Decomposition of hydroxy amino acids in foraminiferal tests; kinetics,mechanism and geochronological implications     

Jeffrey L. Bada  Ming-Yung Shou  Eugene H. Man  Roy A. Schroeder 《Earth and Planetary Science Letters》1978,41(1):67-76

The diagenesis of the hydroxy amino acids serine and threonine in foraminiferal tests has been investigated. The decomposition pathways of these amino acids are complex; the principal reactions appear to be dehydration, aldol cleavage and decarboxylation. Stereochemical studies indicate that the α-amino-n-butyric acid (ABA) detected in foraminiferal tests is the end product of threonine dehydration pathway. Decomposition of serine and threonine in foraminiferal tests from two well-dated Caribbean deep-sea cores, P6304-8 and -9, has been found to follow irreversible first-order kinetics. Three empirical equations were derived for the disappearance of serine and threonine and the appearance of ABA. These equations can be used as a new geochronological method for dating foraminiferal tests from other deep-sea sediments. Preliminary results suggest that ages deduced from the ABA kinetics equation are most reliable because “species effect” and contamination problems are not important for this nonbiological amino acid. Because of the variable serine and threonine contents of modern foraminiferal species, it is likely that the accurate age estimates can be obtained from the serine and threonine decomposition equations only if a homogeneous species assemblage or single species sample isolated from mixed natural assemblages is used.  相似文献   

Recurrence statistics of concentration fluctuations in plumes within a near-neutral atmospheric surface layer     

Eugene Yee  P. R. Kosteniuk  G. M. Chandler  C. A. Biltoft  J. F. Bowers 《Boundary-Layer Meteorology》1993,66(1-2):127-153

This study examines the statistical properties of the concentration derivative, , for a dispersing plume in a near-neutrally stratified atmospheric surface layer. Towards this goal, the probability density function (pdf) of , and the conditional pdf of given a fixed concentration level, , have been measured. These pdfs are found to be modeled well by a generalizedq-Gaussian (gqG) distribution with intermittency exponent,q, equal to 0.3 and 3/4, respectively. These results highlight the strong intermittency effect (patchiness) of the small-scale concentration eddy structures in the plume. The distribution of time intervals between successive high peaks in the squared derivative process, x², is found to be well approximated by a power-law distribution, implying that occurrences of these high peaks are much more clustered than would be predicted by a Poisson or shot-noise process. The results are used to improve models for the joint pdf of and , and for the expected number of upcrossings per unit time interval of a fixed concentration level that have been proposed by Kristensenet al. (1989). The predictions of the improved models are in accord with observations, and suggest that the intercorrelation between and must be explicitly incorporated if good estimates of the upcrossing intensity are to be obtained.  相似文献   

ASTM Subcommittee develops standards for ground water and vadose zone investigations     

Eugene Setzkorn 《GeoJournal》1990,21(3):300-301

Reports

ASTM Subcommittee develops standards for ground water and vadose zone investigations  相似文献   

Below- and Aboveground Biomass of <Emphasis Type="Italic">Spartina alterniflora</Emphasis>: Response to Nutrient Addition in a Louisiana Salt Marsh     

Faith A. Darby  R. Eugene Turner 《Estuaries and Coasts》2008,31(2):326-334

The responses of Spartina alterniflora above- and belowground biomass to various combinations of N, P, and Fe were documented in a 1-year field experiment in a Louisiana salt marsh. Five levels of N additions to 0.25 m² plots resulted in 18% to 138% more live aboveground biomass compared to the control plots and higher stem densities, but had no effect on the amount of live belowground biomass (roots and rhizomes; R&R). There was no change in the aboveground biomass when P or Fe was added as part of a factorial experiment of +P, +N, and +Fe additions, but there was a 40% to 60% decrease in the live belowground biomass, which reduced the average R&R:S ratio by 50%. The addition of various combinations of nutrients had a significant affect on the belowground biomass indicating that the addition of P, not N, eased the need for root foraging activity. The end-of-the-growing-season N:P molar ratios in the live above- and belowground tissues of the control plot was 16.4 and 32.7, respectively. The relative size of the belowground standing stocks of N and P was higher than in the aboveground live tissues, but shifted downwards to about half that in fertilized plots. We conclude that the aboveground biomass was directly related to N availability, but not P, and that the accumulation of belowground biomass was not limited by N. We suggest that the reduction in belowground biomass with increased P availability, and the lower absolute and relative belowground standing stocks of P as plant tissue N:P ratios increased, is related to competition with soil microbes for P. One implication for wetland management and restoration is that eutrophication may be detrimental to long-term salt marsh maintenance and development, especially in organic-rich wetland soils.  相似文献   

Optimized boundary conditions at staircase-shaped coastlines     

Eugene Kazantsev 《Ocean Dynamics》2015,65(1):49-63

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Geophysical Constraints on the Hydrogeologic and Structural Settings of the Gulf of Suez Rift-Related Basins: Case Study from the El Qaa Plain,Sinai, Egypt     

Mohamed Ahmed  William Sauck  Mohamed Sultan  Eugene Yan  Farouk Soliman  Mohamed Rashed 《Surveys in Geophysics》2014,35(2):415-430

Groundwater has been identified as one of the major freshwater sources that can potentially meet the growing demands of Egypt’s population. Gravity data (from 381 ground gravity stations) were collected, processed, and analyzed together with the available aeromagnetic (800 line-km) data to investigate the hydrogeologic and structural settings, areal distribution, geometry, and water storage of the aquifers in El Qaa coastal plain in the southwest Sinai Peninsula, and to assess their longevity given projected extraction rates. Findings include (1) complete Bouguer anomaly and total magnetic intensity maps show two connected sub-basins separated by a narrow saddle with an average basin length of 43 km and an average width of 12 km; (2) two-dimensional modeling of both gravity and magnetic data indicates basin fill with a maximum thickness of 3.5 km; (3) using anomalous residual gravity, the volume of water in storage was estimated at 40–56 km³; and (4) progressive increases in extraction rates over time will deplete up to 40 % of the aquifers’ volume in 200–230 years and will cause the water quality to deteriorate due to seawater intrusion in 45 years. Similar geophysical exploration campaigns, if conducted over the entire coastal plains of the Red Sea and the Gulfs of Suez and Aqaba, could assist in the development of sound and sustainable management schemes for the freshwater resources in these areas. The adopted techniques could pave the way toward the establishment of sustainable utilization schemes for a much larger suite of similar aquifers worldwide.  相似文献   

Assessing and Improving Land Surface Model Outputs Over Africa Using GRACE,Field, and Remote Sensing Data     

Mohamed Ahmed  Mohamed Sultan  Eugene Yan  John Wahr 《Surveys in Geophysics》2016,37(3):529-556

The Gravity Recovery and Climate Experiment (GRACE), along with other relevant field and remote sensing datasets, was used to assess the performance of two land surface models (LSMs: CLM4.5-SP and GLDAS-Noah) over the African continent and improve the outputs of the CLM4.5-SP model. Spatial and temporal analysis of monthly (January 2003–December 2010) Terrestrial Water Storage (TWS) estimates extracted from GRACE (TWS_GRACE), CLM4.5-SP (TWS_CLM4.5), and GLDAS-Noah (TWS_GLDAS) indicates the following: (1) compared to GRACE, LSMs overestimate TWS in winter months and underestimate them in summer months; (2) the amplitude of annual cycle (AAC) of TWS_GRACE is higher than that of TWS_LSM (AAC: TWS_GRACE > TWS_GLDAS > TWS_CLM4.5); (3) higher, and statistically significant correlations were observed between TWS_GRACE and TWS_GLDAS compared to those between TWS_GRACE and TWS_CLM4.5; (4) differences in forcing precipitation and temperature datasets for GLDAS-Noah and CLM4.5-SP models are unlikely to be the main cause for the observed discrepancies between TWS_GRACE and TWS_LSM; and (5) the CLM4.5-SP model overestimates evapotranspiration (ET) values in summer months and underestimates them in winter months compared to ET estimates extracted from field-based (FLUXNET-MTE) and satellite-based (MOD16 and GLEAM) ET measurements. A first-order correction was developed and applied to correct the CLM4.5-derived ET, soil moisture, groundwater, and TWS. The corrections improved the correspondence (i.e., higher correlation and comparable AAC) between TWS_CLM4.5 and TWS_GRACE over various climatic settings. Our findings suggest that similar straightforward correction approaches could potentially be developed and used to assess and improve the performance of a wide range of LSMs.  相似文献   

Interrupting a multi-species bioinvasion vector: the efficacy of in-water cleaning for removing biofouling on obsolete vessels     

Davidson IC  McCann LD  Sytsma MD  Ruiz GM 《Marine pollution bulletin》2008,56(9):1538-1544

Vector management is the primary method for reducing and preventing nonindigenous species (NIS) invasions and their ecological and economic consequences. This study was the first to examine the efficacy of in-water scrubbing using a submersible cleaning and maintenance platform (SCAMP) to prevent invertebrate species transfers from a heavily fouled obsolete vessel. Initially, prior to treatment, 37 species were recorded in a biofouling matrix that reached 30cm depth in some locations. The bryozoan Conopeum chesapeakensis, and bivalves Mytilopsis leucophaeata and Ischadium recurvum, were dominant sessile species that created structure, supporting mobile biota that included crabs and the associated parasitic barnacle Loxothylacus panopae. Scrubbing had the effect of significantly reducing organism extent and the number of species per sample, but a substantial and diverse (30 species) residual fouling community remained across the entire vessel. Further assessments of management options are needed to prevent potentially damaging NIS transfers. Additional measures taken within an integrated vector management (IVM) strategy may further improve invasion prevention measures.  相似文献   

A simple method to model the reduced environment of lake bottom sapropel formation     

Gaskova  Olga L.  Strakhovenko  Vera D.  Ermolaeva  Nadezhda I.  Zarubina  Eugene Yu.  Ovdina  Ekaterina A. 《中国海洋湖沼学报》2017,35(4):956-966

The Kambala and Barchin brackish lakes(Baraba steppe,southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters.We measured the bulk sediment elemental composition,the water chemistry and determined the mineralogical composition and predominant biota species(Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes.The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one.A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes.The surface sodium bicarbonate waters are supersaturated with respect to calcite,magnesite(or low Mg-calcite),quartz and chlorite with minor strontianite,apatite and goethite(pH8.9-9.3,Eh 0.3 V).Nevertheless,it is shown that during sapropel deposition,deep silt waters should be anoxic(Eh0 V).The virtual component CH_2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction.Thermodynamic calculation has shown that silt water is not necessarily euxinic(anoxic and sulfidic).Depending on Eh,sulfate sulfur can dominate in solution,causing the formation of gypsum together with pyrite.An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids.  相似文献   

Chemical analyses of meteorites at the Smithsonian Institution: An update     

Eugene Jarosewich 《Meteoritics & planetary science》2006,41(9):1381-1382

Abstract— Thirteen new meteorites and three meteorite inclusions have been analyzed. Their results have been incorporated into earlier published data for a comprehensive reference to all analyzed meteorites at the Smithsonian Institution. The six tables facilitate a convenient overlook of meteorite data. Table 1 presents an alphabetical list of analyzed meteorites, Table 2 chemical analyses of stony meteorites, Table 3 chemical analyses of iron meteorites, Table 4 elemental composition of stony meteorites, Table 5 average composition of carbonaceous chondrites and achondrites (falls and finds), and Table 6 presents average composition of H, L, LL, and Antarctic chondrites (falls and finds). The tables are available online at the journal's Web site http:meteoritics.org .  相似文献