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71.
72.
Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.  相似文献   
73.
We present global lithological maps of the Vestan surface based on Dawn mission's Visible InfraRed (VIR) Spectrometer acquisitions with a spatial sampling of 200 m. The maps confirm the results obtained with the data set acquired by VIR with a spatial sampling of 700 m, that the reflectance spectra of Vesta's surface are dominated by pyroxene absorptions that can be interpreted within the context of the distribution of howardites, eucrites, and diogenites (HEDs). The maps also partially agree with the ground and Hubble Space Telescope observations: they confirm the background surface being an assemblage of howardite or polymict eucrite, as well as the location of a diogenitic‐rich spot; however, there is no evidence of extended olivine‐rich regions in the equatorial latitudes. Diogenite is revealed on the Rheasilvia basin floor, indicating that material of the lower crust/mantle was exposed. VIR also detected diogenites along the scarp of Matronalia Rupes, and the rims of Severina and a nearby, unnamed crater, and as ejecta of Antonia crater. The diogenite distribution is fully consistent with petrological constraints; although the mapped distribution does not provide unambiguous constraints, it favors the hypothesis of a magma ocean.  相似文献   
74.
The compressibility at room temperature and the thermal expansion at room pressure of two disordered crystals (space group C2/c) obtained by annealing a natural omphacite sample (space group P2/n) of composition close to Jd56Di44 and Jd55Di45, respectively, have been studied by single-crystal X-ray diffraction. Using a Birch–Murnaghan equation of state truncated at the third order [BM3-EoS], we have obtained the following coefficients: V 0 = 421.04(7) Å3, K T0 = 119(2) GPa, K′ = 5.7(6). A parameterized form of the BM3 EoS was used to determine the axial moduli of a, b and c. The anisotropy scheme is β c  ≤ β a  ≤ β b , with an anisotropy ratio 1.05:1.00:1.07. A fitting of the lattice variation as a function of temperature, allowing for linear dependency of the thermal expansion coefficient on the temperature, yielded αV(1bar,303K) = 2.64(2) × 10−5 K−1 and an axial thermal expansion anisotropy of α b  ≫ α a  > α c . Comparison of our results with available data on compressibility and thermal expansion shows that while a reasonable ideal behaviour can be proposed for the compressibility of clinopyroxenes in the jadeite–diopside binary join [K T0 as a function of Jd molar %: K T0 = 106(1) GPa + 0.28(2) × Jd(mol%)], the available data have not sufficient quality to extract the behaviour of thermal expansion for the same binary join in terms of composition.  相似文献   
75.
76.
A comparison of seismic risk maps for Italy   总被引:5,自引:3,他引:2  
National seismic risk maps are an important risk mitigation tool as they can be used for the prioritization of regions within a country where retrofitting of the building stock or other risk mitigation measures should take place. The production of a seismic risk map involves the convolution of seismic hazard data, vulnerability predictions for the building stock and exposure data. The seismic risk maps produced in Italy over the past 10 years are compared in this paper with recent proposals for seismic risk maps based on state-of-the-art seismic hazard data and mechanics-based vulnerability assessment procedures. The aim of the paper is to open the discussion for the way in which future seismic risk maps could be produced, making use of the most up-to-date information in the fields of seismic hazard evaluation and vulnerability assessment.  相似文献   
77.
In order to assess the response of benthic foraminifera to trace element pollution, a study of benthic foraminiferal assemblages was carried out into sediment samples collected from the Santa Gilla lagoon (Sardinia, Italy). The lagoon has been contaminated by industrial waste, mainly trace elements, as well as by agricultural and domestic effluent. The analysis of surficial sediment shows enrichment in trace elements, including Cr, Cu, Hg, Ni, Pb and Zn. Biotic and abiotic data, analyzed with multivariate techniques of statistical analysis, reveal a distinct separation of both the highly polluted and less polluted sampling sites. The innermost part of the lagoon, comprising the industrial complex at Macchiareddu, is exposed to a high load of trace elements which are probably enhanced by their accumulation in the finer sediment fraction. This area reveals lower diversity and higher percentages of abnormalities when compared to the outermost part of the lagoon.  相似文献   
78.
79.
In lavas spanning ~ 10Ma of subduction-related volcanism in Western Anatolia, we observe remarkably similar patterns of δ7Li and δ11B variation. In this setting, magmatism records a transition from calc–alkaline to ultrapotassic character, consistent with overall lower mean extents of melting, and a changing mantle source that reflects a fractionating, higher temperature slab input consistent with the gradual cessation of subduction. Subsequent rift-related intraplate magmatism record δ7Li signatures within the range observed for MORBs and OIBs, indicating an abrupt transition to a mantle source unmodified by subduction.  相似文献   
80.
We use a passive seismic high-frequency receiver function method to image the shallow structure around a mine site. This is a relatively new application of a standard method for mapping major discontinuities in the crust and upper mantle at a scale small enough to be relevant in an exploration context. Data collected in a 21-instrument array is inverted for isotropic velocity structure. The retrieved velocities in the south-eastern part of the array match very well with available sonic log measurements in the top 800 m. Based on the differences in receiver function behaviour for stations across the array, recovered velocity profiles and their similarity to sonic log measurements, the target area is split into two separate regions along a north-northeast trending line that correlates well to the strike of the dominant structure in the area – the Navan Fault. Our results demonstrate the ability of receiver functions to provide both qualitative and quantitative information in an exploration environment.  相似文献   
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