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41.
The crystallinity of natural and synthetic apatite samples is often determined from the broadening of ν 4 PO4 infrared absorption bands. However, various physical mechanisms contribute to the observed linewidth. In the present study, the factors determining the linewidth in the powder spectrum of synthetic fluorapatite and hydroxyapatite samples are investigated. The temperature dependence of the infrared spectrum (10–270 K) is used to assess the respective contributions of homogeneous broadening, related to the decay of phonons through anharmonic coupling, and heterogeneous broadening related to elastic strain and macroscopic electrostatic effects. This latter contribution is dominant in the investigated samples and depends on the shape of powder particles. It is discussed under the light of the theoretical modeling of the low-frequency dielectric properties of apatite based on first-principles density functional theory calculations. The linewidth of the weak ν 1 PO4 absorption band provides a reliable information on microscopic sources of broadening, i.e., apatite crystallinity. In comparison, the other more intense PO4 bands are more sensitive to long-range electrostatic effects.  相似文献   
42.
This article explores the “unpopular” archived life of Charles P. Daly, thirty-five-year president (1864–1899) of the New York–based American Geographical Society. This one-time highly prominent judge and civic leader popularized geography among professionals and the public alike. Daly's popular geography, along with his subsequent containment within the archives, suggests explanations for his dismissal among geographical audiences of today. It is a useful and necessary exercise to trace the neglect of Daly within histories of geography and recapture him for today's audiences, not only because of his influence on post–Civil War American geography but also because his story can shed light on how “disciplinary remembering” functions in geography.  相似文献   
43.
A field tracer test was carried out in a light nonaqueous phase liquid (LNAPL) source zone using a well pattern consisting of one injection well surrounded by four extraction wells (5‐spot well pattern). Multilevel sampling was carried out in two observation wells located inside the test cell characterized by heterogeneous lithology. Tracer breakthrough curves showed relatively uniform flow within soil layers. A numerical flow and solute transport model was calibrated on hydraulic heads and tracer breakthrough curves. The model was used to estimate an average accessible porosity of 0.115 for the swept zone and an average longitudinal dispersivity of 0.55 m. The model was further used to optimize the relative effects of viscous forces versus capillary forces under realistic imposed hydraulic gradients and to establish optimal surfactant solution properties. Maximum capillary number (NCa) values between injection and extraction wells were obtained for an injection flow rate of 16 L/min, a total extraction flow rate of 20 L/min, and a surfactant solution with a viscosity of 0.005 Pa?s. The unconfined nature of the aquifer limited further flow rate or viscosity increases that would have led to unrealistic hydraulic gradients. An NCa range of 3.8 × 10?4 to 7.6 × 10?3 was obtained depending on the magnitude of the simulated LNAPL‐water interfacial tension reduction. Finally, surfactant and chase water slug sizing was optimized with a radial form of the simplified Ogata‐Banks analytical solution (Ogata and Banks 1961) so that injected concentrations could be maintained in the entire 5‐spot cell.  相似文献   
44.
E. Morin  H. Yakir 《水文科学杂志》2014,59(7):1353-1362
Abstract

t Spatio-temporal storm properties have a large impact on catchment hydrological response. The sensitivity of simulated flash floods to convective rain-cell characteristics is examined for an extreme storm event over a 94 km2 semi-arid catchment in southern Israel. High space–time resolution weather radar data were used to derive and model convective rain cells that then served as input into a hydrological model. Based on alterations of location, direction and speed of a major rain cell, identified as the flooding cell for this case, the impacts on catchment rainfall and generated flood were examined. Global sensitivity analysis was applied to identify the most important factors affecting the flash flood peak discharge at the catchment outlet. We found that the flood peak discharge could be increased three-fold by relatively small changes in rain-cell characteristics. We assessed that the maximum flash flood magnitude that this single rain cell can produce is 175 m3/s, and, taking into account the rest of the rain cells, the flash flood peak discharge can reach 260 m3/s.
Editor Z.W. Kundzewicz; Guest editor R.J. Moore

Citation Morin, E. and Yakir, H., 2013. Hydrological impact and potential flooding of convective rain cells in a semi-arid environment. Hydrological Sciences Journal, 59 (7), 1275–1284. http://dx.doi.org/10.1080/02626667.2013.841315  相似文献   
45.
 The Mesoproterozoic Rivard minette dyke provides a case example of dyke-parallel fracturing induced by propagation of low-viscosity melts at deep crustal levels. The dyke constitutes a xenolith-choked intrusion breccia and provides samples of an extensive section of the lithosphere underlying the southwestern Grenville Province of Québec at 1.08 Ga. The xenoliths occupy approximately 50% of the volume of the breccia. They are extremely diverse and include pyroxenites and mafic granulites from the upper mantle and lower crust, and Grenvillian gabbroids, gneisses and quartzites. Wall-rock fragments are detached to various extents along dyke-parallel fractures and apophyses. The host lamprophyre magma has a calculated viscosity of ca. 40 Pa·s. Rapid ascent of magma and turbulence are suggested by the presence of large dense fragments and the brittle-to-ductile deformation at the margins of some xenoliths. A minimum ascent velocity of ca. 50 cm·s–1 is estimated from the settling velocity of a 40 cm long pyroxenite xenolith. The progressive addition of xenoliths increased the effective viscosity of the liquid-solid mixture to 103 Pa·s during emplacement. This favoured Bingham behaviour and laminar flow of the magma, and xenolith suspension. Field evidence suggests that xenoliths were formed through (1) early fracturing of wall rock by inelastic deformation during dyke propagation, and (2) continuous delamination of wall rock by intrusion of magma along the dyke-parallel fractures. This led to removal of chilled margins, and to fluid infiltration, partial melting and microbrecciation in the wall rock. Pre-existing discontinuities played a minor role in the fracturing process. Xenoliths may thus be abundant in alkaline magmas not only because these magmas ascend rapidly and can transport xenoliths, but possibly also, because their low viscosities promote intense fracturing of wall rock. Received: 10 June 1995 / Accepted: 10 February 1996  相似文献   
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48.
Documenting hillslope response to hydroclimatic forcing is crucial to our understanding of landscape evolution. The evolution of talus-pediment sequences (talus flatirons) in arid areas was often linked to climatic cycles, although the physical processes that may account for such a link remain obscure. Our approach is to integrate field measurements, remote sensing of rainfall and modeling to link between storm frequency, runoff, erosion and sediment transport. We present a quantitative hydrometeorological analysis of rainstorms, their geomorphic impact and their potential role in the evolution of hyperarid talus-pediment slopes in the Negev desert, Israel. Rainstorm properties were defined based on intensity–duration–frequency curves and using a rainfall simulator, artificial rainstorms were executed in the field. Then, the obtained measured experimental results were up-scaled to the entire slope length using a fully distributed hydrological model. In addition, natural storms and their hydro-geomorphic impacts were monitored using X-band radar and time-lapse cameras. These integrated analyses constrain the rainfall threshold for local runoff generation at rain intensity of 14 to 22 mm h-1 for a duration of five minutes and provide a high-resolution characterization of small-scale runoff-generating rain cells. The current frequency of such runoff-producing rainstorms is ~1–3 per year. However, extending this local value into the full extent of hillslope runoff indicates that it occurs only under rainstorms with ≥ 100-years return interval, or 1% annual exceedance probability. Sheetwash efficiency rises with downslope distance; beyond a threshold distance of ~100 m, runoff during rainstorms with such annual exceedance probability are capable of transporting surface clasts. The erosion efficiency of these discrete rare events highlights their potential importance in shaping the landscape of arid regions. Our results support the hypothesis that a shift in the properties and frequency of extreme events can trigger significant geomorphic transitions in areas that remained hyperarid during the entire Quaternary. © 2020 John Wiley & Sons, Ltd.  相似文献   
49.
The geomorphic evolution of the Jordan River in recent decades indicates that interaction between incision and high-magnitude floods controls sinuosity changes under increasing mouth gradients during base-level fall. The evolution of the river was analyzed based on digital elevation models, remotely sensed imagery, hydrometric data, and a hydraulic model. The response varies along the river. Near the river mouth, where incision rate is high and a deep channel forms, overbank flooding is less likely. There, large floods exert high shear stress within the confined channel, increasing sinuosity. Upstream, near the migrating knickzone channel gradients also increase, incision is more moderate and floods continue to overtop the banks, favoring meander chute cutoffs. The resulting channel has a downstream well-confined meandering segment and an upstream low-sinuosity segment. These new insights regarding spatial differences along an incising channel can improve interpretations of the evolution of ancient planforms and floodplains that responded to base-level decline. © 2018 John Wiley & Sons, Ltd.  相似文献   
50.
We investigate the problem of balancing model complexity and input data requirements in snow hydrology. For this purpose, we analyze the performance of two models of different complexity in estimating variables of interest in snow hydrology applications. These are snow depth, bulk snow density, snow water equivalent and snowmelt run‐off. We quantify the differences between data and model prediction using 18 years of measurements from an experimental site in the French Alps (Col de Porte, 1325 m AMSL). The models involved in this comparison are a one‐layer temperature‐index model (HyS) and a multilayer model (Crocus). Results show that the expected loss in performance in the one‐layer temperature‐index model with respect to the multilayer model is low when considering snow depth, snow water equivalent and bulk snow density. As for run‐off, the comparison returns less clear indications for identification of a balance. In particular, differences between the models' prediction and data with an hourly resolution are higher when considering the Crocus model than the HyS model. However, Crocus is better at reproducing sub‐daily cycles in this variable. In terms of daily run‐off, the multilayer physically based model seems to be a better choice, while results in terms of cumulative run‐off are comparable. The better reproduction of daily and sub‐daily variability of run‐off suggests that use of the multilayer model may be preferable for this purpose. Variation in performance is discussed as a function of both the calibration solution chosen and the time of year. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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