Analytical Developments in Secondary Ion Mass Spectrometry 2003     

Etienne Deloule  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2005,29(1):37-40

This annual review of secondary ion mass spectrometry (SIMS) highlights significant progress in the application of the technology for the following areas: U-Pb geochronology (notably in the fields of reference material zircons), sources of uncertainty during analysis and secondary ion yields. Major publications introduced a new zircon reference sample and dealt with an intercomparison study of a suite of established calibrators, some of which have been shown to have certain limitations. Another publication claimed that the principal uncertainty in U-Pb dating is related to variations in the Pb and U relative emission yields over a complete analytical session. 2003 saw the introduction of an automated particle identification procedure applied to the analysis of a chondritic meteorite, as well as new geometries of SIMS hardware (NanoSIMS) and techniques (time-of-flight SIMS). NanoSIMS allows a two to three order of magnitude reduction in sampling volume as a result of a reduced beam diameter, and time-of-flight SIMS allows the study of sample surfaces, and can provide data for elements concurrently.  相似文献   

Water penetration through fractured rocks: Test of a tridimensional percolation description     

Stephan Wilke  Etienne Guyon  Ghislain de Marsily 《Mathematical Geosciences》1985,17(1):17-27

  相似文献   

Development of a high resolution runoff routing model, calibration and application to assess runoff from the LMD GCM   总被引：3，自引：0，他引：3  

Agns Ducharne  Catherine Golaz  Etienne Leblois  Katia Laval  Jan Polcher  Emmanuel Ledoux  Ghislain de Marsily 《Journal of Hydrology》2003,280(1-4):207-228

Large-scale runoff routing models (RRMs) are important as a validation tool for GCMs, and to close the hydrological cycle in fully-coupled climate models. The model RiTHM was developed to simulate the discharge of large rivers from the total runoff simulated by the LMD GCM. It uses a 1024×800 grid, nested in the 64×50 grid of the LMD GCM. The runoff simulated in a GCM grid cell is uniformly distributed over the underlying cells, where a series of two reservoirs accounts for the delay related to infiltration through the unsaturated zone and aquifers. The resulting riverflow is routed assuming pure translation along the drainage network, extracted with a GIS from a 5 min DEM. The transfer time from a cell to the outlet depends on topography, and on a basin-wide parameter, the time of concentration. RiTHM was calibrated in 11 river basins, using a realistic runoff forcing (computed by the land surface model SECHIBA from reanalyzed meteorological forcing). This led to a very satisfactory reproduction of observed hydrographs. The main problems were related to hydraulic processes neglected in RiTHM (reservoirs, diversion of riverflow because of flooding or irrigation). These results helped to validate SECHIBA, except for its snow processes, shown to be too simple. With the same parameters, RiTHM was also forced with runoff from the LMD GCM. This induced an important degradation of the simulated hydrographs, regarding both volume and timing. It was largely explained by errors in precipitation, and more generally climate, in the GCM. The direct calibration of RiTHM under the GCM-runoff forcing markedly improved the timing of simulated discharge, which could be interesting for land–atmosphere–ocean coupling. This work demonstrated that the usefulness of RRMs for GCMs strongly depends on their adequate calibration.  相似文献   

Geodynamic significance of the Raspas Metamorphic Complex (SW Ecuador): geochemical and isotopic constraints     

Delphine Bosch  Piercarlo Gabriele  Henriette Lapierre  Jean-Louis Malfere  Etienne Jaillard   《Tectonophysics》2002,345(1-4)

The Raspas Metamorphic Complex of southwestern Ecuador is regarded as the southernmost remnant of oceanic and continental terranes accreted in the latest Jurassic–Early Cretaceous. It consists of variably metamorphosed rock types. (1) Mafic and ultramafic rocks metamorphosed under high-pressure (HP) conditions (eclogite facies) show oceanic plateau affinities with flat REE chondrite-normalized patterns, Nd_{150 Ma} ranging from +4.6 to 9.8 and initial Pb isotopic ratios intermediate between MORB and OIB. (2) Sedimentary rocks metamorphosed under eclogitic conditions exhibit LREE enriched patterns, strong negative Eu anomalies, Rb, Nb, U, Th, Pb enrichments, low Nd_{150 Ma} values (from −6.4 to −9.5), and high initial ⁸⁷Sr/⁸⁶Sr and ^206,207,208Pb/²⁰⁴Pb isotopic ratios suggesting they were originally sediments derived from the erosion of an old continental crust. (3) Epidote-bearing amphibolites show N-MORB affinities with LREE depleted patterns, LILE, Zr, Hf and Th depletion, high Nd_{150 Ma} (>+10) and low initial Pb isotopic ratios.The present-day well defined internal structure of the Raspas Metamorphic Complex seems to be inconsistent with the formerly proposed interpretation of a “tectonic mélange”. The association of oceanic plateau rocks and continent-derived sediments both metamorphosed in HP conditions suggests that the thin edge of the oceanic plateau first entered the subduction zone and dragged sediments downward of the accretionary wedge along the Wadatti–Benioff zone. Subsequently, when its thickest part arrived into the subduction zone, the oceanic plateau jammed the subduction processes, due to its high buoyancy.In Ecuador and Colombia, the latest Jurassic–Early Cretaceous suture involves HP oceanic plateau rocks and N-MORB rocks metamorphosed under lower grades, suggesting a composite or polyphase nature for the latest Jurassic–Early Cretaceous accretionary event.  相似文献   

Late Holocene local vegetation dynamics in the marsh of Gravgaz(southwest Turkey)     

Marleen Vermoere  Thijs Van Thuyne  Simon Six  Leo Vanhecke  Marc Waelkens  Etienne Paulissen  Erik Smets 《Journal of Paleolimnology》2002,27(4):429-451

Late Holocene local vegetation succession is reconstructed in twodifferent sites in a small-scale open marsh ecosystem in southwest Turkey.This is done by comparison of the fossil local pollen assemblage zones in twocores with the local pollen data of 40 surface samples from the marsh. Thepollen data are supplemented with sedimentological and archaeological data. Theinsertion of the mean pollen data of the local pollen zones as passive samplesinto the canonical correspondence analysis triplot of the modern samples allowsus to detect modern analogues for the fossil pollen zones. From this numericalcomparative approach it is concluded that the marsh area was relatively dryuntil ca 2500 BP. After 2500 BP the area shifts towards a wet area dominated bySparganium and/or Typha angustifolia. A diversification of the marsh vegetationstarts at ca 2400/2300 BP. The area around one core site seems to have beensituated in an area with slowly flowing source water, whereas the other coresite is likely to have been characterised by damp conditions. The steadilyincreasing dryness of the marsh area starts after ca 680 BP. The drying upappears to be associated with recent agricultural and grazing pressure.  相似文献   

Experimental study on the flow around two tandem cylinders with unequal diameters     

Yangyang Gao  Stephane Etienne  Xikun Wang  Soon Keat Tan 《中国海洋大学学报(英文版)》2014,13(5):761-770

In this paper, flow around two circular cylinders in tandem arrangement with unequal diameters has been investigated using the particle image velocimetry technique (PIV) in a water channel. The upstream to downstream diameter ratio was kept constant at d/D = 2/3, the centre-to-centre distance was varied from 1.2D to 5D and the Reynolds number was varied from 1200 to 4800. The flow characteristics were analyzed through ensemble-averaged patterns of velocity, vorticity, normalized Reynolds stress contours and streamlines. Based on ensemble-averaged and instantaneous flow fields, different flow patterns, including single-wake-shedding at small spacing ratio, bi-stable flow behavior (alternating behavior of reattachment and vortex shedding) at intermediate spacing ratio and co-shedding pattern at large spacing ratio were observed. The effects of Reynolds number and the centre-to-centre spacing ratio on flow patterns and turbulent characteristics were also investigated. It was found that the diameter ratio appears to have a certain effect on the flow patterns at intermediate spacing ratios, where the reattachment of shear layer depends on the lateral width of the wake flow in the lee of the upstream cylinder. Extensive discussion on the distributions of Reynolds stress and turbulent kinetic energy was presented.  相似文献   

V oxidation state in Fe–Ti oxides by high-energy resolution fluorescence-detected X-ray absorption spectroscopy     

Amélie Bordage  Etienne Balan  Johan P. R. de Villiers  Robert Cromarty  Amélie Juhin  Claire Carvallo  Georges Calas  P. V. Sunder Raju  Pieter Glatzel 《Physics and Chemistry of Minerals》2011,38(6):449-458

The oxidation state of vanadium in natural and synthetic Fe–Ti oxides is determined using high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS). Eleven natural magnetite-bearing samples from a borehole of the Main Magnetite Layer of the Bushveld Complex (South Africa), five synthetic Fe oxide samples, and three natural hematite-bearing samples from Dharwar supergroup (India) are investigated. V K edge spectra were recorded on the ID26 beamline at the European Synchrotron Radiation Facility (Grenoble, France), and the pre-edge features were used to determine the local environment and oxidation state of vanadium. In the case of the magnetite samples (natural and synthetic), we show that vanadium is incorporated in the octahedral site of the spinel structure under two oxidation states: +III and +IV. The variations of the pre-edge area are interpreted as various proportions in V³⁺ and V⁴⁺ (between 9.5 and 16.3% of V⁴⁺), V³⁺ being the main oxidation state. In particular, the variations of the V⁴⁺/V³⁺ ratio along the profile of the Main Magnetite Layer seem to follow the crystallization sequence of the layer. In the case of the hematite samples from India, the pre-edge features indicate that vanadium is substituted to Fe and mainly incorporated as V⁴⁺ (between 40 and 72% of V⁴⁺). We also demonstrate the potentiality of HERFD-XAS for mineralogical studies, since it can filter out the unwanted fluorescence and give better resolved spectra than conventional XAS.  相似文献   

“Stones from the dangerous winds”: reef platform mega-clasts in the tropical Pacific Islands     

James P. Terry  Samuel Etienne 《Natural Hazards》2011,56(3):567-569

Tsunamis and intense tropical storms compete as viable mechanisms for catastrophic marine inundations of coastlines, and so interpretation of deposits laid down by palaeo-events is often problematic. Here, examples are presented from the tropical South Pacific Islands to demonstrate how indigenous knowledge may provide vital clues supporting sedimentological investigation and thereby helping to explain the origin of giant boulders emplaced on top of coral reef platforms.  相似文献   

Deciphering the weathering processes using environmental mineralogy and geochemistry: Towards an integrated model of laterite and podzol genesis in the Upper Amazon Basin     

Emmanuel Fritsch  Etienne Balan  Nadia Régina Do Nascimento  Thierry Allard  Marion Bardy  Guilherme Bueno  Sylvie Derenne  Adolpho José Melfi  Georges Calas 《Comptes Rendus Geoscience》2011,343(2-3):188-198

This article reports major results from collaborative research between France and Brazil on soil and water systems, carried out in the Upper Amazon Basin. It reveals the weathering processes acting in the partly inundated, low elevation plateaus of the Basin, mostly covered by evergreen forest. Our findings are based on geochemical data and mineral spectroscopy that probe the crystal chemistry of Fe and Al in mineral phases (mainly kaolinite, Al- and Fe-(hydr)oxides) of tropical soils (laterites). These techniques reveal crystal alterations in mineral populations of different ages and changes of metal speciation associated with mineral or organic phases. These results provide an integrated model of soil formation and changes (from laterites to podzols) in distinct hydrological compartments of the Amazon landscapes and under altered water regimes.  相似文献   

Editorial     

Eric Pawson  Etienne Nel 《New Zealand geographer》2011,67(1):1-1

  相似文献