Effects of different crystal faces on the surface charge of colloidal goethite (α-FeOOH) particles: an experimental and modeling study     

Fabien Gaboriaud  Jean-Jacques Ehrhardt 《Geochimica et cosmochimica acta》2003,67(5):967-983

The surface charge of colloidal particles is usually determined by potentiometric titration. These acid-base titrations make it possible to measure the pH of point-of-zero charge (pzc) for oxide minerals. This macroscopic property is the most important parameter used in surface complexation modeling to reproduce experimental data. The pzc values of goethite reported in the literature vary between 7.0 and 9.5. Carbonate adsorption and/or surface morphology are thought to account for this wide range.We demonstrate a procedure for the removal of the carbonate ions that initially adsorb on goethite and strongly affect the titration curves and pzc determination. We also investigated the crystal-face-specific reactivity of two morphologically different goethites. The z-profiles obtained from atomic force microscopy (AFM) images showed that the goethite with the smallest specific surface area (S = 49 m²/g, denoted G49) exhibits 70% of the (001) face, whereas this value is only 30% for the goethite with largest specific surface area (S = 95 m²/g, denoted G95). This morphologic difference results in slightly different pzc values: 9.0 for G49 goethite and 9.1 for G95 geothite. These experimental pzc values have been correlated with multisite complexation calculations using both the full-site and the 1-pK approaches. We used the full-site approach to consider all of the configurations of hydrogen bond interactions with surface site. The resulting mean charges gave estimated pzc values of 8.9 and 9.2 for the (001) and (101) faces, respectively. Considering these theoretical pzc values for individual faces and the face distributions obtained from AFM analysis, the calculated pzc values are in full agreement with the experimental pzc values. However, this morphologic difference is more expressed in surface charge values than in the pzc values. Indeed, the surface charge of G49 goethite is much higher than that of G95 goethite, and the 1-pK calculations make it possible to fit the titration data satisfactorily.  相似文献   

A red algal bloom in the aftermath of the Marinoan Snowball Earth     

Marcel Elie  Afonso C.R. Nogueira  Anne Ndlec  Ricardo I.F. Trindade  Fabien Kenig 《地学学报》2007,19(5):303-308

Organic matter from the cap dolostones overlying the Marinoan‐age glacigenic diamictites of the Araras Group, Amazon craton, has been studied to reconstruct the post‐glacial ecosystem. Molecular fossils indicate that the post‐Marinoan ecosystem was marked by an apparent decline in marine algal diversity. The proliferation of red algae may be explained by environmental changes, such as a massive nutrient input accompanying continental weathering after the ice thaw and a dimer light penetrating sea water due to the drowning of the platform. In addition, the presence of green sulphur bacteria indicates that sea water was stratified with an anoxic (possibly euxinic, i.e. sulphidic) layer at the water–sediment interface. Sulphur cycling probably occurred at the redox boundary as suggested by the recognition of active sulphate reduction. This observation supports a microbially induced model for the formation of the cap dolostones.  相似文献   

Anhydrite–gypsum transition in the argillites of flooded salt workings in eastern France     

Elie Boidin  Françoise Homand  Fabien Thomas  Jacques Yvon 《Environmental Geology》2009,58(3):531-542

This study aims at understanding the physico-chemical interactions between the saturated brine and the rocks enclosing the underground salt workings in Lorraine (eastern France). These anhydrite-rich and argillaceous rocks were characterized in terms of mineralogy, micro-texture and connected porosity. Then, the two main lithofacies, massive anhydrite and anhydrite-rich argillite, were immersed in brine during more than 1 year. During this batch experiment, the argillites were affected by macroscopic splitting, contrarily to the massive anhydrite. Micro-texture and brine chemical analyses clearly show the swelling due to the hydration of anhydrite into gypsum inside the argillites, whereas hydration occurs superficially on the massive anhydrite, due to its very low permeability. Anhydrite–gypsum transformation is promoted by the presence of dissolved strontium and potassium in saturated brine. The low activity of water in saturated brine does not allow the clay fraction to swell significantly during the experiment. Thus, the expansion resulting from the hydration of anhydrite into gypsum might be responsible of the splitting of argillite in a saturated brine environment. The superficial anhydrite hydration on massive anhydrite can be explained by the low amount of connected porosity (less than 1%).  相似文献   

Numerical resolution of well-balanced shallow water equations with complex source terms   总被引：3，自引：0，他引：3  

Qiuhua Liang  Fabien Marche 《Advances in water resources》2009

This paper presents a well-balanced numerical scheme for simulating frictional shallow flows over complex domains involving wetting and drying. The proposed scheme solves, in a finite volume Godunov-type framework, a set of pre-balanced shallow water equations derived by considering pressure balancing. Non-negative reconstruction of Riemann states and compatible discretization of slope source term produce stable and well-balanced solutions to shallow flow hydrodynamics over complex topography. The friction source term is discretized using a splitting implicit scheme. Limiting value of the friction force is derived to ensure stability. This new numerical scheme is validated against four theoretical benchmark tests and then applied to reproduce a laboratory dam break over a domain with irregular bed profile.  相似文献   

Regional flow simulation in fractured aquifers using stress-dependent parameters   总被引：2，自引：0，他引：2  

Preisig G  Joel Cornaton F  Perrochet P 《Ground water》2012,50(3):376-385

A model function relating effective stress to fracture permeability is developed from Hooke's law, implemented in the tensorial form of Darcy's law, and used to evaluate discharge rates and pressure distributions at regional scales. The model takes into account elastic and statistical fracture parameters, and is able to simulate real stress-dependent permeabilities from laboratory to field studies. This modeling approach gains in phenomenology in comparison to the classical ones because the permeability tensors may vary in both strength and principal directions according to effective stresses. Moreover this method allows evaluation of the fracture porosity changes, which are then translated into consolidation of the medium.  相似文献   

10Be‐derived assessment of accelerated erosion in a glacially conditioned inner gorge,Entlebuch, Central Alps of Switzerland     

Fabien Van den Berg  Fritz Schlunegger  Naki Akçar  Peter Kubik 《地球表面变化过程与地形》2012,37(11):1176-1188

Inner gorges often result from the propagation of erosional waves related to glacial/interglacial climate shifts. However, only few studies have quantified the modern erosional response to this glacial conditioning. Here, we report in situ ¹⁰Be data from the 64 km² Entlen catchment (Swiss Alps). This basin hosts a 7 km long central inner gorge with two tributaries that are >100 m‐deeply incised into thick glacial till and bedrock. The ¹⁰Be concentrations measured at the downstream end of the gorge yield a catchment‐wide erosion rate of 0.42 ± 0.04 mm yr^‐1, while erosion rates are consistently lower upstream of the inner gorge, ranging from 0.14 ± 0.01 mm yr^‐1 to 0.23 ± 0.02 mm yr^‐1. However, ¹⁰Be‐based sediment budget calculations yield rates of ~1.3 mm yr^‐1 for the inner gorge of the trunk stream. Likewise, in the two incised tributary reaches, erosion rates are ~2.0 mm yr^‐1 and ~1.9 mm yr^‐1. Moreover, at the erosional front of the gorge, we measured bedrock incision rates ranging from ~2.5 mm yr^‐1 to ~3.8 mm yr^‐1. These rates, however, are too low to infer a post‐glacial age (15–20 ka) for the gorge initiation. This would require erosion rates that are between 2 and 6 times higher than present‐day estimates. However, the downcutting into unconsolidated glacial till favored high erosion rates through knickzone propagation immediately after the retreat of the LGM glaciers, and subsequent hillslope relaxation led to a progressive decrease in erosion rates. This hypothesis of a two‐ to sixfold decrease in erosion rates does not conflict with the ¹⁰Be‐based erosion rate budgets, because the modern erosional time scale recorded by ¹⁰Be cover the past 2–3 ka only. These results point to the acceleration of Holocene erosion in response to the glacial overprint of the landscape. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Interferometry basics in practice: Exercises     

Florentin Millour  Damien Sgransan  Jean-Philippe Berger  Gilles Duvert  Fabien Malbet 《New Astronomy Reviews》2008,52(2-5):208

The following exercises aim to learn the link between the object intensity distribution and the corresponding visibility curves of a long-baseline optical interferometer. They are also intended to show the additional constraints on observability that an interferometer has.This practical session is meant to be carried out with the ASPRO software, from the Jean-Marie Mariotti Center, but can also be done using other observation preparation software, such as viscalc from ESO.There are two main parts with series of exercises and the exercises corrections. The first one aims at understanding the visibility and its properties by practicing with simple examples, and the second one is about UV coverage.  相似文献   

Regional Flow and Deformation Analysis of Basin‐Fill Aquifer Systems Using Stress‐Dependent Parameters     

Giona Preisig  Fabien Joel Cornaton  Pierre Perrochet 《Ground water》2014,52(1):125-135

Changes in effective stress due to water pressure variations modify the intrinsic hydrodynamic properties of aquifers and aquitards. Overexploited groundwater systems, such as basins with heavy pumping, are subject to nonrecoverable modifications. This results in loss of permeability, porosity, and specific storage due to system consolidation. This paper presents (1) the analytical development of model functions relating effective stress to hydrodynamic parameters for aquifers and aquitards constituted of unconsolidated granular sediments, and (2) a modeling approach for the analysis of aquifer systems affected by effective stress variations, taking into account the aforementioned dependency. The stress‐dependent functions were fit to laboratory data, and used in the suggested modeling approach. Based on only few unknowns, this approach is computationally simple, efficiently captures the hydromechanical processes that are active in regional aquifer systems under stress, and readily provides an estimate of their consolidation.  相似文献   

Response of estuarine meio- and macrofauna to in situ bioremediation of oil-contaminated sediment     

Schratzberger M  Daniel F  Wall CM  Kilbride R  Macnaughton SJ  Boyd SE  Rees HL  Lee K  Swannell RP 《Marine pollution bulletin》2003,46(4):430-443

Numerous studies have demonstrated the efficacy of bioremediation for enhancing oil removal but the ecological effect on shoreline biota is unclear. Therefore, a field experiment was designed at an intertidal sandflat in SW England to assess the effects of nutrient addition to oiled sediments on meio- and macrofauna for a period of up to 45 weeks. Natural assemblages were exposed to different types of experimental treatments (no oil, oil alone, oil treated with slow-release fertiliser or liquid fertiliser). Bioremediation stimulated the microbial population and increased oil biodegradation. This, however, did not result in faster recolonisation rates of fertilised versus non-fertilised oiled sediments. Mild effects of oil and bioremediation treatments on benthic fauna were observed, including short-term shifts in dominance patterns. Decreased abundance of dominant species in the oiled compared to unoiled sediments resulted in significantly higher evenness of benthic assemblages within the first 11 weeks of the experiment.  相似文献   

Stable Carbon and Nitrogen Isotopic     

Jennifer Lawson  Peter T Doran  Fabien Kenig  David J Des marais  John C Priscu 《Aquatic Geochemistry》2004,10(3-4):269-301

The perennially ice-covered lakes in the McMurdo Dry Valleys, Antarctica, are part of the coldest and driest ecosystem on earth. To understand lacustrine carbon and nitrogen cycling in this end-member ecosystem, and to define paleolimnological proxies for ice-covered lakes, we measured the stable carbon and nitrogen isotopic composition of particulate organic matter (POM) and benthic organic matter (BOM) within the lakes of Taylor Valley. The ¹³C compositions of seasonally ice-free edges of the lakes (moats) are enriched relative to under-ice organic matter. Thus, the organic carbon isotopic composition of buried sediments may be a proxy for sample position within the lake. In the moats, ¹³C values are governed by limited CO₂diffusion across benthic cyanobacterial cell membranes. During a high glacial melt (2001–2002) season, both ¹³C_POM and ¹³C_BOM in the moats were more depleted than during previous low melt years. We propose that this occurred in response to higher [CO₂]_(aq) and/or reduced growth rates resulting from turbidity-induced light limitation. Though moats and under-ice environments are usually poorly connected, during the 2001–2002 season, the enrichment of the ¹³C_POM values at 6 m depth in the stream-proximal sites relative to deep-profile sites implies enhanced connectivity between these environments. The ¹³C compositions of BOM and POM profiles in Lake Hoare and Lake Fryxell indicate that these lakes are dominated by benthic productivity. In contrast, in Lake Bonney, the similarity of the ¹³C values of BOM and POM indicates the pelagic component dominance in the carbon cycle.  相似文献