9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR     

Antonio Martínez Cortizas  Jenny K. Sjöström  Eleonor E. Ryberg  Malin E. Kylander  Joeri Kaal  Olalla López-Costas  Noemi Álvarez Fernández  Richard Bindler 《Boreas: An International Journal of Quaternary Research》2021,50(4):1161-1178

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   

Detailing the impact of the Storegga Tsunami at Montrose,Scotland     

Mark D. Bateman  Tim C. Kinnaird  Jon Hill  Robert A. Ashurst  Jenna Mohan  Rebecca B. I. Bateman  Ruth Robinson 《Boreas: An International Journal of Quaternary Research》2021,50(4):1059-1078

The Storegga tsunami, dated in Norway to 8150±30 cal. years BP, hit many countries bordering the North Sea. Run-ups of >30 m occurred and 1000s of kilometres of coast were impacted. Whilst recent modelling successfully generated a tsunami wave train, the wave heights and velocities, it under-estimated wave run-ups. Work presented here used luminescence to directly date the Storegga tsunami deposits at the type site of Maryton, Aberdeenshire in Scotland. It also undertook sedimentological characterization to establish provenance, and number and relative power of the tsunami waves. Tsunami model refinement used this to better understand coastal inundation. Luminescence ages successfully date Scottish Storegga tsunami deposits to 8100±250 years. Sedimentology showed that at Montrose, three tsunami waves came from the northeast or east, over-ran pre-existing marine sands and weathered igneous bedrock on the coastal plain. Incorporation of an inundation model predicts well a tsunami impacting on the Montrose Basin in terms of replicate direction and sediment size. However, under-estimation of run-up persisted requiring further consideration of palaeotopography and palaeo-near-shore bathymetry for it to agree with sedimentary evidence. Future model evolution incorporating this will be better able to inform on the hazard risk and potential impacts for future high-magnitude submarine generated tsunami events.  相似文献   

Late Pleistocene and Holocene Afromontane vegetation and headwater wetland dynamics within the Eastern Mau Forest,Kenya     

Esther N. Githumbi  Colin J. Courtney Mustaphi  Rob Marchant 《第四纪科学杂志》2021,36(2):239-254

The Mau Forest Complex is Kenya's largest fragment of Afromontane forest, providing critical ecosystem services, and has been subject to intense land use changes since colonial times. It forms the upper catchment of rivers that drain into major drainage networks, thus supporting the livelihoods of millions of Kenyans and providing important wildlife areas. We present the results of a sedimentological and palynological analysis of a Late Pleistocene–Holocene sediment record of Afromontane forest change from Nyabuiyabui wetland in the Eastern Mau Forest, a highland region that has received limited geological characterization and palaeoecological study. Sedimentology, pollen, charcoal, X-ray fluorescence and radiocarbon data record environmental and ecosystem change over the last ~16 000 cal a bp. The pollen record suggests Afromontane forests characterized the end of the Late Pleistocene to the Holocene with dominant taxa changing from Apodytes, Celtis, Dracaena, Hagenia and Podocarpus to Cordia, Croton, Ficus, Juniperus and Olea. The Late Holocene is characterized by a more open Afromontane forest with increased grass and herbaceous cover. Continuous Poaceae, Cyperaceae and Juncaceae vegetation currently cover the wetland and the water level has been decreasing over the recent past. Intensive agroforestry since the 1920s has reduced Afromontane forest cover as introduced taxa have increased (Pinus, Cupressus and Eucalyptus).  相似文献   

Lead contamination of small cetaceans in European waters--the use of stable isotopes for identifying the sources of lead exposure     

Caurant F  Aubail A  Lahaye V  Van Canneyt O  Rogan E  López A  Addink M  Churlaud C  Robert M  Bustamante P 《Marine environmental research》2006,62(2):131-148

Lead concentrations and isotopic composition have been measured in bone and teeth of small cetaceans belonging to three species (Delphinus delphis, Phocoena phocoena and Stenella coeruleoalba), to evaluate the toxicological risk and to determine sources of lead in the European waters. Lead concentrations, far lower than threshold value inducing toxic effects in human, were higher in teeth than in bones, but highly correlated between the two tissues (r=0.92, p<0.001). Large variations of 206Pb/207Pb values in bone tissue showed that cetaceans must be submitted to various atmospheric influences. No geographical differences appeared which is consistent with studies on their distribution indicating seasonal movements between Brittany waters and the Bay of Biscay. The negative correlation between 206Pb/207Pb ratios and age of the individuals reflected the decrease in the production of alkyl lead in Europe, i.e., the increasing use of unleaded gasoline.  相似文献   

Late Miocene evaporite geochemistry of Lorca and Fortuna basins (Eastern Betics,SE Spain): Evidence of restriction and continentalization     

Javier García-Veigas  Luis Gibert  Dioni I. Cendón  David Artiaga  Hugo Corbí  Jesús M. Soria  Tim K. Lowenstein  Enrique Sanz 《Basin Research》2020,32(5):916-948

The Lorca and Fortuna basins are two intramontane Neogene basins located in the eastern Betic Cordillera (SE Spain). During the Late Tortonian—Early Messinian, marine and continental evaporites precipitated in these basins as a consequence of increased marine restriction and isolation. Here we show a stratigraphic correlation between the evaporite records of these basins based on geochemical indicators. We use SO₄ isotope compositions and Sr isotopic ratios in gypsum, and halite Br contents to characterize these units and to identify the marine or continental source of the waters feeding the evaporite basins. In addition, we review the available chronological information used to date these evaporites in Lorca (La Serrata Fm), including a thick saline deposit, that we correlate with the First Evaporitic Group in Fortuna (Los Baños Fm). This correlation is also supported by micropalaeontological data, giving a Late Tortonian age for this sequence. The Second Evaporitic Group, (Chicamo Fm), and the Third Evaporitic Group (Rambla Salada Fm) developed only in Fortuna during the Messinian. According to the palaeogeographical scheme presented here, the evaporites of the Lorca and Fortuna basins were formed during the Late Tortonian—Early Messinian, close to the Betic Seaway closure. Sulphate isotope compositions and Sr isotopic ratios of the Ribera Gypsum Mb, at the base of the Rambla Salada Fm (Fortuna basin), match those of the Late Messinian selenite gypsum beds in San Miguel de Salinas, in the near Bajo Segura basin (40 km to the East), and other Messinian Salinity Crisis gypsum deposits in the Mediterranean. According to these geochemical indicators and the uncertainty of the chronology of this unit, the assignment of the Rambla Salada Fm to the MSC cannot be ruled out.  相似文献   

Copper Ore Quality Tracking in a Belt Conveyor System Using Simulation Tools     

Bardzinski  Piotr  Jurdziak  Leszek  Kawalec  Witold  Król  Robert 《Natural Resources Research》2020,29(2):1031-1040

Natural Resources Research - The ore quality at mining faces in the KGHM underground copper ore mines can be determined based on channel samples and block models built in the Datamine system....  相似文献   

Seismic‐stratigraphic constraints on the age of the Faroe Islands Basalt Group,Faroe–Shetland region,Northeast Atlantic Ocean     

Jana lavsdttir  Martyn S. Stoker  Lars O. Boldreel  Morten Sparre Andersen   luva R. Eidesgaard 《Basin Research》2019,31(5):841-865

Lower Palaeogene extrusive igneous rocks of the Faroe Islands Basalt Group (FIBG) dominate the Faroese continental margin, with flood basalts created at the time of breakup and separation from East Greenland extending eastwards into the Faroe‐Shetland Basin. This volcanic succession was emplaced in connection with the opening of the NE Atlantic; however, consensus on the age and duration of volcanism remains lacking. On the Faroe Islands, the FIBG comprises four main basaltic formations (the pre‐breakup Lopra and Beinisvørð formations, and the syn‐breakup Malinstindur and Enni formations) locally separated by thin intrabasaltic sedimentary and/or volcaniclastic units. Offshore, the distribution of these formations remains ambiguous. We examine the stratigraphic framework of these rocks on the Faroese continental margin combining onshore (published) outcrop information with offshore seismic‐reflection and well data. Our results indicate that on seismic‐reflection profiles, the FIBG can be informally divided into lower and upper seismic‐stratigraphic packages separated by the strongly reflective A‐horizon. The Lower FIBG comprises the Lopra and Beinisvørð formations; the upper FIBG includes the Malinstindur and Enni formations. The strongly reflecting A‐horizon is a consequence of the contrast in properties of the overlying Malinstindur and underlying Beinisvørð formations. Onshore, the A‐horizon is an erosional surface, locally cutting down into the Beinisvørð Formation; offshore, we have correlated the A‐horizon with the Flett unconformity, a highly incised, subaerial unconformity, within the juxtaposed and interbedded sedimentary fill of the Faroe‐Shetland Basin. We refer to this key regional boundary as the A‐horizon/Flett unconformity. The formation of this unconformity represents the transition from the pre‐breakup to the syn‐breakup phase of ocean margin development in the Faroe–Shetland region. We examine the wider implications of this correlation considering existing stratigraphic models for the FIBG, discussing potential sources of uncertainty in the correlation of the lower Palaeogene succession across the Faroe–Shetland region, and implications for the age and duration of the volcanism.  相似文献   

A method for checking the quality of geographic metadata based on ISO 19157     

Manuel Antonio Ureña-Cámara  Javier Lacasta  Francisco Javier Ariza-López 《International journal of geographical information science》2019,33(1):1-27

With recent advances in remote sensing, location-based services and other related technologies, the production of geospatial information has exponentially increased in the last decades. Furthermore, to facilitate discovery and efficient access to such information, spatial data infrastructures were promoted and standardized, with a consideration that metadata are essential to describing data and services. Standardization bodies such as the International Organization for Standardization have defined well-known metadata models such as ISO 19115. However, current metadata assets exhibit heterogeneous quality levels because they are created by different producers with different perspectives. To address quality-related concerns, several initiatives attempted to define a common framework and test the suitability of metadata through automatic controls. Nevertheless, these controls are focused on interoperability by testing the format of metadata and a set of controlled elements. In this paper, we propose a methodology of testing the quality of metadata by considering aspects other than interoperability. The proposal adapts ISO 19157 to the metadata case and has been applied to a corpus of the Spanish Spatial Data Infrastructure. The results demonstrate that our quality check helps determine different types of errors for all metadata elements and can be almost completely automated to enhance the significance of metadata.  相似文献   

Variations of young oceanic intraplate seismic energy released with relation to lithosphere age. Implications in the East Pacific Rise and its convergence with the Rivera subduction zone     

Pinzón  Nicolás  Vargas  Carlos A. 《Marine Geophysical Researches》2019,40(4):643-654

Marine Geophysical Research - We have estimated empirical relationships that associate the age of the Pacific oceanic lithosphere with the seismic energy released on both flanks of the East Pacific...  相似文献   

Synergetic efficiency of Lidar and WorldView-2 for 3D urban cartography in Northeast Mexico     

Fabiola D. Yépez Rincón  Diego F. Lozano García 《国际地球制图》2019,34(2):164-178

Three-dimensional urban cartography is needed for city changes’ assessment. The variety of studies using 3D calculations of urban elements grows each year. Building and vegetation volumes are necessary to assess and understand spatio-temporal urban changeable environments. However, there are technical questions as to which method can improve 3D urban cartographic accuracy. The innovative part of this current study is the creation of a six-band hybrid obtained from LIDAR and WorldView2 synergy. Two different enhancement algorithms demonstrated the most important spectral features for the urban development and vegetation classes. Results indicated an improvement in accuracy by up to 21.3%, according to the Kappa coefficient. Both infra-red band and intensity band were the most significant, according to the principal components analysis. The synergy delimited classes and polygons, as well as the direct display of information regarding heights of elements and improving the extraction of roads, buildings and vegetation classes.  相似文献