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421.
Amphiboles, orthopyroxenes, and clinopyroxenes dominate the heavy mineral suite of surficial sediments in lower Cook Inlet, Alaska. Sources for these sediments include the igneous arc terrane of the northeast Alaska Range, reworked intrabasinal sediments, and local drainages in lower Cook Inlet. The distribution of these deposits is a reflection of both the tidal currents and the prevailing southerly net movement from the head of Cook Inlet. The heavy mineral studies concur with similar findings from gravel analyses, clay mineral investigations, and quartz microtexture observations.  相似文献   
422.
During RV SONNE cruise SO-79 to the eastern Pacific Ocean, two areas of about 65×80 km in the northern Peru Basin were surveyed with the acoustic mapping systems HYDROSWEEP (bathymetry), PARASOUND (3.5 kHz high-resolution seismic system), and a deep-towed side-scan sonar system. In addition, we sampled sediments using piston and box corers. The data show an unexpected variability of seafloor features: The bathymetry is characterized by an abyssal hill topography with predominately N-S ridges up to 300 m high, and scattered volcanic hills. Moreover, one 2000-m-high seamount was mapped. PARASOUND shows several distinct reflectors within the sediment cover, all of which are attributed to carbonate-rich strata. In the northern area, the uppermost prominent reflector is related to the Mid-Brunhes Event (0.45 Ma) in the sediment cores, while the lowermost represents acoustic basement. In the southern area, the seismic pattern reveals an upper opaque zone and a lower transparent zone. The base of the opaque zone is marked by a distinct reflector which corresponds to a huge carbonate peak (6–7 Ma) in the sediment cores. However, despite this general pattern, the PARASOUND records show a highly variable situation, with the distribution of sediment echo types strongly influenced by the seafloor topography. The side-scan sonar revealed the existence of numerous small volcanic cones up to 25 m high and nearly free of sediment. Additionally, the sonar records show a patchy (up to 800 m across) seafloor reflectiviti. We interpret this patchiness as a local lack of manganese nodule coverage. Volcanic cones and the most distinct nodule-free patches are usually on ridges. We interpret this variability as caused by winnowing and erosion, an interpretation that is supported by the occurrence of outcrops of Tertiary strata. This regional small-scale variability argues for a highly dynamic depositional history of the Peru Basin.  相似文献   
423.
The hazard posed to aquatic organisms by exposure to aromatic amines will depend on their ability to activate or detoxify these potentially genotoxic compounds. We studied the metabolism of four aromatic amines (p-toluidine, aniline, 2-acetylaminofluorene (2-AAF) and 2-aminofluorene (2-AF)) in Bay mussels (Mytilus edulis) to gain an understanding of their metabolic capabilities in vivo. Mussels rapidly accumulated these compounds from the water column and depurated the majority of their steady-state body burdens as metabolites and unmetabolized parent compounds. The biotransformation pathways of [14C]-labeled parent compounds were determined by analyses of depurated metabolites and tissue residues. Biotransformation of p-toluidine and aniline resulted in the formation of their corresponding N-acetylated detoxification products. Mussels converted small amounts of 2-AAF into a deacetylated product (2-AF) and a mutagenically active metabolite (N-hydroxy-2-AF). 2-AF was extensively detoxified via N-acetylation, which limited the amount of primary amine available for activation.  相似文献   
424.
Frequency-domain electromagnetic sensing can be an effective tool for ascertaining subsurface water dynamics. In California, the paucity of available irrigation water, recurrence of drought and presence of indigenous salts within the geological parent materials affect crop health. Subsurface leaching variability analyses were performed using dual dipolar induction surveys and stochastic computations to determine salinity conditions conducive to plant growth. Soils in the study area had randomly variable salinity with elevated salt levels within the substratum. The salinity values were mostly above 300 mS m?1 and some areas exceeded the 1500 mS m?1 level. The leaching conditions across the fields varied generally from 5 to 50%. Both variables showed slightly positive skewness with minutely asymmetrical tailing. The salinity distribution had less peakedness than the leaching distribution. Albeit with spatially dependent variability and skewness, the distribution patterns had low errors. There was a strong and significant correlation (r?=?0.939 at P?<?0.05) between the observed and predicted conductivity data. The leaching variables exhibited directional dependence along vertical and horizontal gradients. Spatial increase in salinity within the substratum conformed to salt leaching and water percolation processes. All observed salinity values within the substratum exceeded salt tolerance threshold limits for major crops and favorable leaching conditions were observed at low salinity levels. Sustainability of agriculture in California is heavily dependent on adequate water use planning and our approach of leaching variability analyses can facilitate water management and crop production by assessing removal of superfluous salts from the soil substratum.  相似文献   
425.
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427.
This paper presents evidence for a limnological response to the Laacher See eruption (LSE) as detected in lake sediments from Nahe, northern Germany. The sediment section of the Allerød period dating to between 13 422 and 12 708 cal. a BP is preserved in annual laminations. Within this section, the LSE was identified as a cryptotephra layer (12 944±44 cal. a BP). Microfacies analysis, continuous high-resolution geochemical measurements and pollen analyses enabled a high-resolution reconstruction of environmental change. The older part of the Allerød (c. 13 422 to 12 943 cal. a BP) was characterized by relatively stable sedimentation conditions. Evidence for windier conditions dating to c. 13 160 to 13 080 cal. a BP probably reflects the Gerzensee oscillation. Pronounced changes of the lake sedimentation followed the LSE. Four unusually thick varves with increased amounts of allochthonous material indicate serious disturbance of the local environment immediately after the LSE, related to increased storminess and/or the occurrence of high intensity rainfall events. A pronounced reduction of biogenic silica accumulation for c. 60 years after the LSE could reflect a period of acidification. Indications of a simultaneous lake level increase until c. 60 years after the LSE are in line with the supposed reduced evapotranspiration associated with cooler conditions. About 120 years after the LSE, increased oxygen access at the lake bottom, allochthonous input and Cl fluxes point to an onset of increasingly stronger westerly winds, probably as a long-term response to the LSE. This supports the idea of a southward shift of the mid-latitude westerlies wind system within the interval between the LSE and the beginning of the Younger Dryas. The pace of the southwards shift of this wind system decreased from 10 km a−1 in the initial phase (40–120 years after LSE) to 6 km a−1 in the later phase (120–200 years after LSE).  相似文献   
428.
Homogeneity, mass fractions of about forty trace elements and Sr isotope composition of Ca carbonate reference materials (RMs) between original and nano‐powdered pellets are compared. Our results using nanosecond and femtosecond LA‐(MC)‐ICP‐MS show that the nano‐pellets of the RMs MACS‐3NP, JCp‐1NP and JCt‐1NP are about a factor of 2–3 more homogeneous than the original samples MACS‐3, JCp‐1 and JCt‐1, and are therefore much more suitable for microanalytical purposes. With the exception of Si, the mass fractions of the synthetic RM MACS‐3 agree with its fine‐grained analogue MACS‐3NP. Very small, but significant, differences between original and nano‐pellets are observed in the RMs JCp‐1 and JCt‐1 for some trace elements with very low contents, indicating the need for re‐certification. Strontium mass fractions in the analysed RMs are high (1500–7000 mg kg?1), and their isotope compositions determined by LA‐MC‐ICP‐MS in the original and the nano‐pellets agree within uncertainty limits.  相似文献   
429.
The present study evaluated the interactive effects of cadmium contamination and pathogenic organisms (trematodes Himasthla elongata and bacteria Vibrio tapetis) singularly and in combination during 7 days on the bivalve Cerastoderma edule. Some defense-related activities were analyzed such as genetic expression, metallothionein and immune responses. Trematode metacercarial infection, similar whatever the treatment, induced the strongest responses of immune parameters. Particularly, the interaction between cadmium and parasite exposures induced unusual responses on gene expression and immune responses. No effect of bacterial challenge appeared on bivalve responses, nevertheless a strong mortality of V. tapetis infected cockles occured between 7 and 14 days. Cadmium bioaccumulation was significantly modulated by both pathogenic organisms. Furthermore, an antagonistic effect of trematodes and bacteria was shown on metal bioaccumulation of co-infected cockles. These results highlighted the importance of considering the multiplicity of perturbation sources in coastal ecosystems to assess the health status of organisms.  相似文献   
430.
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