Assessment of ERA5 and ERA-Interim in Reproducing Mean and Extreme Climates over West Africa     

Imoleayo Ezekiel GBODE  Toju Esther BABALOLA  Gulilat Tefera DIRO  Joseph Daniel INTSIFUL 《大气科学进展》2023,40(4):570-586

In situ data in West Africa are scarce, and reanalysis datasets could be an alternative source to alleviate the problem of data availability. Nevertheless, because of uncertainties in numerical prediction models and assimilation methods, among other things, existing reanalysis datasets can perform with various degrees of quality and accuracy. Therefore, a proper assessment of their shortcomings and strengths should be performed prior to their usage. In this study, we examine the performance of E...  相似文献   

Dehydroxylation mechanisms in Al/Fe dioctahedral phyllosilicates by quantum mechanical methods with cluster models     

Esther Molina-Montes  Alfonso Hernández-laguna 《Geochimica et cosmochimica acta》2008,72(16):3929-3938

Atomic models involving the dehydroxylation process of dioctahedral phyllosilicates without interlayer charge were used to calculate energies and explore the reaction paths of the possible mechanisms of this reaction at a quantum mechanical level. The geometrical features and electronic structure of a molecular cluster model of two edge-sharing octahedrally coordinated cations coupled to a ring of six silicate tetrahedra was evaluated by ab initio molecular orbital calculations with Hartree-Fock approximation. Two dehydroxylation mechanisms are considered. One mechanism involves two contiguous hydroxyl that are on an octahedron shared edge that joins a pair of octahedral cations. The other model considered involves OH loss from across an octahedral vacant. The substitution effect of Al³⁺ by Fe³⁺ in the octahedral sheet on the activation energy and structural transformations is compared by minimization of the critical points of the Potential Energy Surface (PES) for the reactant, transition state and product along the reaction path of the dehydroxylation process. The calculated energy differences and vibration frequencies are according to previous experimental results. The dehydroxylation mechanism involving OH across the octahedral hole, is less energetically favorable and is endothermic.  相似文献   

Geographers in the U.S. Government in Washington,DC, during World War II     

Chauncy D. Harris 《The Professional geographer》1997,49(2):245-256

Geographers in Washington, DC, during World War II and the agencies in which they worked are recalled through the naming of geographers engaged in wartime work during this seminal period in the development of the geography profession in the United States. The five agencies then employing the largest number of geographers were the Research and Analysis Branch of the Office of Strategic Services, the Topographic Branch of the Military Intelligence Division of the War Department, the Board of Economic Warfare (later the Foreign Economic Administration), the Board on Geographic Names, and the Office of the Geographer, Department of State. The impacts of this period on individual geographers, the professional organization of geographers, cartography, higher education, and the government are suggested.  相似文献   

Improving the performance of f–x prediction filtering at low signal-to-noise ratios     

P.E. Harris  R.E. White 《Geophysical Prospecting》1997,45(2):269-302

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Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods     

G. W. Harris  D. Klemp  T. Zenker  J. P. Burrows  B. Mathieu 《Journal of Atmospheric Chemistry》1992,15(3-4):315-326

Measurements of NO₂, HCHO, and H₂O₂ were made by the highly specific method of mid infra-red absorption spectroscopy using tunable diode lasers (TDLAS) during the 1988 Polarstern expedition. The TDLAS data are compared to those obtained during the cruise using less direct methods. Southern Hemisphere NO₂ levels suggest nett photochemical destruction of O₃ in the boundary layer. Northern Hemisphere HCHO averaged 0.47±0.2 ppbv; the HCHO measurements are used in a simple calculation to estimate OH noontime maxima of 3–6×10⁶ cm^-3.  相似文献   

Copper, lead, and zinc distribution in the sediments of the Fly River Delta and Torres Strait   总被引：1，自引：0，他引：1  

Elaine K. Baker  Peter T. Harris 《Marine pollution bulletin》1991,22(12):614-618

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Geochemistry of the Mesozoic regional basic dykes of western Dronning Maud Land,Antarctica     

Chris Harris  Brian R Watters  P Bruce Groenewald 《Contributions to Mineralogy and Petrology》1991,107(1):100-111

Regional dolerite dykes of Mesozoic age in western Dronning Maud Land are variable in both major and trace element composition and include picritic types (MgO>18 wt%). The range in incompatible element concentrations is considerable (e.g. Zr 40–478 ppm) and shows little correlation with MgO content. Both high-and low-Ti, Zr (HTZ and LTZ) magma types are present and there is a spread of compositions between these types. Major element oxide variations in dykes having MgO>10 wt% indicate that olivine and orthoyproxene fractionation occurred, presumably at an early high-pressure stage of magma evolution. Major element oxide variations in dykes having MgO<10 wt% indicate control by olivine and clinopyroxene. A minority of the more evolved dykes are compositionally similar to the nearby Kirwan basalts, but the majority cannot be related to the Kirwan basalts by any simple petrogenetic process as they contain higher concentrations of incompatible elements and have higher Mg-numbers. The HTZ Dronning Maud Land dolerites have incompatible trace element concentrations which are very similar to the HTZ basalt magma types of the Karoo of southern Africa with the exception of lower K and Rb in DML dolerites. The HTZ dolerites occur in the part of Dronning Maud Land which appears to have been tectonically stable since the Archaean and are not found to intrude the surrounding high-grade (about 1000 Ma) metamorphic rocks of the Sverdrup Group. These data provide qualified support for models which seek to relate spatially the HTZ Mesozoic basalt types of Gondwana to sources beneath stable Archaean cratons.  相似文献   

Carbonic fluid inclusions in South Indian granulites: evidence for entrapment during charnockite formation   总被引：1，自引：0，他引：1  

M. Santosh  D. H. Jackson  N. B. W. Harris  D. P. Mattey 《Contributions to Mineralogy and Petrology》1991,108(3):318-330

Field evidence and fluid inclusion studies on South Indian incipient charnockites suggest that charnockite formation occurred during a decompressional brittle regime following the ‘peak’ of metamorphism and regional deformation. The most abundant type of inclusions in quartz and garnet grains in these charnockites contain high-density carbonic fluids, although lower-density fluids occur in younger arrays of inclusions. Discrete fluid inclusion generations optically are observed to decrepitate over well-defined temperature intervals, and quantitative measurements of CO₂ abundance released from these inclusions by stepped thermal decrepitation show up to a four-fold increase (by volume) in the incipient charnockites relative to the adjacent gneisses from which they are derived. Studies based on optical thermometry, visual decrepitation and stepped-heating inclusion release together indicate that entrapment of carbonic fluids coincided with charnockite formation. We confirm that an influx of carbon dioxide-rich fluids is associated with the amphibolite-granulite transition, as recorded by the incipient charnockites, the remnants of which are commonly preserved as the earliest generation of high-density fluid inclusions.  相似文献   

A new multidimensional scaling technique based upon associations of triple objects—Pijk and its application to the analysis of geochemical data     

Guocheng Pan  D. P. Harris 《Mathematical Geosciences》1991,23(6):861-886

A new multidimensional scaling (MS) technique, referred to as the Pijk model, is formulated on the basis of associations among triple objects (samples or variables), instead of pairs of objects as used in the usual MS methods, such as factor analysis. The computational scheme provided for this method is the reduction of an original problem to a standard eigenvalue-eigenvector problem. The major goal of the technique is simplification and reduction of data structures and the rescaling of original objects into a new and reduced space, so that patterns and relations of the original objects can be conventiently examined in two-dimensional “factor” plots. The Pïjk method is illustrated and tested by using a set of geochemical data related to the epithermal gold and silver vein deposits in the Walker Lake quadrangle of Nevada and California. The characteristics of element associations suggested in the Pijk analysis are consistent with field observations. A preliminary comparison between the new method and the ordinary factor analysis also is made on the basis of the same data set. Results are encouraging in that analysis by the Pijk model captures triple-object associations that might be missed by the ordinary factor analysis which considers only pair-variable correlations  相似文献   

Methane emission measurements in urban areas in Eastern Germany     

Joanne H. Shorter  J. Barry Mcmanus  Charles E. Kolb  Eugene J. Allwine  Brian K. Lamb  Byard W. Mosher  Robert C. Harriss  Uwe Partchatka  Horst Fischer  Geoffrey W. Harris  Paul J. Crutzen  Hans-Josef Karbach 《Journal of Atmospheric Chemistry》1996,24(2):121-140

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.  相似文献