The quantitative analysis of OH in vesuvianite: a polarized FTIR and SIMS study     

Fabio Bellatreccia  Giancarlo Della Ventura  Luisa Ottolini  Eugen Libowitzky  Anton Beran 《Physics and Chemistry of Minerals》2005,32(1):65-76

A well-characterized suite of vesuvianite samples from the volcanic ejecta (skarn or syenites) from Latium (Italy) was studied by single-crystal, polarized radiation, Fourier-transform infrared (FTIR) spectroscopy and secondary-ion mass-spectrometry (SIMS). OH-stretching FTIR spectra consist of a rather well-defined triplet of broad bands at higher-frequency (3,700–3,300 cm^–1) and a very broad composite absorption below 3,300 cm^–1. Measurements with E//c or Ec show that all bands are strongly polarized with maximum absorption for E//c. They are in agreement with previous band assignments (Groat et al. Can Mineral 33:609, 1995) to the two O(11)–H(1) and O(10)–H(2) groups in the structure. Pleochroic measurements with changing direction of the E vector of the incident radiation show that the orientation of the O(11)–H(1) dipole is OHc~35°, in excellent agreement with the neutron data of Lager et al. (Can Mineral 37:763, 1999). A SIMS-based calibration curve at ~10% rel. accuracy has been worked out and used as reference for the quantitative analysis of H₂O in vesuvianite by FTIR. Based on previous SIMS results for silicate minerals (Ottolini and Hawthorne in J Anal At Spectrom 16:1266, 2001; Ottolini et al. in Am Mineral 87:1477, 2002) the SiO₂ and FeO content of the matrix were assumed as the major factors to be considered at a first approximation in the selection of the standards for H. The lack of vesuvianite standards for quantitative SIMS analysis of H₂O has been here overcome by selecting low-silica elbaite crystals (Ottolini et al. in Am Mineral 87:1477, 2002). The resulting integrated molar absorption FTIR coefficient for vesuvianite is _i=100.000±2.000 l mol^–1 cm^–2. SIMS data for Li, B, F, Sr, Y, Be, Ba REE, U and Th are also provided in the paper.  相似文献   

Effects of the Magnetic Field on the Hα Emission from Jets     

Fabio de Colle  Alejandro Raga 《Astrophysics and Space Science》2004,293(1-2):173-180

We present results of MHD axisymmetrical cylindrical simulations performed to study Hα emission maps from jets, with a toroidal field geometry for the magnetic field. Our code uses a linear Riemann solver, integrates equations in 2.5 dimensions and includes the calculation of the ionization fraction and the effects of the emission due to the collisional excitation of [O I] and [O II] lines, radiative recombination of H and the collisional ionization of H and excitation of Lyman-α. The simulations with variable ejection velocities show that the magnetic field produces an increase in the emission from all of the knots except for the first bow shock.  相似文献   

European projects for innovative GNSS-related applications     

Paolo?MulassanoEmail author  Fabio?Dovis  Frederic?Collomb 《GPS Solutions》2004,7(4):268-270

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Rainfall stochastic modeling for runoff forecasting     

Fabio Russo  Federico Lombardo  Eugenio Gorgucci 《Physics and Chemistry of the Earth》2006,31(18):1252-1261

Rainfall fields estimation over a catchment area is an important stage in many hydrological applications. In this context, weather radars have several advantages because a single-site can scan a vast area with very high temporal and spatial resolution. The construction of weather radar systems with dual polarization capability allowed progress on radar rainfall estimation and its hydro-meteorological applications. For these applications of radar data it is necessary to remove the ground clutter contamination with an algorithm based on the backscattering signal variance of the differential reflectivity. The calibration of the GDSTM model (Gaussian Displacements Spatial-Temporal Model), a cluster stochastic generation model in continuous space and time, is herewith presented. In this model, storms arrive in a Poisson process in time with cells occurring in each storm that cluster in space and time. The model is calibrated, using data collected by the weather radar Polar 55C located in Rome, inside a square area of 132 × 132 km², with the radar at the centre. The GDSTM is fitted to sequences of radar images with a time interval between the PPIs scans of 5 min. A generalized method of moment procedure is used for parameter estimation. For the validation of the ability of the model to reproduce internal structure of rain event, a geo-morphological rainfall-runoff model, based on width function (WFIUH), was calibrated using simulated and observed data. Several rainfall fields are generated with the stochastic model and later they are used as input of the WFIUH model so that the forecast discharges can be compared to the observed ones.  相似文献   

Estimation of green grass/herb biomass from airborne hyperspectral imagery using spectral indices and partial least squares regression   总被引：7，自引：0，他引：7  

Moses Azong Cho  Andrew Skidmore  Fabio Corsi  Sipke E. van Wieren  Istiak Sobhan   《International Journal of Applied Earth Observation and Geoinformation》2007,9(4):414-424

The main objective was to determine whether partial least squares (PLS) regression improves grass/herb biomass estimation when compared with hyperspectral indices, that is normalised difference vegetation index (NDVI) and red-edge position (REP). To achieve this objective, fresh green grass/herb biomass and airborne images (HyMap) were collected in the Majella National Park, Italy in the summer of 2005. The predictive performances of hyperspectral indices and PLS regression models were then determined and compared using calibration (n = 30) and test (n = 12) data sets. The regression model derived from NDVI computed from bands at 740 and 771 nm produced a lower standard error of prediction (SEP = 264 g m⁻²) on the test data compared with the standard NDVI involving bands at 665 and 801 nm (SEP = 331 g m⁻²), but comparable results with REPs determined by various methods (SEP = 261 to 295 g m⁻²). PLS regression models based on original, derivative and continuum-removed spectra produced lower prediction errors (SEP = 149 to 256 g m⁻²) compared with NDVI and REP models. The lowest prediction error (SEP = 149 g m⁻², 19% of mean) was obtained with PLS regression involving continuum-removed bands. In conclusion, PLS regression based on airborne hyperspectral imagery provides a better alternative to univariate regression involving hyperspectral indices for grass/herb biomass estimation in the Majella National Park.  相似文献   

Sequence of instability processes triggered by heavy rainfall in the northern Italy   总被引：3，自引：0，他引：3  

Fabio Luino   《Geomorphology》2005,66(1-4):13

Northern Italy is a geomorphologically heterogeneous region: high mountains, wide valleys, gentle hills and a large plain form a very varied landscape and influence the temperate climate of the area. The Alps region has harsh winters and moderately warm summers with abundant rainfall. The Po Plain has harsh winters with long periods of subfreezing temperatures and warm sultry summers, with rainfall more common in winter.Geomorphic instability processes are very common. Almost every year, landslides, mud flows and debris flows in the Alpine areas and flooding in the Po flood plain cause severe damage to structures and infrastructure and often claim human lives. Analyses of major events that have struck northern Italy over the last 35 years have provided numerous useful data for the recognition of various rainfall-triggering processes and their sequence of development in relation to the intensity and duration of rainfall. Findings acquired during and after these events emphasise that the quantity and typology of instability processes triggered by rainfall are related not only to an area's morphological and geological characteristics but also to intense rainfall distribution during meteorological disturbances. Moreover, critical rainfall thresholds can vary from place to place in relation to the climatic and geomorphological conditions of the area. Once the threshold has been exceeded, which is about 10% of the local mean annual rainfall (MAR), the instability processes on the slopes and along the hydrographic networks follow a sequence that can be reconstructed in three different phases.In the first phase, the initial instability processes that can usually be observed are soil slips on steep slopes, mud–debris flows in small basins of less than 20 km² in area, while discharge increases substantially in larger stream basins of up to 500 km². In continuous precipitation, in the second phase, first mud–debris flows can be triggered also in basins larger than 20 km² in area. Tributaries swell the main stream, which is already in a critical condition. The violent flow causes severe problems mainly along valley bottoms of rivers with basins up to 2000 km² in area. First bedrock landslides can occur, reaching a considerable area density, with volumes from a few hundred up to about one to two million cubic meters. In continuous precipitation, in the third phase, basins of more than 2000 km² in area reach their first critical stage. River-bed morphology is extensively modified, with erosional and depositional processes which can locally undermine the stability of structures and infrastructures. Waters overflow levees, flooding villages and towns to various widths and depths and sometimes claiming casualties. Some days after an intense rainfall period, large landslides involving the bedrock can still take place. These processes usually cause the movement of very large rock masses. The total duration of rainfall usually has a greater effect on these landslides than does the number of short periods of very intensive precipitation. This sequence cannot be divided into separate phases when the events occur simultaneously because of the presence of intense rainfall pulses and the generation of very diffuse surface runoff. Such situations usually happen during short-lasting heavy summer rainstorms or in late spring, when snow melt combines with intense rainfall. The three-phase sequence has been identified in three severe events that are analysed in this paper: Valtellina (Lombardy) in 1987, Tanaro Valley (Piedmont) in 1994 and Aosta Valley in 2000; but this sequence has also been observed during other events that occurred in northern Italy: in Piedmont in 1968, 1977, 1978, 1993 and 2000; in Lombardy in 1983 and 1992; in the Aosta Valley in 1993.  相似文献   

The interplay of geomorphic processes and soil development in an upland environment, Calabria, South Italy   总被引：1，自引：0，他引：1  

Fabio Scarciglia  Emilia Le Pera  Giuseppe Vecchio  Salvatore Critelli   《Geomorphology》2005,69(1-4):169-190

Five representative soil profiles outcropping in the area around the Cecita Lake (Calabria, South Italy) were characterised by field work, chemical and mineralogical analyses, optical and scanning electron microscopy. Interactions among weathering, pedogenesis and geomorphic processes are emphasised, in an attempt to link the results obtained at different scales of observation. The important role of topography in controlling soil development or removal by erosive processes is discussed, in relation to the natural geomorphological context and the effects of human pressure. Both present-day and relict features were recognised in the studied soils, and discussed in terms of environmental conditions and climatic changes. The chemical composition of volcanoclastic components identified in some soil horizons with Andosol-like field appearance, coupled with pedogenetic features, contributed useful chronological constraints for the reconstruction of Late Quaternary geomorphic events.  相似文献   

Poisson's ratio at high pore pressure   总被引：1，自引：0，他引：1  

José M. Carcione  Fabio Cavallini 《Geophysical Prospecting》2002,50(1):97-106

Laboratory investigations suggest that a precise relationship exists between Poisson's ratio, pore pressure and fluid type. Values of Poisson's ratio for dry samples are significantly smaller than those for fluid-saturated samples. The values are anomalously high for high pore pressure, with the possibility of differentiating between gas-saturated, brine-saturated and oil-saturated porous rocks.
The present study considers two overpressure models, based on oil/gas conversion and disequilibrium compaction, to obtain Poisson's ratio versus differential pressure (confining pressure minus pore pressure). The model results are in good agreement with experiments. Poisson's ratio is approximately constant at high differential pressures and increases (decreases) for saturated (dry) rocks at low differential pressures. Fluid type can be determined at all differential pressures from Poisson's ratio. The analysis is extended to the anisotropic case by computing the three Poisson's ratios of a transversely isotropic rock versus differential pressure. While one of them is practically independent of effective pressure, the others increase with increasing pore pressure. Experiments performed on cores under different pressure conditions, and calibration of the models with these data, provide a tool for inverting pore pressure from seismic data.  相似文献   

Paleomagnetism of Jurassic to Miocene sediments from the Apenninic carbonate platform (southern Apennines, Italy): evidence for a 60° counterclockwise Miocene rotation     

Jérôme Gattacceca  Fabio Speranza 《Earth and Planetary Science Letters》2002,201(1):19-34

The tectonic evolution of the Apennine belt/southern Tyrrhenian Sea system is addressed through a paleomagnetic study of Lias to Langhian sediments from the Apenninic carbonate platform (southern Apennines, Italy). Reliable paleomagnetic data gathered from 21 sites document a regional-scale post-Langhian 80° counterclockwise (CCW) rotation. Since previous studies of the Plio-Pleistocene clays spread over the orogen had shown a ∼20°CCW rotation, we conclude that the southern Apennines rotated by 60° during Middle-Late Miocene. Our data provide evidence that the southeastward drift of Calabrian block (and synchronous spreading of the southern Tyrrhenian Sea) induced ‘saloon door’ like deformation of the southern Apennines and Sicily, which underwent similar magnitude (although opposite in sign) orogenic rotations. A paleomagnetically derived paleogeographic reconstruction shows that at 15 Ma (Late Langhian) the Alpine-Apennine belt collided with a NNE-oriented carbonate platform corridor surrounded by oceanic basins. We speculate that both the end of the Corsica-Sardinia rotation and the eastward jump of the locus of back-arc extension (from the Liguro-Provençal to the Tyrrhenian Sea) may have been consequences of this event.  相似文献   

Paleomagnetic analysis of curved thrust belts reproduced by physical models     

Elisabetta Costa  Fabio Speranza   《Journal of Geodynamics》2003,36(5):633-654

This paper presents a new methodology for studying the evolution of curved mountain belts by means of paleomagnetic analyses performed on analogue models. Eleven models were designed aimed at reproducing various tectonic settings in thin-skinned tectonics. Our models analyze in particular those features reported in the literature as possible causes for peculiar rotational patterns in the outermost as well as in the more internal fronts. In all the models the sedimentary cover was reproduced by frictional low-cohesion materials (sand and glass micro-beads), which detached either on frictional or on viscous layers. These latter were reproduced in the models by silicone. The sand forming the models has been previously mixed with magnetite-dominated powder. Before deformation, the models were magnetized by means of two permanent magnets generating within each model a quasi-linear magnetic field of intensity variable between 20 and 100 mT. After deformation, the models were cut into closely spaced vertical sections and sampled by means of 1×1-cm Plexiglas cylinders at several locations along curved fronts. Care was taken to collect paleomagnetic samples only within virtually undeformed thrust sheets, avoiding zones affected by pervasive shear. Afterwards, the natural remanent magnetization of these samples was measured, and alternating field demagnetization was used to isolate the principal components. The characteristic components of magnetization isolated were used to estimate the vertical-axis rotations occurring during model deformation. We find that indenters pushing into deforming belts from behind form non-rotational curved outer fronts. The more internal fronts show oroclinal-type rotations of a smaller magnitude than that expected for a perfect orocline. Lateral symmetrical obstacles in the foreland colliding with forward propagating belts produce non-rotational outer curved fronts as well, whereas in between and inside the obstacles a perfect orocline forms only when the ratio between obstacles' distance and thickness of the cover is greater than 10. Finally, when a belt collides with an obstacle in the foreland oblique to the shortening direction the outer front displays rotations opposite in sign to oroclinal-type rotations, whereas the internal fronts seem to assume an “oroclinal type” rotational pattern. Furthermore rotation is easier in laterally unconfined models, i.e. when the wedge can “escape” laterally. The results from our models may be useful when compared to paleomagnetic rotations detected in natural arcs. In these cases, our results may allow for better understanding the tectonic setting controlling the genesis of curved mountain fronts, as is the case of the Gela Nappe of Sicily we compare with some of our models.  相似文献