Elemental and isotopic (Si and O) tracing of glass alteration mechanisms     

Nathalie Valle  Jérôme Sterpenich  Etienne Deloule 《Geochimica et cosmochimica acta》2010,74(12):3412-18706

To better understand glass alteration mechanisms, especially alteration layers formation, leaching experiments of a borosilicate glass (SON68) doped with a different rare earth element (La, Ce, or Nd) with solutions rich in ²⁹Si and ¹⁸O were carried out. The coupled analyses of glass, alteration products, and solution led to a complete elemental and isotopic (²⁹Si and ¹⁸O) budget. They revealed different behaviours of elements that depend not only on their structural role in the glass, but also on their affinity for alteration products (gel, phyllosilicates, phosphates). However, analyses of both glass and solution are not sufficient to describe the real exchanges occurring between glass and solution. The use of ²⁹Si and ¹⁸O tracers gives new insights on the formation of alteration layers. During alteration the phyllosilicates records the isotopic variations of the leaching solution. Their isotopic signatures highlight a mechanism of dissolution/precipitation, which implies equilibrium between the secondary phases and the solution. On the other hand the gel isotopic signature, that is intermediate between the glass and the solution, substantiates the hypothesis that the gel is formed by hydrolysis/condensation reactions. This mechanism can thus explain the influence of the gel formation conditions (alteration conditions, solution saturation) on the structure (reorganisation) and texture (porosity) of this layer and on its protective effect. These hydrolysis/condensation reactions are also certainly involved in the aluminosilicate glass alteration and in the formation of palagonite.  相似文献   

First-principles calculation of H/D isotopic fractionation between hydrous minerals and water     

Merlin Méheut  Michele Lazzeri  Etienne Balan  Francesco Mauri 《Geochimica et cosmochimica acta》2010,74(14):3874-3882

Hydrogen fractionation laws between selected hydrous minerals (brucite, kaolinite, lizardite, and gibbsite) and perfect water gas have been computed from first-principles quantum-mechanical calculations. The β-factor of each phase was calculated using the harmonic phonon dispersion curves obtained within density functional theory. All the fractionation laws show the same shape, with a minimum between 200 °C (brucite) and 500 °C (gibbsite). At low temperatures, the mineral/liquid water fractionation laws have been obtained using the experimental gas/liquid water fractionation laws. The resulting fractionation laws systematically overestimate measurements by 15‰ at low temperatures to 8‰ at ≈400 °C. Based on this general agreement, all calculated laws were empirically corrected with reference to brucite/water data. These considerations suggest that the experimental or natural calibrations by Xu and Zheng (1999) and Horita et al. (2002) (brucite/water), Gilg and Sheppard (1996) (kaolinite/water), Wenner and Taylor (1973) (lizardite/water), and in some extents Vitali et al. (2001) (gibbsite/water) are representative of equilibrium fractionations. Besides, internal isotopic fractionation of hydrogen between inner-surface and inner hydroxyl groups has been computed for kaolinite and lizardite. The obtained fractionation is large, of opposite sign for the two systems (respectively, −23‰ and +63‰ at 25 °C) and is linear in T^-2. Internal fractionation of hydrogen in TO phyllosilicates might thus be used in geothermometry.  相似文献   

Society Awards 2011     

Etienne Nel 《New Zealand geographer》2012,68(1):67-67

  相似文献   

Precision spacecraft navigation using a low-cost GPS receiver   总被引：1，自引：1，他引：0  

Oliver Montenbruck  Paul Swatschina  Markus Markgraf  Stefano Santandrea  Joris Naudet  Etienne Tilmans 《GPS Solutions》2012,16(4):519-529

Within the PROBA-2 microsatellite mission, a miniaturized single-frequency GPS receiver based on commercial-off-the-shelf (COTS) technology is employed for onboard navigation and timing. A rapid electronic fuse protects against destructive single-event latch-ups (SEL) and enables a quasi-continuous receiver operation despite the inherent sensitivity to space radiation. While limited to single-frequency C/A-code tracking with a narrow-band frontend, the receiver is able to provide precision navigation services through processing of raw GPS measurements on ground as well as a built-in real-time navigation system. In both cases, ionospheric path delays are eliminated through a combination of L1 pseudorange and carrier phase measurements, which also offers a factor-of-two noise reduction relative to code-only processing. By comparison with satellite laser ranging (SLR) measurements, a 0.3-m (3D rms) accuracy is demonstrated for the PROBA-2 reduced dynamic orbit determinations using post-processed GPS orbit and clock products. Furthermore, the experimental onboard navigation system is shown to provide real-time position information with a 3D rms accuracy of about 1?m, which notably outperforms the specification of the Standard Positioning Service (SPS). In view of their lower hardware complexity, mass budget and power requirements as well as the reduced interference susceptibility, legacy C/A-code receivers can thus provide an attractive alternative to dual-frequency receivers even for demanding navigation applications in low Earth orbit.  相似文献   

The solar radiation incident at the top of the atmospheres of Uranus and Neptune     

Etienne Van Hemelrijck 《Earth, Moon, and Planets》1988,40(2):149-164

The latitudinal and seasonal variation of the direct solar radiation incident at the top of the atmosphere of Uranus and Neptune has been recalculated by use of updated values for the period of axial rotation and the oblateness. Values for the solar radiation are given in Watt per square meter instead of the unit used in earlier papers (calories per square centimeter per planetary day). The solar radiation averaged over a season and a year as a function of planetocentric latitude has also been reviewed. In addition, attention is made to the ratio of the solar radiation incident on an oblate planet to that incident on a spherical planet.  相似文献   

Devensian glacigenic sedimentation and landscape evolution in the Cardigan area of southwest Wales     

Michael J. Hambrey  Jeremy R. Davies  Neil F. Glasser  Richard A. Waters  Julian A. Dowdeswell  Philip R. Wilby  David Wilson  James L. Etienne 《第四纪科学杂志》2001,16(5):455-482

The depositional processes associated with late Devensian ice in areas bordering the Irish Sea basin have been the subject of considerable debate. Among the key areas around the Irish Sea, southwest Wales occupies a particularly crucial position because it is here that ice flowing from the north impinged upon the coast orthogonally and encroached inland. Two main hypotheses have emerged concerning deglaciation of the Irish Sea basin. The traditional hypothesis holds that sedimentation was ice‐marginal or subglacial, whereas an alternative hypothesis that emerged in the 1980s argued that sedimentation was glaciomarine. Southwest Wales is well‐placed to contribute to this debate. However, few detailed sedimentological studies, linked to topography, have been made previously in order to reconstruct glacial environments in this area. In this paper, evidence is presented from four boreholes drilled recently in the Cardigan area, combined with data from coastal and inland exposures in the lower Teifi valley and adjacent areas. A complex history of glaciation has emerged: (i) subglacial drainage channel formation in pre‐Devensian time, (ii) deposition of iron‐cemented breccias and conglomerates possibly during the last interglacial (or in the early/mid‐Devensian interstadial), (iii) late Devensian ice advance across the region, during which a glaciolacustrine sequence over 75 m thick accumulated, within a glacial lake known as Llyn Teifi, (iv) a second high‐level glaciolacustrine succession formed near Llandudoch, (v) outside the Teifi valley, ice‐marginal, subglacial and glaciofluvial sediments were also laid down, providing a near‐continuous cover of drift throughout the area. Glacial advance was characterized by reworking, deformation and sometimes erosion of the underlying sediments. The glaciomarine hypothesis is thus rejected for southwest Wales. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Surface-rupturing history of the Bree fault scarp, Roer Valley graben: Evidence for six events since the late Pleistocene     

Kris Vanneste  Koen Verbeeck  Thierry Camelbeeck  Etienne Paulissen  Mustapha Meghraoui  François Renardy  Denis Jongmans  Manfred Frechen 《Journal of Seismology》2001,5(3):329-359

Since 1996 paleoseismological investigations have been used to develop the surface- rupturing history of the Bree fault scarp, the morphologically best-defined segment of the southwestern border fault of the Roer Valley graben in northeastern Belgium. The first studies determined that the escarpment is associated with a surface fault, and they exposed evidence for three surface displacements since about 40 ka BP. The most recent eventprobably occurred between 1000 and 1350 yr cal BP. Geophysical and trenching studies at a new site near the southeastern end of the fault scarp reconfirmed the coincidence of the frontal escarpment with a shallow normal fault, which displaces the Middle Pleistocene `Main Terrace' of the Maas River, as well as overlying coversands of Saalian to late Weichselian age. Different amounts of displacement shown by the two youngest coversand units indicate two discrete faulting events, but primary evidence for the coseismic nature of these events is sparse. Radiocarbon and optically stimulated luminescence dating constrainthe age of these events to the Holocene and between 14.0 ± 2.3 ka BP and 15.8 ± 2.9 ka BP, respectively. In addition, four older surface-rupturing events are inferred from the presence of four wedge-shaped units of reworked Main Terrace deposits that are interbedded with coversand units in the hanging wall of the trench and in shallow boreholes. These wedges are interpreted as colluvial wedges, produced by accelerated slope processes in response torejuvenation of the fault scarp, most probably in a periglacial environment. Luminescence dating indicates that five out of a total of six identified faulting events are younger than 136.6 ± 17.6 ka. The antepenultimate event was the largest faulting event, associated with a total fault displacement in excess of 1 m. Thus, the newly investigated trench site represents the longest and most complete record of surface rupturing recovered so far along the Bree fault scarp. This study also demonstrates the viability of the paleoseismological approach to identify past large earthquakes in areas of present-day moderate to low seismic activity.  相似文献   

汉诺坝幔源单斜辉石巨晶氢同位素组成的离子探针分析:微尺度不均一性   总被引：3，自引：0，他引：3  

夏群科  潘尤杰  陈道公  DELOULE Etienne  支霞臣  程昊  吴元保 《岩石学报》2001,17(1):7-10

运用离子探针技术测定了河北汉诺坝新生代玄武岩中3个单斜辉石巨晶的氢同位素组成,结果显示同一颗粒内部表现出微尺度的不均一性,2mm范围内δD的变化达到60‰。δD和氢含量之间不存在同步的变化,巨晶内部的化学成分均一,因此我们认为巨晶的氢同位素不均一性继承自母岩浆。母岩浆的氢同位素变化可能是去气过程中气相与熔体之间的分馏引起的。单斜辉石巨晶形成后很短的时间内即被寄主岩浆带至地表并经历了快速淬火。  相似文献   

Tourism as a local development strategy in South Africa   总被引：1，自引：0，他引：1  

Tony Binns  & Etienne Nel 《The Geographical journal》2002,168(3):235-247

The promotion of tourism has been identified as a key strategy that can lead to economic upliftment, community development and poverty relief in the developing world. In the last few years, tourism has also emerged as a significant development option in post–apartheid South Africa. In the context of some current debates on tourism in poor countries, the paper examines how economic, social and environmental resources are being utilized to promote tourism as a local economic development strategy in South Africa, and more specifically it focuses on current local government endeavours in this regard and two communities that have suffered the loss of their economic resource base. Tourism–based development initiatives, one in KwaZulu–Natal and one in the Western Cape, are evaluated in the context of generating economic growth, alleviating poverty and addressing the apartheid legacy of discrimination and inequality. The significance of the dynamics of development processes involved in these initiatives has much wider relevance for local economic development, both within South Africa and elsewhere.  相似文献   

Richterite-bearing peridotites and MARID-type inclusions in lavas from North Eastern Morocco: mineralogy and D/H isotopic studies   总被引：4，自引：0，他引：4  

C. Wagner  Etienne Deloule  Abdelkader Mokhtari 《Contributions to Mineralogy and Petrology》1996,124(3-4):406-421

 K-richterite/phlogopite-bearing peridotite xenoliths and MARID inclusions have been found in Late Cretaceous (67±0.2 million years) monchiquites and an olivine nephelinite from North Eastern Morocco. It is the first evidence of MARID rocks and K-richterite/phlogopite-bearing peridotites outside the kimberlitic context. In the hydrous xenoliths, textural features suggest that K-richterite, phlogopite and Al-poor diopside are replacement minerals. K-richterites contain 2–5 wt% FeO, 0.1–1.5 wt% TiO₂ and <0.5 wt% Cr₂O₃. Micas contain 5.4–7.4 wt% FeO and 0.3–2.2 wt% TiO₂, with Cr and Ni contents <0.2 wt%. Diopsides are Al-poor (<0.2 wt% Al₂O₃) and contain 0.1–0.2 wt% TiO₂, 0.9–1.1 wt% Na₂O and 1.3–1.7 wt% Cr₂O₃. Compared to known K-richterites and micas from metasomatised peridotite nodules (PKP types), the Moroccan minerals are more Fe rich, K-richterites have higher Ti and micas less Cr and Ni. They are thus closer to MARID than to PKP minerals. K-richterites and mica from the MARID inclusions show typical characteristics, e.g. high FeO (4.3–4.7 wt% in richterite and 7.2 wt% in mica), low NiO and/or Cr₂O₃ and the incomplete filling of the tetrahedral site by Si+Al. Ion probe D/H analyses of amphiboles and micas from both xenolith types give high δD values ranging from –8 to –73, with large variations within single grains (up to 50‰). Both the D-enrichment and the δD variations are inherited from the mantle. The similar chemical composition and δD values of K-richterite/phlogopite from the hydrous peridotites and MARID minerals suggest a genetic link between the two types of xenoliths. The conditions required for producing MARIDs and K-richterite/phlogopite-bearing peridotites may thus exist in contexts other than stable cratonic settings. MARID rocks and the associated metasomites may result from a hydrous fluid interaction with a peridotite, the metasomatic agent being characterised by a high K and low Al signature and a high δD value. A D-rich source is involved in the metasomatic event producing the hydrous minerals, and the scatter observed in the δD values suggests a mixing between this source and another one with typical upper mantle D/H composition. As indicated by the low δD (–74) values of micas from the host lava, metasomatism predated and is unrelated to the alkaline volcanism. Received: 9 March 1995 / Accepted: 4 April 1996  相似文献