<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite     

Sven-Ulf Weber  Michael Grodzicki  Werner Lottermoser  Günther J. Redhammer  Gerold Tippelt  Johann Ponahlo  Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.  相似文献   

<Superscript>57</Superscript>Fe Mössbauer measurements and electronic structure calculations on natural lawsonites     

S.-U. Weber  M. Grodzicki  C. A. Geiger  W. Lottermoser  G. Tippelt  G. J. Redhammer  M. Bernroider  G. Amthauer 《Physics and Chemistry of Minerals》2007,34(1):1-9

Three natural lawsonites from Syke Rock, Mendocino Co., Reed Ranch, Marin Co., and Blake Gardens, Sonoma Co., all from the Coast Range Region in California, were studied by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe analysis, and X-ray powder diffraction. The samples contain about 0.6, 1.0, and 1.4 wt% of total iron oxide, respectively. ⁵⁷Fe Mössbauer spectra are consistent with the assumption that high-spin Fe³⁺ substitutes for Al in the octahedrally coordinated site. The Mössbauer spectrum of lawsonite from Syke Rock exhibits a second doublet with ⁵⁷Fe hyperfine parameters typical for octahedrally coordinated high-spin Fe²⁺. Electronic structure calculations in the local spin density approximation yield quadrupole splittings for Fe³⁺ in quantitative agreement with experiment indicating, however, that substitution of Al by Fe³⁺ must be accompanied by local distortion around the octahedral site. Model calculations also reproduce the room temperature hyperfine parameters of ferrous high-spin iron assuming the substitution of Ca by Fe²⁺. However, it cannot be excluded that Fe²⁺ may occupy a more asymmetric site within the microstructural cavity occupied by Ca and a H₂O molecule.  相似文献   

The international GLONASS experiment: products, progress and prospects   总被引：2，自引：0，他引：2  

R. Weber  T. A. Springer 《Journal of Geodesy》2001,75(11):559-568

 In October 1998 the IGEX field campaign, the first coordinated international effort to monitor GLONASS satellites on global basis, was started. Currently about 40 institutions worldwide support this effort either by providing GLONASS tracking data or in operating related data and analysis centers. The increasing quality and consistency of the calculated GLONASS orbits (about 25 cm early in 2000), even after the end of the official IGEX field campaign, are shown. Particular attention is drawn to the combination of precise ephemerides in order to generate a robust, reliable and complete IGEX orbits product. Some problems in modeling the effect of solar radiation pressure on GLONASS satellites are demonstrated. Finally, the expected benefits and prospects of the upcoming International GLOnass Service-Pilot Project (IGLOS-PP) of the International GPS Service (IGS) are discussed in more detail. Received: 17 August 2000 / Accepted: 12 April 2001  相似文献   

Growth, ionic and osmotic relations of an Allenrolfea occidentalis population in an inland salt playa of the Great Basin Desert     

Bilquees Gul  Darrell J. Weber  M. Ajmal Khan 《Journal of Arid Environments》2001,48(4):445

Variation in growth, physiology and ionic relations patterns of Allenrolfea occidentalis, a perennial halophyte of dry habitats, was studied under field conditions from May 1996 to November 1997. An A. occidentalis community has a characteristic soil pH of 7·3–8·3. During the two years, the population was exposed to great variations in soil salinity, from 29 to 146 dS m⁻¹, and soil moisture, ranging from drought (9·2%) to wet (19%). The salt concentrations were significantly higher in the surface soil layers than in the subsurface layers. Seasonal changes in dry weight are directly related to soil salinity stress. Allenrolfea occidentalis had greater growth and biomass production under saline conditions. Na⁺and Cl⁻ions were accumulated in plant tissues in much greater amounts than K⁺, Ca²⁺, and Mg²⁺. Soil salinities were significantly reduced at the end of the growing season. Water potentials of the shoots decreased significantly with increasing salinity. The plant (F_v/F_mratio) was more affected by salinity and irradiation levels during the summer period.  相似文献   

Health Risks and Environmental Inequity: A Geographical Analysis of Accidental Releases of Hazardous Materials     

Florence Lansana Margai 《The Professional geographer》2001,53(3):422-434

This study examines the spatial distribution and impact of nonroutine accidental releases of hazardous materials relative to the demographic composition of residents in nearby communities. First, atmospheric dispersion modeling methods are used to delineate the impact zones of worst‐case accidents in two New York counties over the last ten years. Next, using accidental reports for 1997, GIS and statistical operations are used at the census tract level of the two counties to determine whether these incidents disproportionately affected disadvantaged neighborhoods. The results suggest that the areas of high‐impact from accidental releases of hazardous materials are best characterized by a large proportion of families below the poverty line, Hispanics, and other minorities.  相似文献   

Entwicklung eines Enzymimmunoassays zum Nachweis des Herbizids Mecoprop in Trink- und Grundwasser auf der Basis von Antikörpern aus den Eiern von Legehennen     

I. Westfehling  W. Weber  K. Rubach 《洁净——土壤、空气、水》1996,24(3):137-141

Development of an Enzyme Immunoassay for the Detection of Mecoprop in Drinking Water and Groundwater Based on Antibodies Raised in Chicken Egg Yolk Antibodies against mecoprop were isolated from egg yolk of immunized hens and were used for the development of an enzyme-linked immunosorbent assay. We tested assay parameters (pH and concentration of buffer, incubation temperature, kind of enzyme tracer) to optimize the standard curve for mecoprop. By decreasing the pH, the detection limit was reached at a concentration of 0.35 μg/L mecoprop. The concentration for 50% inhibition (50% B/B₀) was 2.8 μg/L. Dichlorprop and the methyl esters of both mecoprop and dichlorprop showed high crossreactivity (165%, 400% and 233%). Antibodies against mecoprop separated from egg yolk were compared to antibodies raised in rabbit for both sensitivity and specificity. Chicken immunoglobulins were found to be less sensitive and specific than the mammalian IgG's.  相似文献   

The effect of low-velocity sediments on the mislocation vectors of the GRF array   总被引：1，自引：0，他引：1  

F. Krüger  M. Weber 《Geophysical Journal International》1992,108(1):387-393

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Experimentally determined mineral-melt partition coefficients for Sc,Y and REE for olivine,orthopyroxene, pigeonite,magnetite and ilmenite   总被引：6，自引：0，他引：6  

Roger L. Nielsen  William E. Gallahan  Florence Newberger 《Contributions to Mineralogy and Petrology》1992,110(4):488-499

Our current lack of understanding of the partitioning behavior of Sc, Y and the REE (rare-earth elements) can be attributed directly to the lack of a sufficiently large or chemically diverse experimental data set. To address this problem, we conducted a series of experiments using several different natural composition lavas, doped with the elements of interest, as starting compositions. Microprobe analyses of orthopyroxene, pigeonite, olivine, magnetite, ilmenite and co-existing glasses in the experimental charges were used to calculate expressions that describe REE partitioning as a function of a variety of system parameters. Using expressions that represent mineral-melt reactions (versus element ratio distribution coefficients) it is possible to calculate terms that express low-Ca pyroxene-melt partitioning behavior and are independent of both pyroxene and melt composition. Compositional variations suggest that Sc substitution in olivine involves either a paired substitution with Al or, more commonly, with vacancies. The partitioning of Sc is dependent both on melt composition and temperature. Our experimentally determined olivine-melt REE Ds (partition coefficients) are similar to, but slightly higher than those reported by McKay (1986) and support their conclusions that olivines are strongly LREE depleted. Y and REE mineral/melt partition coefficients for magnetite range from 0.003 for La to 0.02 for Lu. Ilmenite partition coefficients range from 0.007 for La to 0.029 for Lu. These experimental values are two orders of magnitude lower than many of the published values determined by phenocryst/matrix separation techniques.  相似文献   

Cadomian terranes,wrench faulting and thrusting in the central Europe Variscides: geophysical and geological evidence     

J. B. Edel  K. Weber 《International Journal of Earth Sciences》1995,84(2):412-432

Sixty five per cent of the Paleozoic basement of western and central Europe is hidden by a sedimentary cover and/or sea. This work aims to remove that blanket to detect new structures which could used to build a more comprehensive model of the Variscan orogeny. It is based on the interpretation of various forms of data: (a) published gravity maps corrected for the effects of the crust-mantle boundary topography and light sedimentary basins; (b) aeromagnetic maps; (c) measurements of densities; and (d) induced and remanent magnetizations on rocks from Paleozoic outcrops of the upper Rhenish area. From the northern Bohemian Massif to the eastern Paris Basin, the Saxothuringian is characterized by a 500 km long belt of gravity highs, the most important being the Kraichgau high. Most of the corresponding heavy bodies are buried under a post-early Viséan cover. They are interpreted as relics of Late Proterozoic terranes overlain by an Early to Middle Paleozoic sequence, equivalent to the Bohemian terrane in the Bohemian Massif. The most probable continuation of these dense Bohemian terranes toward the west is the Southern Channel-Northern Brittany Cadomian terrane. The gravity lows are correlated with Variscan granites and pre- and early Variscan metagranites.Gravity and magnetic maps demonstrate large-scale displacement in Devonian-Early Carboniferous times along the parallel and equidistant, NW-SE striking, Vistula, Elbe, Bavarian, Bray and South Armorican dextral wrench faults. In the Vosges-Schwarzwald and Central Massif the faults continue with the east-west striking Lalaye-Lubine-Baden-Baden and Marche faults and with south vergent thrusts. The Bavarian faults shift the Kraichgau terrane by 150 km relative to the Bohemian terrane, whereas the offset of the Northern Brittany Cadomian relative to the Northern Vosges-Kraichgau terranes is estimated at 400 km along the Bray fault. Sinistral wrench faults are the NE-SW striking Sillon Houiller, Rheingraben, Rodl, Vitis and Diendorf faults. The southern Vosges-Schwarzwald Devonian-Dinantian basin is interpreted as a pull-apart basin at the south-easterly extremity of the Bray fault. The Bohemian and Kraichgau body form allochthonous terranes which were thrust over the Saxothuringian crust. Thrusting to the north-west was accompanied by back-thrusting and led to the formation of pop-up structures. Contemporaneous dextral and sinistral wrench faulting resulted in transpressive strain during collision. The zonal structure of the Variscides in the sense of Kossmat (1927) is relevant only to the Rhenohercynian Foreland Belt. Kossmat (1927) already spoke of a Moldanubian Region because it displays no real zonal structure. The Saxothuringian Zone was formed by terrane accretion. Their apparent zonal structure is not a pre-collisional feature, but only the result of accretion and collision.  相似文献   

Zur Auswertung des ebenen Dreischichtenfalles in der Reflexionsseismik durch Potenzreihenentwicklung     

M. Weber  G. Berset 《Pure and Applied Geophysics》1970,80(1):38-47

Zusammenfassung Ein Verfahren zur Bestimmung der im Sinne der Methode der kleinsten Quadrate bestangepassten Schichtparameter an eine gemessene Laufzeitkurve wird angegeben. Es können höchstens drei Parameter berechnet werden, die drei übrigen Parameter müssen bekannt sein. Die Brechung wird exakt berücksichtigt. Das Verfahren ist für Berechnung durch Computer geeignet. Einfache Formeln gestatten eine angenäherte Bestimmung der unbekannten Parameter.

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Summary A procedure for determining the best fitted parameters of a three layer case to a given travel time curve by the least squares method is described. At most three parameters can be calculated, the other three have to be known. Refraction is taken into account exactly. The calculations have to be made with the aid of a computer. The unknown parameters can be determined approximatively by simple formulas.

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