Effect of Biofuels on Biodegradation of Benzene and Toluene at Gasoline Spill Sites          下载免费PDF全文

John T. Wilson  Cherri Adair  Hal White  Robert L. Howard 《Ground Water Monitoring & Remediation》2016,36(4):50-61

The risk that benzene and toluene from spills of gasoline will impact drinking water wells is largely controlled by the natural anaerobic biodegradation of benzene and toluene. Benzene and toluene, as well as ethanol and other biofuels, are degraded under anaerobic conditions to the same pool of degradation products. Biodegradation of biofuels may produce concentrations of degradation products that make the thermodynamics for degradation of benzene and toluene infeasible under methanogenic conditions and produce larger plumes of benzene and toluene. This study evaluated the concentrations of fuel alcohols that are necessary to inhibit the anaerobic degradation of benzene and toluene under methanogenic conditions. At two ethanol spill sites, concentrations of ethanol greater ≥42 mg/L inhibited the anaerobic degradation of toluene. The pH and concentrations of acetate, dissolved inorganic carbon, and molecular hydrogen were used to calculate the Gibbs free energy for the biodegradation of toluene. In general, the anaerobic biodegradation of toluene was not thermodynamically feasible in water with ≥42 mg/L ethanol. In a microcosm study, when the concentrations of ethanol were ≥14 mg/L or the concentrations of n‐butanol were ≥16 mg/L, the biodegradation of the alcohols consistently produced concentrations of hydrogen, dissolved inorganic carbon, and acetate that would preclude natural anaerobic biodegradation of benzene and toluene by syntrophic organisms. In contrast, iso‐butanol and n‐propanol only occasionally produced conditions that would preclude the biodegradation of benzene and toluene.  相似文献   

Simulating flow in karst aquifers at laboratory and sub-regional scales using MODFLOW-CFP   总被引：5，自引：1，他引：4  

Josue Jacob Gallegos  Bill X. Hu  Hal Davis 《Hydrogeology Journal》2013,21(8):1749-1760

Groundwater flow in a well-developed karst aquifer dominantly occurs through bedding planes, fractures, conduits, and caves created by and/or enlarged by dissolution. Conventional groundwater modeling methods assume that groundwater flow is described by Darcian principles where primary porosity (i.e. matrix porosity) and laminar flow are dominant. However, in well-developed karst aquifers, the assumption of Darcian flow can be questionable. While Darcian flow generally occurs in the matrix portion of the karst aquifer, flow through conduits can be non-laminar where the relation between specific discharge and hydraulic gradient is non-linear. MODFLOW-CFP is a relatively new modeling program that accounts for non-laminar and laminar flow in pipes, like karst caves, within an aquifer. In this study, results from MODFLOW-CFP are compared to those from MODFLOW-2000/2005, a numerical code based on Darcy’s law, to evaluate the accuracy that CFP can achieve when modeling flows in karst aquifers at laboratory and sub-regional (Woodville Karst Plain, Florida, USA) scales. In comparison with laboratory experiments, simulation results by MODFLOW-CFP are more accurate than MODFLOW 2005. At the sub-regional scale, MODFLOW-CFP was more accurate than MODFLOW-2000 for simulating field measurements of peak flow at one spring and total discharges at two springs for an observed storm event.  相似文献   

Response to Hairsine's and Sander's ‘Comment on “A transport‐distance based approach to scaling erosionrates”: Parts 1, 2 and 3 by Wainwright et al.’     

John Wainwright  Anthony J. Parsons  Eva N. Müller  Richard E. Brazier  D. Mark Powell 《地球表面变化过程与地形》2009,34(6):886-890

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A transport‐distance approach to scaling erosion rates: 1. Background and model development     

John Wainwright  Anthony J. Parsons  Eva N. Müller  Richard E. Brazier  D. Mark Powell  Bantigegne Fenti 《地球表面变化过程与地形》2008,33(5):813-826

The process basis of existing soil‐erosion models is shown to be ill‐founded. The existing literature builds directly or indirectly on Bennett's (1974) paper, which provided a blueprint for integrated catchment‐scale erosion modelling. Whereas Bennett recognized the inherent assumptions of the approach suggested, subsequent readings of the paper have led to a less critical approach. Most notably, the assumption that sediment movement could be approximated by a continuity equation that related to transport in suspension has produced a series of submodels that assume that all movement occurs in suspension. For commonly occurring conditions on hillslopes, this case is demonstrably untrue both on theoretical grounds and from empirical observations. Elsewhere in the catchment system, it is only partially true, and the extent to which the assumption is reasonable varies both spatially and temporally. A second ground‐breaking paper – that of Foster and Meyer (1972) – was responsible for subsequent uncritical application of a first‐order approximation to deposition based on steady‐state analysis and again a weak empirical basis. We describe in this paper an alternative model (Mahleran – Model for Assessing Hillslope‐Landscape Erosion, Runoff And Nutrients) based upon particle‐travel distance that overcomes existing limitations by incorporating parameterizations of the different detachment and transport mechanisms that occur in water erosion in hillslopes and small catchments. In the second paper in the series, we consider the sensitivity and general behaviour of Mahleran , and test it in relation to data from a large rainfall‐simulation experiment. The third paper of the sequence evaluates the model using data from plots of different sizes in monitored rainfall events. From this evaluation, we consider the scaling characteristics of the current form of Mahleran and suggest that integrated modelling, laboratory and field approaches are required in order to advance the state of the art in soil‐erosion modelling. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Vegetation patterns and diversity along an altitudinal and a grazing gradient in the Jabal al Akhdar mountain range of northern Oman   总被引：1，自引：0，他引：1  

Katja Brinkmann  Annette Patzelt  Uta Dickhoefer  Eva Schlecht  Andreas Buerkert 《Journal of Arid Environments》2009,73(11):1035-1045

Little is known about the effects of grazing on vegetation composition on the Arabian Peninsula. The aim of this study therefore was to analyse the vegetation response to environmental conditions of open woodlands along an altitudinal and a grazing gradient in the Jabal al Akhdar mountain range of Oman. The species composition, vegetation structure, grazing damage and several environmental variables were investigated for 62 samples using a nested plot design. Classification analysis and a Canonical Variate Analysis (CVA) were used to define vegetation types and to identify underlying environmental gradients. The relationship between environmental variables and diversity was analysed using correlation coefficients and a main-effects ANOVA. The plant species richness followed a unimodal distribution along the altitudinal gradient with the highest number of species at the intermediate altitudinal belt. The cluster analysis led to five vegetation groups: The Sideroxylon mascatense–Dodonaea viscosa group on grazed and the Olea europaea–Fingerhuthia africana group on ungrazed plateau sites at 2000 m a.s.l., the Ziziphus spina-christi–Nerium oleander group at wadi sites and the Moringa peregrina–Pteropyrum scoparium group at 1200 m a.s.l, and the Acacia gerrardii–Leucas inflata group at 1700 m a.s.l. The CVA indicated a clear distinction of the groups obtained by the agglomerative cluster analysis. The landform, altitude and grazing intensity were found to be the most important variables distinguishing between clusters. Overgrazing of the studied rangeland is an increasing environmental problem, whereas the plant composition at ungrazed sites pointed to a relatively fast and high regeneration potential of the local vegetation.  相似文献   

Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment   总被引：1，自引：1，他引：0  

Stefan Jansen  Eva Walpersdorf  Ursula Werner  Markus Billerbeck  Michael E Böttcher  Dirk de Beer 《Ocean Dynamics》2009,59(2):317-332

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.  相似文献   

Analysis of burnt schist outcrops in the alps: Relation to historical archaeology and Hannibal's crossing in 218 B.C.     

William C. Mahaney  Michael W. Milner  Rana Sodhi  Ronald I. Dorn  Sal Boccia  Roelf P. Beukens  Pierre Tricart  Stphane Schwartz  Eva Chamorro‐Perrez  Ren W. Barendregt  Volli Kalm  Randy W. Dirszowsky 《Geoarchaeology》2007,22(7):797-816

Identification of the exact route followed by Hannibal during his invasion of Italia in the Second Punic War is one of the major questions of antiquity and one that historians/archaeologists have long studied. One of the many clues in the ancient literature that can help answer this question is the mention of fired rock, the result of a conflagration Hannibal is reputed to have employed to reduce the size of boulders in a blocking rockslide some distance down from the high col on the Italian side. The only route with evidence of fired rock along the roadway leading into Italia follows the Col du Clapier, one of the possible northern routes discussed by historians. Radiocarbon dating of calcined rocks is not possible, but whereas Time‐of‐Flight Secondary Ion Mass Spectrometry (ToF‐SIMS), Field Emission Scanning Electron Microscope (FESEM‐EDS), backscatter electron scanning microscopy (BSE), High Resolution Transmission Electron Microscope (HRTEM), and Raman Spectroscopic data do not provide an age for the burnt rock, compositional evidence of the conflagration derived from these analyses may shed light on Hannibal's actual route. © 2007 Wiley Periodicals, Inc.  相似文献   

An Overview of Surface-Based Precipitation Observations at Environment and Climate Change Canada     

Eva Mekis  Norman Donaldson  Janti Reid  Alex Zucconi  Jeffery Hoover  Qian Li 《大气与海洋》2018,56(2):71-95

The objective of this paper is to provide an overview of the present status and procedures related to surface precipitation observations at Environment and Climate Change Canada (ECCC). This work was done to support the ongoing renewal of observation systems and networks at the Meteorological Service of Canada. The paper focusses on selected parameters, namely, accumulated precipitation, precipitation intensity, precipitation type, rainfall, snowfall, and radar reflectivity. Application-specific user needs and requirements are defined and captured by World Meteorological Organization (WMO) Expert Teams at the international level by Observing Systems Capability Analysis and Review (OSCAR) and WMO Integrated Global Observing System (WIGOS), and by ECCC user engagement initiatives within the Canadian context. The precipitation-related networks of ECCC are separated into those containing automatic instruments, those with human (manual) observers, and the radar network. The unique characteristics and data flow for each of these networks, the instrument and installation characteristics, processing steps, and limitations from observation to data distribution and storage are provided. A summary of precipitation instrument-dependent algorithms that are used in ECCC's Data Management System is provided. One outcome of the analysis is the identification of gaps in spatial coverage and data quality that are required to meet user needs. Increased availability of data, including from long-serving manual sites, and an increase in the availability of precipitation type and snowfall amount are identified as improvements that would benefit many users. Other recognized improvements for in situ networks include standardized network procedures, instrument performance adjustments, and improved and sustained access to data and metadata from internal and external networks. Specific to radar, a number of items are recognized that can improve quantitative precipitation estimates. Increased coverage for the radar network and improved methods for assessing and portraying radar data quality would benefit precipitation users.  相似文献   

A model study of dickite intercalated with formamide and N-methylformamide     

Eva Scholtzová  Lubomir Benco  Daniel Tunega 《Physics and Chemistry of Minerals》2008,35(6):299-309

Local geometry and orientation of intercalated molecules of formamide (FA) and N-methylformamide (NMFA) in the clay mineral dickite (D) was studied by means of Density Functional Theory (DFT) calculations. Ten configurations with different orientation of the intercalated molecule were investigated for both D_FA and D_NMFA intercalates. Four groups of relaxed structures sorted by the calculated total electronic energy were found in both cases. The experimental geometry of the D_FA intercalate was denoted as the most stable structure from the investigated models. The differences in the total electronic energy of all D_FA configurations are within the interval of ∼92 kJ/mol. On one hand FA forms intercalates specifically and a close relation between the orientation of the FA molecules in the interlayer space and the stability of a particular configuration has been observed. On the other hand, N-methylformamide forms intercalated structures non-specifically. Small differences in the total energy, not larger than 18 kJ/mol, are observed for different orientations of the NMFA molecules The reorientation of the intercalated molecules has only a small effect on the stabilization of the D_NMFA intercalate what is in contrast with the D_FA intercalate. It was also observed that the experimental D_NMFA configuration is not the most stable. A small variation of the total electronic energy of different configurations correlates with small changes of the orientation of the dipole moment of the intercalated NMFA molecule.  相似文献   

Combination of multi-mission altimetry data along the Mekong River with spatio-temporal kriging     

Eva Boergens  Sven Buhl  Denise Dettmering  Claudia Klüppelberg  Florian Seitz 《Journal of Geodesy》2017,91(5):519-534

River water-level time series at fixed geographical locations, so-called virtual stations, have been computed from single altimeter crossings for many years. Their temporal resolution is limited by the repeat cycle of the individual altimetry missions. The combination of all altimetry measurements along a river enables computing a water-level time series with improved temporal and spatial resolutions. This study uses the geostatistical method of spatio-temporal ordinary kriging to link multi-mission altimetry data along the Mekong River. The required covariance models reflecting the water flow are estimated based on empirical covariance values between altimetry observations at various locations. In this study, two covariance models are developed and tested in the case of the Mekong River: a stationary and a non-stationary covariance model. The proposed approach predicts water-level time series at different locations along the Mekong River with a temporal resolution of 5 days. Validation is performed against in situ data from four gauging stations, yielding RMS differences between 0.82 and 1.29 m and squared correlation coefficients between 0.89 and 0.94. Both models produce comparable results when used for combining data from Envisat, Jason-1, and SARAL for the time period between 2002 and 2015. The quality of the predicted time series turns out to be robust against a possibly decreasing availability of altimetry mission data. This demonstrates that our method is able to close the data gap between the end of the Envisat and the launch of the SARAL mission with interpolated time series.  相似文献