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71.
72.
Little Kickapoo Creek (LKC), a low‐gradient stream, mobilizes its streambed–fundamentally altering its near‐surface hyporheic zone–more frequently than do higher‐gradient mountain and karst streams. LKC streambed mobility was assessed through streambed surveys, sediment sampling, and theoretical calculations comparing basal shear stress (τb) with critical shear stress (τc). Baseflow τb is capable of entraining a d50 particle; bankfull flow could entrain a 51·2 mm particle. No particle that large occurs in the top 30 cm of the substrate, suggesting that the top 30 cm of the substrate is mobilized and redistributed during bankfull events. Bankfull events occur on average every 7·6 months; flows capable of entraining d50 and d85 particles occur on average every 0·85 and 2·1 months, respectively. Streambed surveys verify streambed mobility at conditions below bankfull. While higher gradient streams have higher potential energy than LKC, they achieve streambed‐mobilization thresholds less frequently. Heterogeneous sediment redistribution creates an environment where substrate hydraulic conductivity (K) varies over four orders of magnitude. The frequency and magnitude of the substrate entrainment has implications on hyporheic zone function in fluid, solute and thermal transport models, interpretations of hyporheic zone stability, and understanding of LKC's aquatic ecosystem. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
73.
A spectral imager specifically designed to measure the O+(2P-2D) emission in the thermosphere during twilight has been constructed and tested in Toronto (43.8°N, 79.3°W), and found to show promise for long-term and campaign-mode operations. A modification of the mesopause oxygen rotational temperature imager (MORTI), it consists basically of a narrow-band interference filter (0.14 nm bandwidth) to separate wavelengths as a function of off-axis angle, a lens to focus the spectrum into a series of concentric rings, and a focal plane array (CCD) to record the spectral images in digital form. The instrument was built with two fields of view, one for the zenith and one for 20° above the horizon, movable to track the azimuth of the Sun, in order to provide appropriate data for inversion. Data gathered during June 1991 provided measurements of the column-integrated emission rate with a precision of about 3%. An atomic oxygen profile was deduced that showed good agreement with that predicted by the MSIS-90 model atmosphere. Geomagnetically induced variations of the O+ lines, calcium spectra resulting from meteor showers, and OH nightglow were also observed.  相似文献   
74.
Hydrocarbon compositions have been determined for 210Pb-dated sediment cores collected at 23 sites within the inland marine waters of northwestern Washington State, U.S.A. Concentrations of total aliphatic hydrocarbons (TAH) and an unresolved complex mixture (UCM) are significantly higher in surface sediments near urban areas than at all other locations with a chronology that indicates a predominantly anthropogenic origin. Concentrations of chromatographically resolvable alkanes are comparatively uniform; the major constituents are plant wax n-alkanes and a naturally-occurring suite of fossil isoprenoid and n-alkanes. Pristane concentrations decrease sharply near the sea-sediment interface suggesting rapid degradation of a plankton-derived component. A saturated multibranched, but nonisoprenoid, C20 hydrocarbon and two novel mono-olefinic analogs have been isolated along with a previously unreported suite for four acyclic multibranched C25 polyenes. Structural and distributional similarities between the C20 and C25 multibranched hydrocarbons suggest that they may be structurally homologous and share a common source.  相似文献   
75.
In the modern South Atlantic the transition between deep water and bottom water is marked by a clear change in the associated benthonic foraminiferal fauna. uvigerina and Globocassidulina characterize oxygen-poor Circumpolar Deep Water which has long been isolated from the surface. Planulina and miliolids are found associated with the more newly formed, oxygen-rich North Atlantic Deep Water. Antarctic Bottom Water is characterized by “Epistominella” umbonifera. Analysis of the benthonic foraminiferal faunas in two sediment cores recovered from the Vema and Hunter Channels in the western South Atlantic shows that the level of the transition between deep and bottom waters shallowed sharply about 700,000 yr ago. This rise indicates a sharp, sustained increase in the volume of bottom water flowing through the South Atlantic after this time. Prior to about 700,000 yr ago, the amount of Antarctic Bottom Water entering the western South Atlantic was greatly reduced and Circumpolar Deep Water apparently accounted for the bulk of northward flow. Production of southward-flowing North Atlantic Deep Water seems not to have been affected. The timing of this change in circulation regime suggests a possible causal link to similar changes in records of terrestrial and sea-surface climate.  相似文献   
76.
Since February 1969 Alae Crater, a 165-m-deep pit crater on the east rift of Kilauea Volcano, has been completely filled with about 18 million m3 of lava. The filling was episodic and complex. It involved 13 major periods of addition of lava to the crater, including spectacular lava falls as high as 100 m, and three major periods of draining of lava from the crater. Alae was nearly filled by August 3, 1969, largely drained during a violent ground-cracking event on August 4, 1969, and then filled to the low point on its rim on October 10, 1969. From August 1970 to May 1971, the crater acted as a reservoir for lava that entered through subsurface tubes leading from the vent fissure 150 m away. Another tube system drained the crater and carried lava as far as the sea, 11 km to the south. Much of the lava entered Alae by invading the lava lake beneath its crust and buoying the crust upward. This process, together with the overall complexity of the filling, results in a highly complicated lava lake that would doubtless be misinterpreted if found in the fossil record.  相似文献   
77.
Wicks C  Kelley C  Peterson E 《Ground water》2004,42(3):384-389
Adverse impacts on the health of some fish populations, such as skewed sex distributions, have been noted in surface waters and in laboratory experiments with relatively low concentrations (above 25 ng/L) of natural estrogen (17 beta-estradiol--E2). Sources of E2 to surface and ground waters can include avian, human, and mammalian waste products. The Ozark Plateau Aquifer (OPA) is a karstic basin that receives a significant portion of its water through losing reaches of rivers. Thus, there is a direct connection between surface water and ground water. The OPA was targeted for an E2 study to assess the potential for adverse health effects to aquatic organisms living in the system. Eight springs, which drain the aquifer, were sampled quarterly. The concentrations of E2 in the OPA ranged from 13 to 80 ng/L. For any one sampling event, the concentrations of E2 at the spring waters were statistically similar; however, the concentrations of E2 at all springs varied throughout the year. At Maramec Spring, one of the larger springs, the E2 concentration, was correlated with discharge. Based on the correlation between discharge and E2 concentration, aquatic organisms living in the plateau or in its discharged waters, including the threatened southern cavefish T. subterraneus, are exposed to concentration of E2 above 25 ng/L approximately 60% of the time. This implies that organisms living in karst basins throughout the OPA are likely exposed to E2 concentrations that may adversely impact their reproductive success for a significant portion of each year.  相似文献   
78.
Satellite data were the primary source of information for the eruption of Mt. Cleveland, Alaska on 19 February, and 11 and 19 March 2001. Multiple data sets were used pre-, syn- and post-eruption to mitigate the hazard and determine an eruption chronology. The 19 February eruption was the largest of the three, resulting in a volcanic cloud that formed an arc over 1000 km long, moved to the NE across Alaska and was tracked using satellite data over more than a 50-h period. The volcanic cloud was “concurrently” detected on the GOES, AVHRR and MODIS data at various times and their respective signals compared. All three sensors detected a cloud that had a very similar shape and position but there were differences in their areal extent and internal structural detail. GOES data showed the largest volcanic cloud in terms of area, probably due to its oblique geometry. MODIS bands 31 and 32, which are comparable to GOES and AVHRR thermal infrared wavelengths, were the least effective single channels at detecting the volcanic cloud of those investigated (MODIS bands 28, 29, 31 and 32). MODIS bands 28 and 29 detected the largest volcanic clouds that could easily be distinguished from weather clouds. Of the split-window data, MODIS bands 29 minus band 32 detected the largest cloud, but the band 31 minus band 32 data showed the volcanic cloud with the most internal structural detail. The Puff tracking model accurately tracked the movement, and predicted the extent and shape of this complex cloud even into areas beyond satellite detection. Numerous thermal anomalies were also observed during the eruption on the twice-daily AVHRR data and the high spatial-resolution Landsat data. The high-resolution Radarsat data showed that the AVHRR thermal anomalies were due to lava and debris flow features and a newly formed fan along the west coast of the island. Field observations and images from a hand-held Forward Looking Infrared Radiometer (FLIR) showed that the flow features were ′a′a lava, debris flows and a warm debris fan along the west coast. Real-time satellite data were the primary tool used to monitor the eruption, track changes and to mitigate hazards. High-resolution data, even though coverage is infrequent, were critical in helping to identify volcanic processes and to compile an eruption chronology.  相似文献   
79.
Shombole, a nephelinite-carbonatite volcano in south Kenya, erupted silicate lavas, carbonatite dikes and tuffs, and pyroclastic rocks similar to those at other East African alkaline centres. Shombole lavas containing cpx + nepheline + accessory minerals range from perovskite-bearing nephelinites (43% SiO2, volatile-free) to sphene-bearing and phonolitic nephelinites (46–49% SiO2) and phonolites (49–56% SiO2) and have low peralkalinity ([Na+K]/Al 1.15) which does not correlate with SiO2. Early fractionation of olivine and clinopyroxene strongly depleted Ni and Cr concentrations (10 ppm); fractionation of perovskite, melanite, sphene, and apatite produced negative correlations of all REE with SiO2. Many lavas contain cognate intrusive xenoliths and xenocrysts and oscillatory zoning is a common feature of clinopyroxene, nepheline, and melanite crystals, indicating recycling of intrusive material. Irregular calcite-rich bodies in many samples are interpreted as quenched immiscible Ca-carbonatite liquid, and [Ca-carbonate]-silicate liquid immiscibility is observed in experiments with one nephelinite. Chemical variation in the Shombole suite can be modeled as a combination of crystal fractionation (clinopyroxene and heavy minor phases) and retention of neutral density nepheline derived from disaggregated xenoliths entrained during emplacement of dike swarms. Six newly analyzed lavas from Oldoinyo L'engai, northern Tanzania, are geochemically similar to Shombole nephelinites except that they have relatively high Na2O+K2O (average 18% vs 12%) and Zr (average 680 ppm vs 400 ppm). They are extremely peralkaline and are not typical of nephelinites from other centres. Three with [Na+K]/Al1.5 contain euhedral wollastonite phenocrysts; three with [Na+K]/Al2.0 contain combeite (Na2Ca2Si3O9) phenocrysts and pseudomorphs after wollastonite. Both types contain abundant sodalite phenocrysts (+nepheline+clinopyroxene+melanite+sphene). Seven other wollastonite nephelinite samples from L'engai have been described, but it is a lava type rarely seen in other centres. Combeite has been described from only two other locations (Mt. Shaheru, Zaire; Mayener Feld, Eifel). The hyperalkaline L'engai nephelinites have compositions similar to those of experimental silicate liquids immiscible with natrocarbonatite. Textural evidence for both carbonate-silicate (as carbonate globules) and silicate-silicate (as two optically discrete glasses with distinct compositions) liquid immiscibility is observed in the samples.  相似文献   
80.
A method of parameter estimation is outlined for a two-component grinding-liberation model. The large number of model variables is reduced by using functional forms. The parameters for the functional forms are estimated using a modified Gauss-Newton algorithm. The technique is applied to both synthetic and real experimental data. Parameters estimated from wet grinding batch tests of Illinois No. 6 coal were used to predict mill output for a larger pilot-plant mill. The predictions were found to match the actual mill output within the limits of experimental error.  相似文献   
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