On the mechanisms for H and Al incorporation in stishovite     

Geoffrey D. Bromiley  Fiona A. Bromiley  David W. Bromiley 《Physics and Chemistry of Minerals》2006,33(8-9):613-621

The solubility and incorporation mechanisms of hydrogen in synthetic stishovite as a function of Al₂O₃ content have been investigated. Mechanisms for H incorporation in stishovite are more complex than previously thought. Most H in stishovite is incorporated via the Smyth et al. (Am Mineral 80:454–456, 1995) model, where H docks close to one of the shared O–O edges, giving rise to an OH stretching band in infrared (IR) spectra at 3,111–3,117 cm⁻¹. However, careful examination of IR spectra from Al-stishovite reveals the presence of an additional OH band at 3,157–3,170 cm⁻¹. All H is present on one site, with interstitial H both coupled to Al³⁺ substitutional defects on adjacent octahedral (Si⁴⁺) sites, and decoupled from other defects, giving rise to two distinct absorption bands. Trends in IR data as a function of composition are consistent with a change in Al incorporation mechanism in stishovite, with Al³⁺ substitution for Si⁴⁺ charge-balanced by oxygen vacancies at low bulk Al₂O₃ contents, and coupled substitution of Al³⁺ onto octahedral (Si⁴⁺) and interstitial sites at high bulk Al₂O₃ contents. Trends in OH stretching frequencies as a function of Al₂O₃ content suggest that any such change in Al incorporation mechanism could alter the effect that Al incorporation has on the compressibility of stishovite, as noted by Ono et al. (Am Mineral 87:1486–1489, 2002).  相似文献   

Cirque development in a steadily uplifting range: rates of erosion and long‐term morphometric change in alpine cirques in the Ben Ohau Range,New Zealand     

Martin S. Brook  Martin P. Kirkbride  Ben W. Brock 《地球表面变化过程与地形》2006,31(9):1167-1175

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Evidence that polycyclic aromatic hydrocarbons in two carbonaceous chondrites predate parent-body formation     

Fiona L Plows  Richard N Zare  Peter R Buseck 《Geochimica et cosmochimica acta》2003,67(7):1429-1436

Organic material in meteorites provides insight into the cosmochemistry of the early solar system. The distribution of polycyclic aromatic hydrocarbons (PAHs) in the Allende and Murchison carbonaceous chondrites was investigated by use of a technique called microprobe laser-desorption laser-ionization mass spectrometry, which permits spatial resolution with approximately a 40-μm spot size. Sharp chemical gradients of PAHs are associated with specific meteorite features. The ratios of various PAH intensities relative to the smallest PAH, naphthalene, are nearly constant across the sample. These findings suggest a common origin for PAHs dating before or during the formation of the parent body, consistent with proposed interstellar formation mechanisms.  相似文献   

Methods for determining minimum freshwater inflow needs of Texas bays and estuaries     

Gary L. Powell  Junji Matsumoto  David A. Brock 《Estuaries and Coasts》2002,25(6):1262-1274

In response to legislative directives beginning in 1975, the Texas Water Development Board (TWDB) and the Texas Parks and Wildlife Department (TPWD) jointly established and currently maintain a data collection and analytical study program focused on determining the effects of and needs for freshwater inflows into the state's 10 bay and estuary systems. Study elements include hydrographic surveys, hydrodynamic modeling of circulation and salinity patterns, sediment analyses, nutrient analyses, fisheries analyses, freshwater inflow optimization modeling, and verification of needs. For determining the needs, statistical regression models are developed among freshwater inflows, salinities, and coastal fisheries. Results from the models and analyses are placed into the Texas Estuarine Mathematical Programming (TxEMP) model, along with information on salinity viability limits, nutrient budgets, fishery biomass ratios, and inflow bounds. The numerical relationships are solved within the constraints and limits, and optimized to meet state management objectives for maintenance of biological productivity and overall ecological health. Solution curves from the TxEMP model are verified by TWDB’s hydrodynamic simulation of estuarine circulation and salinity structure, which is evaluated against TPWD’s analysis of species abundance and distribution patterns in each bay and estuary system. An adequate system-wide match initially verifies the inflow solution. Long-term monitoring is recommended in order to verify that implementation of future water management strategies maintain ecological health of the estuaries and to provide an early warning of needs for adaptive management strategies.  相似文献   

Crustal structure across the Canadian High Arctic region from teleseismic receiver function analysis   总被引：1，自引：0，他引：1  

Fiona A. Darbyshire 《Geophysical Journal International》2003,152(2):372-391

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Community Cohesion: Social and Economic Ties in the Personal Networks of Fisherfolk     

Fiona Nunan  Dražen Cepić  Bwambale Mbilingi  Konstantine Odongkara  Ernest Yongo  Monica Owili 《社会与自然资源》2018,31(3):306-319

Social ties influence access to knowledge and cooperation in natural resource management, with the sharing of certain characteristics thought to be positive for social cohesion and participatory forms of management. In this article, a holistic characterisation of fisherfolk personal networks is developed, disaggregating results by the main occupational groups within the fisheries studied, to provide a more nuanced understanding of the personal networks of types of fisherfolk. Links are then made between the characteristics of personal networks and evidence on how fisherfolk benefit from their networks, interpreted as contributing to social cohesion within the communities. The personal networks of fisherfolk (boat crew, boat owners and traders/processors) of Kenya, Tanzania and Uganda bordering Lake Victoria were investigated using personal network analysis, with fisherfolk asked who they discuss their fisheries activities with. The analysis found that networks based on the same occupation were more characteristic of fish traders/processors networks than those of boat crew and boat owners and that shared ethnicity, gender and location were characteristic of boat owner and boat crew networks, though shared ethnicity may reflect the composition of the communities rather than choice. Social and economic interactions within the networks were based on provision of credit, social support and advice, suggesting that these form the basis of social cohesion and should be taken into consideration in working with fishing communities in both development interventions and designing collaborative management approaches.  相似文献   

Development of the HEFT and NuSTAR focusing telescopes     

Fiona A. Harrison  Finn E. Christensen  William Craig  Charles Hailey  Wayne Baumgartner  C. M. H. Chen  James Chonko  W. Rick Cook  Jason Koglin  Kristin-Kruse Madsen  Michael Pivavoroff  Steven Boggs  David Smith 《Experimental Astronomy》2005,20(1-3):131-137

Hard X-ray/soft gamma-ray astrophysics is on the verge of a major advance with the practical realization of technologies capable of efficiently focusing X-rays above 10 keV. Hard X-ray focusing telescopes can achieve orders of magnitude improvements in sensitivity compared to the instruments based on coded apertures and collimated detectors that have traditionally been employed in this energy band. Compact focal planes enable high-performance detectors with good spectral resolution to be employed in efficient, low-background configurations. We have developed multilayer coated grazing incidence optics and solid state Cadmium Zinc Telluride focal plane systems for the High Energy Focusing Telescope (HEFT) balloon-borne experiment, and for the Nuclear Spectroscopic Telescope Array (NuSTAR) Small Explorer satellite. In this paper we describe the technologies, telescope designs, and performance of both experiments.  相似文献   

Resolving Power and the OTF     

G. C. Brock 《The Photogrammetric Record》1972,7(39):377-379

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High‐energy sedimentation,Creag Aoil,Spean Bridge,Scotland: implications for meltwater movement and storage during Loch Lomond Stadial (Younger Dryas) ice retreat     

Andrew J. Russell  Fiona S. Tweed  Tim Harris 《第四纪科学杂志》2003,18(5):415-430

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Radiocarbon dating of charcoal from tropical sequences: results from the Niah Great Cave,Sarawak, and their broader implications     

Thomas F. G. Higham  Huw Barton  Chris S. M. Turney  Graeme Barker  Christopher Bronk Ramsey  Fiona Brock 《第四纪科学杂志》2009,24(2):189-197

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