Torr     

Estelle Turpin  Christa Fittschen  Alexandre Tomas  Pascal Devolder 《Journal of Atmospheric Chemistry》2003,46(1):1-13

We have determined the 2-oxo-propyl CH₃C(O)CH₂ (sometimes called 1-methylvinoxy or acetonyl) radical yield for the reaction of acetone with OH radical relative to the 2-oxo-propyl yields for the reactions of F- and Cl atoms with acetone using the Discharge Flow technique. The 2-oxo-propyl radical has been monitored by Laser Induced Fluorescence LIF at short reaction times in the systems: OH + acetone (R1), F + acetone (R2), and Cl + acetone (R3). From these measurements we have deduced the branching ratio for the 2-oxo-propyl radical formation in the title reaction to be in the range 0.8 R 1.  相似文献   

Shear modulus and damping ratio of grouted sand   总被引：2，自引：0，他引：2  

Estelle Delfosse-Ribay  Irini Djeran-Maigre  Richard Cabrillac  Daniel Gouvenot   《Soil Dynamics and Earthquake Engineering》2004,24(6):461-471

An experimental comparative study of three different grouted sands in terms of their effects on the values of two dynamic properties is presented. The dynamic properties studied are the shear modulus and the damping ratio which are determined with resonant column tests and cyclic triaxial tests. The behaviour of a pure Fontainebleau sand is compared with the behaviour of a Fontainebleau sand grouted with a silicate grout, a micro-fine cement grout and a mineral grout. The effects of the grouting treatment, the type of grout, the confining pressure, and the strains, on the shear modulus and the damping ratio are studied. The test results have shown that grouting improves the stiffness of the sand especially for small strains. Whatever the type of material, confining stress improves the shear modulus whereas it has a negligible effect on the damping ratio. When strain increases, the shear modulus decreases and the damping ratio increases.  相似文献   

Structure-from-motion,multi-view stereo photogrammetry applied to line-scan sediment core images     

Jacq  Kévin  Ployon  Estelle  Rapuc  William  Blanchet  Claire  Pignol  Cécile  Coquin  Didier  Fanget  Bernard 《Journal of Paleolimnology》2021,66(3):249-260

Journal of Paleolimnology - Images of sediment cores are often acquired to preserve primary color information, before such profiles are altered by subsequent sampling and destructive analyses. In...  相似文献   

Quota discarding and distributive justice: The case of the under-10 m fishing fleet in Sussex,England     

Tim Gray  R.C. Korda  Selina Stead  Estelle Jones 《Marine Policy》2011

Marine fish discarding has become a contentious environmental issue, but little attention has been paid to the moral grievances that sometimes underlie discarding practices. This article explores such a moral grievance through a case study of the under-10 m fishery in Sussex, England, where discarding of cod (Gadus morhua) has become a highly charged issue, skippers blaming it on unjust quota allocations. The moral claim to a greater quota allocation is analysed using two conceptions of distributive justice, entitlement and desert. The conclusion reached is that the under-10 m fleet’s entitlement arguments for a higher quota are weaker than their desert arguments, but that entitlement arguments weigh more heavily than desert arguments with government when it allocates quota.  相似文献   

Pervasive shock melting at >65 GPa in a Martian basalt,the shergottite Northwest Africa 14672     

R. H. Hewins  H. Leroux  D. Jacob  S. Pont  O. Beyssac  V. Malarewicz  J.-P. Lorand  P.-M. Zanetta  B. Zanda 《Meteoritics & planetary science》2024,59(4):640-669

Shergottites have provided abundant information on the volcanic and impact history of Mars. Northwest Africa (NWA) 14672 contributes to both of these aspects. It is a vesicular ophitic depleted olivine–phyric shergottite, with average plagioclase An₆₁Ab₃₉Or_0.2. It is highly ferroan, with pigeonite compositions En_49-25Fs_41-61Wo_10-14 like those of basaltic shergottites, for example, NWA 12335. Olivine (Fo_53-15) has discrete ferroan overgrowths, more ferroan when in contact with plagioclase than when enclosed by pyroxene. The pyroxene (a continuum of augite, subcalcic augite, and pigeonite) is patchy, with ragged “cores” enveloped or invaded by ferroan pyroxene. Magma mixing may be responsible for capture of olivine and formation of pyroxene mantles. The plagioclase is maskelynite-like in appearance, but the original laths were (congruently) melted and the melt partly crystallized as fine dendrites. Most of the 14% vesicles occur within plagioclase. Olivine, pyroxene, and ilmenite occur in part as fine aggregates crystallized after congruent melting with limited subsequent liquid mixing. There are two fine-grained melt components, barred plagioclase with interstitial Fe-bearing phases, and glass with olivine dendrites, derived by melting of mainly plagioclase and mainly pyroxene, respectively. Rare silica particles contain coesite and/or quartz, and silica glass. The rock has experienced >50% melting, compatible with peak pressure >~65 GPa. It is the most highly shocked shergottite so far, at shock stage S6/7. It may belong to the group of depleted shergottites ejected at ~1 Myr from Tooting Crater.  相似文献   

Characterization of regional and local scattering effects from small-aperture seismic array recordings     

Estelle?SchisseléEmail author  Stéphane?Gaffet  Yves?Cansi 《Journal of Seismology》2005,9(2):137-149

In 1998, four small-aperture arrays separated by 20 km have been deployed in the southern French Alps in order to record the natural seismicity during two consecutive months. One of the main objectives of this experiment was to characterize the heterogeneities that influence the wavefield propagation, by analysis of the coda characteristics recorded by each of the seismic arrays.The time-azimuth-velocity characteristics of the coda phases have been obtained using a high-resolution wavenumber decomposition method.A statistical analysis, using the coda characteristics of the whole data set (20 regional earthquakes) recorded by the four arrays has been performed and lead to the calculation of the density of scattered energy within the medium. Three regional heterogeneous areas (> 10 km) have been characterized, and are located in the N–NE, W and S directions from the four arrays. Scattered energy is also located at local distances (< 10 km) from the four arrays.The comparison of the waveforms recorded (i) with one of the array, for different groups of earthquakes, and (ii) with the four arrays, for one group of earthquakes, show that the geometrical configuration of the source–scattering area–recording site system can strongly influence the energetic distributions related to the secondary phases of the seismograms.In particular cases, we experimentally show that the interactions of the direct wavefield with the heterogeneous structures of the medium can be sufficiently energetic to induce secondary scattered phases that dominate the seismic motions recorded at a given site. In such case, these effects should be taken into account for the quantification of the expected ground motion recorded during an earthquake.  相似文献