A critical evaluation of using bulk sediment instead of fine fraction in environmental marine studies, investigated on example of Rijeka harbor, Croatia     

Stanislav Frančišković-Bilinski  Neven Cukrov 《Environmental Earth Sciences》2014,71(1):341-356

This work tested the preferential use of fine (<63 μm) or bulk sediment (<2 mm) in environmental research of marine sediments in the Eastern Adriatic. Fine fraction sediment containing silt and clay (<63 μm), predominating in the studied area, was examined to evaluate past and present anthropogenic inputs and to test our hypothesis that investigation of bulk sediment should be preferred. Following aqua regia digestion, chemical analyses of 58 elements were performed by ICP/OES, ICP-MS and cold vapor AAS, and statistical analysis was performed. The concentrations of the majority of the analyzed elements increased with age of the sediment, except for Ag and Sn, which had higher concentrations in recent sediments. The previous main sources of metal contamination in Rijeka harbor were now abandoned municipal-sewage outflow and oil refinery, and continuing harbor activities and antifouling paint use. All activities except of antifouling paint use have been decreasing significantly. Anomalies of selected elements were determined by the box-plot method. More anomalies were found in the bulk sediment than in the fine fraction. Results of Q-modality clustering and factor analysis in the fine fraction almost correlate with that applied on bulk sediments. Thus, it can be said that the differences between the element distribution in the bulk and fine fraction are not statistically significant. Our conclusion is that analysis of bulk marine sediment gives a better insight into the state of pollution and supports previous recommendations to use bulk sediment as a chosen media for environmental studies.  相似文献   

Effects of sinuosity factor on hydrodynamic parameters estimation in karst systems: a dye tracer experiment from the Beyyayla sinkhole (Eskişehir,Turkey)     

Harun Aydin  Mehmet Ekmekçi  Mehmet Evren Soylu 《Environmental Earth Sciences》2014,71(9):3921-3933

The sinuosity factor (SF) is a critical value in karst systems in terms of estimating their hydrodynamic parameters including groundwater velocity, coefficient of dispersion, etc., through dye tracer experiments. SF has been used in a number of different dye tracer experiments in karstic systems to estimate a representative flow path. While knowing SF is crucially important in the estimation of hydrodynamic parameters, its calculation is associated with significant uncertainty due to the complexity of subsurface karstic features. And yet, only a few studies have discussed its uncertainties, which might lead some errors in estimation of hydrodynamic parameters from dye tracer experiment. In this study, dye tracer experiments were conducted in two consecutive years (2003 and 2004) representing low and high flow conditions in the Beyyayla sinkhole (Eski?ehir, Turkey) where the flow path is well known. Uranine was used in experiments as a tracer and QTRACER computer program was used to determine the hydrodynamic properties of the Beyyayla karst system as well as to gain insights into the effects of SF from dye tracer experiments on estimated parameters. The results showed that the breakthrough curve follows a unimodal and a bimodal distribution in low and high flow conditions, respectively. These different distributions stem from the water transport mechanisms, where velocities were calculated as 58.2 and 93.6 m h^?1 during low and high flow conditions observed in a spring emerging from the south side of the studied system. The results also show that the coefficient of dispersion, Reynolds number, and Peclet number increased and longitudinal dispersivity decreased with the higher flow rate. Furthermore, the estimated parameters did not vary with either the flow conditions or the tracer transit time, but they have shown some variations with SF. When SF was increased by 50 %, a change in these parameters was obtained in the range of 50–125 %.  相似文献   

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)     

Nenad Grba  Aleksandra Šajnović  Ksenija Stojanović  Vladimir Simić  Branimir Jovančićević  Goran Roglić  Vladisav Erić 《Chemie der Erde / Geochemistry》2014

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.  相似文献   

The crystal structure of bøgvadite (Na2SrBa2Al4F20)     

Tonči Balić-Žunić 《Mineralogy and Petrology》2014,108(4):479-486

The crystal structure of bøgvadite, Na₂SrBa₂Al₄F₂₀, has been solved and refined to a R₁ factor of 4.4 % from single-crystal data (MoKα X-ray diffraction, CCD area detector) on a sample from the cryolite deposit at Ivittuut, SW Greenland. Bøgvadite is monoclinic, P2₁/n space group, with unit cell parameters a?=?7.134(1), b?=?19.996(3) and c?=?5.3440(8) Å, β?=?90.02(1)^o. A close proximity of the crystal structure to an orthorhombic symmetry and the presence of the two twin components in a nearly 1:1 ratio suggest that the investigated bøgvadite crystal has originally formed as a high-temperature orthorhombic polymorph which on cooling transformed to the stable low temperature monoclinic structure. The bøgvadite crystal structure has groupings of cation-fluoride coordination polyhedra similar to those found in the crystal structures of the genetically closely associated minerals jarlite and jørgensenite. However, its structure type is different from the latter two. The fluoridoaluminate framework of bøgvadite consists of infinite zig-zag chains of cis-connected AlF₆ coordination octahedra. The ¹ _∞[AlF₅] chains are interconnected by infinite chains of Na-F coordination polyhedra which extend in the same direction. Na is coordinated by nine F atoms if its full surrounding is taken in consideration, but makes significant chemical bonds only to closest five. The chains of AlF₆ and NaF₉ coordination polyhedra form double layers. In the centre of layers, relatively large voids in the form of pentagonal antiprisms are occupied by Sr atoms which make chemical bonds with the closest six F atoms. Between the SrF₁₀ coordinations in the centre of layers run empty channels. The double layers are interconnected by Ba atoms which are coordinated by eight F atoms and fill the spaces between the layers. Bøgvadite belongs to the group of fluoridoaluminates with infinite chains of cis-connected AlF₆ coordination octahedra, alike those found in the crystal structures of Ba-fluoridoaluminates.  相似文献   

青海省都兰县阿拉克湖地区水系沉积物地球化学特征及找矿方向     

颜自给  李学彪 《矿产与地质》2014,(1):58-65

分析了区内的水系沉积物地球化学参数特征及其元素的相关性,认为元素(地球化学)异常(高值区)严格受东昆中断裂带、东昆南断裂带、布青山南坡乌断裂带,以及阿尼玛卿蛇绿岩带和东昆中蛇绿岩带,古-中元古代地层、岩体接触带、热液活动、脉岩等因素联合控制。根据异常特征与成矿地质条件,圈定了找矿远景区5个,且为该区下一步的找矿工作指明了方向。  相似文献   

Direct detection of the secondary spectrum of the interacting eclipsing binary TX UMa     

J. Grygar  L. Hřič  R. Komžík  Z. Šíma 《Astrophysics and Space Science》1991,185(2):189-193

Eclipsing binary TX UMa was observed with the D.A.O. high-dispersion spectrographs in 1969–1970, with emphasis on the detailed coverage of the primary minimum. One spectrum was taken exclusively within totality, thus exhibiting an uncontaminated spectrum of the secondary component. This leads to spectral reclassification of the secondary (F6 IV). The narrowing of the line profile of the H-line in totality is interpreted in terms of synchronous rotation of the secondary (v sini80 km s^–1) while the primary rotates faster (v sini130 km s^–1) than synchronously (v sini50 km s^–1). Although the secondary does not fill in its Roche lobe fully, the system exhibits pronounced indications of rather strong physical interaction. This is now supported also by the profound changes of the line profiles of the H-line with phase.  相似文献   

Coherence of river and ocean conditions along the US West Coast during storms     

Tara A. Kniskern  Jonathan A. Warrick  Katherine L. Farnsworth  Robert A. Wheatcroft  Miguel A. Goñi 《Continental Shelf Research》2011,31(7-8):789-805

The majority of water and sediment discharge from the small, mountainous watersheds of the US West Coast occurs during and immediately following winter storms. The physical conditions (waves, currents, and winds) within and acting upon the proximal coastal ocean during these winter storms strongly influence dispersal patterns. We examined this river–ocean temporal coherence for four coastal river–shelf systems of the US West Coast (Umpqua, Eel, Salinas, and Santa Clara) to evaluate whether specific ocean conditions occur during floods that may influence coastal dispersal of sediment. Eleven years of corresponding river discharge, wind, and wave data were obtained for each river–shelf system from USGS and NOAA historical records, and each record was evaluated for seasonal and event-based patterns. Because near-bed shear stresses due to waves influence sediment resuspension and transport, we used spectral wave data to compute and evaluate wave-generated bottom-orbital velocities. The highest values of wave energy and discharge for all four systems were consistently observed between October 15 and March 15, and there were strong latitudinal patterns observed in these data with lower discharge and wave energies in the southernmost systems. During floods we observed patterns of river–ocean coherence that differed from the overall seasonal patterns. For example, downwelling winds generally prevailed during floods in the northern two systems (Umpqua and Eel), whereas winds in the southern systems (Salinas and Santa Clara) were generally downwelling before peak discharge and upwelling after peak discharge. Winds not associated with floods were generally upwelling on all four river–shelf systems. Although there are seasonal variations in river–ocean coherence, waves generally led floods in the three northern systems, while they lagged floods in the Santa Clara. Combined, these observations suggest that there are consistent river–ocean coherence patterns along the US West Coast during winter storms and that these patterns vary substantially with latitude. These results should assist with future evaluations of flood plume formation and sediment fate along this coast.  相似文献   

Late Cenozoic depositional history of the western Svalbard continental shelf, controlled by subsidence and climate     

A. Solheim  E. S. Andersen  A. Elverhi  A. Fiedler 《Global and Planetary Change》1996,12(1-4)

Based on a grid of high resolution, single channel seismic lines, this paper addresses the Late Cenozoic evolution of the western Svalbard continental shelf. The seismic structure of the shelf includes at least 16 erosional unconformities, each representing a glacial advance. The evolution during the last approximately one million years has been divided into six main erosional and depositional phases. Differential margin subsidence around a hinge zone is an important controlling mechanism for the accumulation of the sedimentary wedge at the outer shelf. The most significant depositional change appears to be related to a general climatic shift, globally recorded to be centred around 1 Ma. At this level, corresponding to the Upper Regional Unconformity (URU) on the shelf, the depositional regime changed from net erosion to net deposition and shelf aggradation. Of major significance is probably a shift from thick, eroding glaciers with steep ice profiles, to low profile fast flowing ice streams maintained by an increased amount of interglacial and interstadial sediments. The relationship between climatic fluctuations, glacial dynamics and depositional regime is discussed.  相似文献   

Historical torrential flood events in the Kolubara river basin   总被引：1，自引：0，他引：1  

Ana M. Petrović  Slavoljub S. Dragićević  Boris P. Radić  Ana Z. Milanović Pešić 《Natural Hazards》2015,79(1):537-547

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Single-frequency precise point positioning: an analytical approach   总被引：1，自引：0，他引：1  

Oskar Sterle  Bojan Stopar  Polona Pavlovčič Prešeren 《Journal of Geodesy》2015,89(8):793-810

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