Melt inclusion constraints on volatile systematics and degassing history of the 2014–2015 Holuhraun eruption,Iceland     

E.?BaliEmail authorView author&#;s OrcID profile  M.?E.?Hartley  S.?A.?Halldórsson  G.?H.?Gudfinnsson  S.?Jakobsson 《Contributions to Mineralogy and Petrology》2018,173(2):9

The mass of volatiles emitted during volcanic eruptions is often estimated by comparing the volatile contents of undegassed melt inclusions, trapped in crystals at an early stage of magmatic evolution, with that of the degassed matrix glass. Here we present detailed characterisation of magmatic volatiles (H₂O, CO₂, S, Fl and Cl) of crystal-hosted melt and fluid inclusions from the 2014–2015 Holuhraun eruption of the Bárðarbunga volcanic system, Iceland. Based on the ratios of magmatic volatiles to similarly incompatible trace elements, the undegassed primary volatile contents of the Holuhraun parental melt are estimated at 1500–1700 ppm CO₂, 0.13–0.16 wt% H₂O, 60–80 ppm Cl, 130–240 ppm F and 500–800 ppm S. High-density fluid inclusions indicate onset of crystallisation at pressures?≥?0.4 GPa (~?12 km depth) promoting deep degassing of CO₂. Prior to the onset of degassing, the melt CO₂ content may have reached 3000–4000 ppm, with the total magmatic CO₂ budget estimated at  23–55 Mt. SO₂ release commenced at 0.12 GPa (~?3.6 km depth), eventually leading to entrapment of SO₂ vapour in low-density fluid inclusions. We calculate the syn-eruptive volatile release as 22.2 Mt of magmatic H₂O, 5.9–7.7 Mt CO₂, and 11.3 Mt of SO₂ over the course of the eruption; F and Cl release were insignificant. Melt inclusion constraints on syn-eruptive volatile release are similar to estimates made during in situ field monitoring, with the exception of H₂O, where field measurements may be heavily biased by the incorporation of meteoric water.  相似文献   

Melt inclusion constraints on petrogenesis of the 2014–2015 Holuhraun eruption,Iceland     

Margaret?E.?HartleyEmail authorView author&#;s OrcID profile  Enik??Bali  John?Maclennan  David?A.?Neave  S?mundur?A.?Halldórsson 《Contributions to Mineralogy and Petrology》2018,173(2):10

The 2014–2015 Holuhraun eruption, on the Bárðarbunga volcanic system in central Iceland, was one of the best-monitored basaltic fissure eruptions that has ever occurred, and presents a unique opportunity to link petrological and geochemical data with geophysical observations during a major rifting episode. We present major and trace element analyses of melt inclusions and matrix glasses from a suite of ten samples collected over the course of the Holuhraun eruption. The diversity of trace element ratios such as La/Yb in Holuhraun melt inclusions reveals that the magma evolved via concurrent mixing and crystallization of diverse primary melts in the mid-crust. Using olivine–plagioclase–augite–melt (OPAM) barometry, we calculate that the Holuhraun carrier melt equilibrated at 2.1?±?0.7 kbar (7.5?±?2.5 km), which is in agreement with the depths of earthquakes (6?±?1 km) between Bárðarbunga central volcano and the eruption site in the days preceding eruption onset. Using the same approach, melt inclusions equilibrated at pressures between 0.5 and 8.0 kbar, with the most probable pressure being 3.2 kbar. Diffusion chronometry reveals minimum residence timescales of 1–12 days for melt inclusion-bearing macrocrysts in the Holuhraun carrier melt. By combining timescales of diffusive dehydration of melt inclusions with the calculated pressure of H₂O saturation for the Holuhraun magma, we calculate indicative magma ascent rates of 0.12–0.29 m s^?1. Our petrological and geochemical data are consistent with lateral magma transport from Bárðarbunga volcano to the eruption site in a shallow- to mid-crustal dyke, as has been suggested on the basis of seismic and geodetic datasets. This result is a significant step forward in reconciling petrological and geophysical interpretations of magma transport during volcano-tectonic episodes, and provides a critical framework for the interpretation of premonitory seismic and geodetic data in volcanically active regions.  相似文献   

The stability of hydrous phases beyond antigorite breakdown for a magnetite-bearing natural serpentinite between 6.5 and 11 GPa     

J.?MauriceEmail author  N.?Bolfan-Casanova  J.?A.?Padrón-Navarta  G.?Manthilake  T.?Hammouda  J.?M.?Hénot  D.?Andrault 《Contributions to Mineralogy and Petrology》2018,173(10):86

Phase relations for a natural serpentinite containing 5 wt% of magnetite have been investigated using a multi-anvil apparatus between 6.5 and 11 GPa and 400–850 °C. Post-antigorite hydrous phase assemblages comprise the dense hydrous magnesium silicates (DHMSs) phase A (11.3 wt% H₂O) and the aluminous phase E (Al-PhE, 11.9 wt% H₂O). In addition, a ferromagnesian hydrous silicate (11.1 wt% H₂O) identified as balangeroite (Mg,Fe)₄₂Si₁₆O₅₄(OH)₄₀, typically described in low pressure natural serpentinite, was found coexisting with Al-PhE between 650 and 700 °C at 8 GPa. In the natural antigorite system, phase E stability is extended to lower pressures (8 GPa) than previously reported in simple chemical systems. The reaction Al-phase E?=?garnet?+?olivine?+?H₂O is constrained between 750 and 800 °C between 8 and 11 GPa as the terminal boundary between hydrous mineral assemblages and nominally anhydrous assemblages, hence restricting water transfer into the deep mantle to the coldest slabs. The water storage capacity of the assemblage Al-PhE?+?enstatite (high-clinoenstatite)?+?olivine, relevant for realistic hydrated slab composition along a relatively cold temperature path is estimated to be ca. 2 wt% H₂O. Attempts to mass balance run products emphasizes the role of magnetite in phase equilibria, and suggests the importance of ferric iron in the stabilization of hydrous phases such as balangeroite and aluminous phase E.  相似文献   

Salinization and Deterioration of Groundwater Quality by Nitrate and Fluoride in the Chittur Block,Palakkad, Kerala     

E. Shaji  J.J. Gómez-Alday  S. Hussein  T. R. Deepu  Y. Anilkumar 《Journal of the Geological Society of India》2018,92(3):337-345

Chittur block represents a mid-land region of Palakkad district, Kerala and the block differs from the rest of the blocks in its climate and availability of groundwater. About 75% of the people depend on agriculture for their livelihood. Results showed that groundwater salinity levels (up to 1,963 mg/L TDS),fluoride (up to 6.3 mg/L) and nitrate (up to 141 mg/L) contents have increased significantly in tandem with the increase in groundwater abstraction. Before human intervention the chemical weathering of gneisses and granites was the main process impinging on the chemical signature of groundwater. The initial chemical equilibrium conditions change with increasing groundwater withdrawal rates and fertilizer input, in a milieu of lower natural groundwater recharge. The appearance of higher levels of bicarbonate, linked to denitrification processes, and the decrease in calcium, due to calcite precipitation, can lead to increased content of sodium and fluoride in groundwater. In this scenario the use of groundwater resources for human consumption and agriculture represents a public health risk if water management actions do not change the trend in water use in the near future. The potential loss of fertile soil by groundwater salinization must also be considered when planning sustainable policies in a region with over dependence on groundwater resources.  相似文献   

Ancient Forests in European drylands: Holocene palaeoecological record of Mazarrón,south-eastern Spain     

José S. Carrión  Elena Fierro  Milagros Ros  Manuel Munuera  Santiago Fernández  Juan Ochando  Gabriela Amorós  Francisca Navarro  Tomás Rodríguez-Estrella  Saúl Manzano  Penélope González-Sampériz  Ana Moreno 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(4):512-525

This paper presents a new Holocene palaeoecological record from coastal south-eastern Spain, a region characterised by high plant species diversity, varied physiography, high risk of desertification, and a history of human pressure on the landscape that stretches to antiquity. The pollen sequence shows four main vegetation phases: the first characterised by mixed forests of Pinus and evergreen Quercus accompanied by broad-leaved mesophilous trees, and a diversity of Mediterranean scrub; the second phase is characterised by mesophytic decline and expansion of Artemisia; a third, mid-Holocene phase of thermo-mesophytic maxima with prevalence of forested landscapes; and, finally, the progressive opening of the landscape with sparse pines, halo-xerophytic grasslands and sclerophyllous brushwood. The current treeless situation of south-eastern Spain is a relatively recent feature resulting from a dramatic change in the ecological structure of the regional landscapes. This paper stresses the continued vulnerability of these arid systems in the face of a changing climate. This sequence adds to previous palaeobotanical records (pollen and charcoal) and archaeological reports to suggest that deforestation started earlier in low-elevation areas and river basins than in the inland mountains and platforms, a factor that appears in connection to human exploitation of the natural environment.  相似文献   

Illumina sequencing for the identification of filamentous bulking and foaming bacteria in industrial activated sludge plants     

T. Dunkel  E. L. de León Gallegos  C. Bock  A. Lange  D. Hoffmann  J. Boenigk  M. Denecke 《International Journal of Environmental Science and Technology》2018,15(6):1139-1158

In this study, Illumina sequencing was used for the identification of bulking and foaming bacteria in industrial wastewater treatment plants. The reliable identification of bulking and foaming bacteria represents the first step in developing effective and specific control strategies to avoid disturbances in activated sludge systems. Illumina sequencing revealed 432 16S rRNA operational taxonomic units, representing phylotypes and including 21 bulking and foaming bacteria in the two investigated industrial wastewater treatment plants. Foaming represents the most severe problem in the cascade biology system. Up to 22.5% of all sequencing reads are bulking and foaming bacteria, including Chryseobacterium, Candidatus Microthrix parvicella and Gordonia sp. as the dominant bulking and foaming bacteria which are known for foam formation. Moreover, Illumina sequencing revealed an increase in Candidatus Microthrix parvicella and Gordonia sp. reads from activated sludge to foam and scum samples, indicating a preferred flotation and/or growth advantages in the foam and scum layers. Analyses of the taxonomic assignment and distribution showed that the phylum Actinobacteria is the most dominant phylum, underlining the key role of Actinobacteria in bulking and foaming. Multivariate data analysis was applied, revealing that the dominant bulking and foaming bacteria are positively correlated with the sludge age and influent flow and negatively correlated with the dissolved oxygen level and the temperature. In terms of developing a specific control strategy, the positive linear relationships to the fatty acid and surfactant sludge loadings are highlighted and the removal of lipid compounds from the wastewater influent could avoid an overgrowth of bulking and foaming bacteria.  相似文献   

Emissions from mechanically biologically treated waste landfills at field scale     

A. López  M. García  A. L. Esteban-García  M. Cuartas  A. Molleda  A. Lobo 《International Journal of Environmental Science and Technology》2018,15(6):1285-1300

Modern waste management tends towards greater sustainability in landfilling, with the implementation of strategies such as the pretreatment of solid waste. This work assesses the behaviour of rejects from a refining stage of mechanically biologically treated municipal solid waste at the landfill. The main results of 18 months’ monitoring of an experimental pilot cell with waste from a full-scale plant are presented. This first stage is expected to be the most problematic period for this type of waste. The evolution of the temperature and the composition of leachate and gas at various points within the cell are included. During the first weeks, pollutant concentrations in the leachate exceeded the reference ranges in the literature, coinciding with a rapid onset of methanogenic conditions. However, there was a quick wash, reducing concentrations to below one-third of the initial values before the first year. pH values influenced concentrations of some pollutants such as copper. These results indicate that, right from the beginning of disposal, such facilities should be prepared to treat a high pollution load in the leachate and install the gas emissions control elements due to the rapid onset of methanogenesis.  相似文献   

Records of organochlorine pesticides in soils and sediments on the southwest of Buenos Aires Province,Argentina     

Norma Tombesi  Karla Pozo  Andrés Arias  Mónica Alvarez  Petra Pribylova  Ondrej Audy  Jana Klánová 《Environmental Earth Sciences》2018,77(11):403

The present study fills a gap in the knowledge in regards to the occurrence of banned pesticides at both coastal and inland locations at the Southwest Buenos Aires region, Argentina. Superficial sediment and soil samples were collected from different sites along the Bahia Blanca Estuary and surrounding sites to assess the concentration levels and spatial distribution of 12 selected organochlorine pesticides (OCs); 13 spatial locations including inland and shore-coast were sampled to evaluate occurrence and concentration levels of hexachlorocyclohexanes α-HCH, β-HCH, δ-HCH, γ-HCH, dichlorodiphenyltrichloroethane and its degradation products (DDXs: p,p′-DDT, o,p′-DDT, p,p′-DDE, o,p′-DDE, p,p′-DDD, o,p′-DDD) and the polychlorobenzenes PeCB (pentachlorobenzene) and HCB (hexachlorobenzene). After cleaning and extractions steps, samples were analyzed by means of gas chromatography/mass spectrometry. ∑OCs (sum of all studied compounds) ranged between 0.206 and 1040 ng g^?1 dw (mean?=?82.4 and SD?=?277 ng g^?1 dw). Total HCHs (sum of α-HCH, β-HCH, γ-HCH and δ-HCH) ranged from 0.0858 to 0.876 ng g^?1 dw (mean?=?0.43 and SD?=?0.23 ng g^?1 dw), DDXs (sum of p,p′and o,p′ isomers) from 0.080 to 1040 ng g^?1 dw (mean?=?81.3 and SD?=?277 ng g^?1 dw). Lower concentrations were found for PeCB (mean?=?0.095 and SD 0.17 ng g^?1 dw) and HCB (mean?=?0.56 and SD 1.7 ng g^?1 dw). Principal component analysis (PCA) permitted the extraction of underlying information about common factors, providing an overview of the distribution of pesticides and allowing the characterization of sites in regards to the major pesticide signature.  相似文献   

Temporal and spatial dynamics in aquatic macroinvertebrate communities along a small urban stream     

Tamás Bozóki  Eszter Ágnes Krasznai-Kun  András Csercsa  Gábor Várbíró  Pál Boda 《Environmental Earth Sciences》2018,77(15):559

Urbanization is a current and increasing threat to biodiversity. The effects of urbanization on the functional and taxonomic composition of macroinvertebrate assemblages were investigated in two seasons along a small urban stream. Species composition was determined by the rate of urbanization; however, response of species richness could not be evidenced. Relative abundance of the sensitive macroinvertebrate groups (EPT%) was negatively related to urbanization. Almost all feeding groups showed a sharp decline in the number of specimens along the increase of urbanization. The study supports the view that urbanization has a negative effect on the biological quality of a stream, yet, this obvious impact can be overridden by different measures such as modification in streambed morphology. The altered conditions and new circumstances in urban environments lead to the creation of novel ecosystems, inhabited by macroinvertebrate communities with species richness approaching that of low impacted sites. However, species composition of these communities could be basically different from that of the natural ones.  相似文献   

Editorial to the topical collection in Environmental Earth Sciences “Stone in the architectural heritage: from quarry to monuments—environment,exploitation, properties and durability”     

Siegfried Siegesmund  Luís Sousa  Rubén Alfonso López-Doncel 《Environmental Earth Sciences》2018,77(21):730

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