Lithium isotope geochemistry of marine pore waters - Insights from cold seep fluids     

Florian Scholz  Christian Hensen  Matthias Haeckel  Anette Meixner  Rolf L. Romer 《Geochimica et cosmochimica acta》2010,74(12):3459-206

Lithium concentration and isotope data (δ⁷Li) are reported for pore fluids from 18 cold seep locations together with reference fluids from shallow marine environments, a sediment-hosted hydrothermal system and two Mediterranean brine basins. The new reference data and literature data of hydrothermal fluids and pore fluids from the Ocean Drilling Program follow an empirical relationship between Li concentration and δ⁷Li (δ⁷Li = −6.0(±0.3) · ln[Li] + 51(±1.2)) reflecting Li release from sediment or rocks and/or uptake of Li during mineral authigenesis. Cold seep fluids display δ⁷Li values between +7.5‰ and +45.7‰, mostly in agreement with this general relationship. Ubiquitous diagenetic signals of clay dehydration in all cold seep fluids indicate that authigenic smectite-illite is the major sink for light pore water Li in deeply buried continental margin sediments. Deviations from the general relationship are attributed to the varying provenance and composition of sediments or to transport-related fractionation trends. Pore fluids on passive margins receive disproportionally high amounts of Li from intensely weathered and transported terrigenous matter. By contrast, on convergent margins and in other settings with strong volcanogenic input, Li concentrations in pore water are lower because of intense Li uptake by alteration minerals and, most notably, adsorption of Li onto smectite. The latter process is not accompanied by isotope fractionation, as revealed from a separate study on shallow sediments. A numerical transport-reaction model was applied to simulate Li isotope fractionation during upwelling of pore fluids. It is demonstrated that slow pore water advection (order of mm a⁻¹) suffices to convey much of the deep-seated diagenetic Li signal into shallow sediments. If carefully applied, Li isotope systematics may, thus, provide a valuable record of fluid/mineral interaction that has been inherited several hundreds or thousands of meters below the actual seafloor fluid escape structure.  相似文献   

Earthquakes in Switzerland and surrounding regions during 2009     

Nicholas Deichmann  John Clinton  Stephan Husen  Benjamin Edwards  Florian Haslinger  Donat Fäh  Domenico Giardini  Philipp Kästli  Urs Kradolfer  Iris Marschall  Stefan Wiemer 《Swiss Journal of Geoscience》2010,103(3):535-549

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2009. During this period, 450 earthquakes and 68 quarry blasts were detected and located in the region under consideration. The three strongest events occurred about 15 km NW of Basel in southern Germany (M_L 4.2), near Wildhaus in the Toggenburg (M_L 4.0) and near Bivio in Graubünden (M_L 3.5). Although felt by the population, they were not reported to have caused any damage. With a total of 24 events with M_L ≥ 2.5, the seismic activity in the year 2009 was close to the average over the previous 34 years.  相似文献   

The Role of Zooplankton Grazing and Nutrient Loading in the Occurrence of Harmful Cyanobacterial Blooms in Florida Bay,USA     

Jennifer A. Goleski  Florian Koch  Maria A. Marcoval  Charles C. Wall  Frank J. Jochem  Bradley J. Peterson  Christopher J. Gobler 《Estuaries and Coasts》2010,33(5):1202-1215

Florida Bay is Florida’s (USA) largest estuary and has experienced harmful picocyanobacteria blooms for nearly two decades. While nutrient loading is the most commonly cited cause of algal blooms in Florida Bay, the role of zooplankton grazing pressure in bloom occurrence has not been considered. For this study, the spatial and temporal dynamics of cyanobacteria blooms, the microbial food web, microzooplankton and mesozooplankton grazing rates of picoplankton, and the effects of nutrients on plankton groups in Florida Bay were quantified. During the study, cyanobacteria blooms (>3 × 10⁵ cells mL⁻¹) persisted in the eastern and central regions of Florida Bay for more than a year. Locations with elevated abundance of cyanobacteria hosted microzooplankton grazing rates on cyanobacteria that were significantly lower (p < 0.001) and less frequently detectable compared to sites without blooms. Consistent with this observation, cyanobacteria abundances were significantly correlated with ciliates and heterotrophic nanoflagellates at low cyanobacteria densities (p < 0.001) but were not correlated during bloom events. The experimental enrichment of mesozooplankton abundance during blooms yielded a significant decrease in the net growth rate of picoplankton but had the opposite effect when blooms were absent, suggesting that the cascading effect of mesozooplankton grazing on the microbial food web was also altered during blooms. While inorganic nutrient enrichment significantly increased the net growth rates of eukaryotic phytoplankton and heterotrophic bacteria, such nutrient loading had no effect on the net growth rates of cyanobacteria. Hence, this study demonstrates that low rates of zooplankton grazing and low rates of inorganic nutrient loading contribute to the persistence of cyanobacteria blooms in Florida Bay.  相似文献   

Badass gully morphodynamics and sediment generation in Waipaoa Catchment,New Zealand     

Ian C. Fuller  Florian Strohmaier  Samuel T. McColl  Jon Tunnicliffe  Michael Marden 《地球表面变化过程与地形》2020,45(15):3917-3930

Large (>0.1 km²) gully–mass movement complexes (badass gullies) are significant contributors to the sediment cascade in New Zealand's steepland East Coast Region catchments. The scale of change taking place in these gully systems allows significant evolution in morphology and sediment dynamics to be tracked at annual to decadal timescales. Here we document changes in two adjacent badass gullies in Waipaoa catchment (Tarndale and Mangatu) to infer sediment generation processes and connectivity using a morphological budgeting approach. A baseline dataset for this study is provided by a LiDAR-derived digital elevation model (DEM) in 2005. We produced new DEMs and orthophoto mosaics using photogrammetry in 2017, 2018, and 2019 to quantify gully morphodynamics and associated volumes of sediment erosion and deposition in both systems as they co-evolved. Results indicate ongoing rapid development of both gully complexes. Severe erosion took place at the gully heads with lowering and migration (up to 25 m vertically and laterally) of the topographic divide separating the two gullies between 2005 and 2019. Over the same period, net lowering of each gully system was ~250 mm year⁻¹. Key sediment-generating processes included surface erosion, deep-seated landslides, and debris flows. Longer term, the overall contribution of sediment from both badass gullies to the Waipaoa catchment has been declining. In the mid-20th century, both gullies yielded in excess of 300 kt year⁻¹. From 2005 to 2019, 80 kt year⁻¹ was yielded from Tarndale and 110 kt year⁻¹ from Mangatu. Our most recent surveys demonstrated considerable variability in sediment yield, ranging from 76 kt year⁻¹ (2017–2018) to 291 kt year⁻¹ (2018–2019). The annual variability observed reflects the complex morphodynamics of discrete hillslopes and tributary fans in these badass gully systems and underlines the importance of integrating decadal and annual surveys when assessing system trajectory. © 2020 John Wiley & Sons, Ltd.  相似文献   

Characterizing Water Flow in Vegetated Lysimeters with Stable Water Isotopes and Modeling     

Fatemeh Shajari  Florian Einsiedl  Arno Rein 《Ground water》2020,58(5):759-770

We have used stable water isotopes (δ¹⁸O, δ²H) in combination with lumped-parameter modeling for characterizing unsaturated flow in two lysimeters vegetated with maize. The lysimeters contained undisturbed soil cores dominated by sandy gravel (Ly1) and clayey sandy silt (Ly2). Stable water isotopes were analyzed in precipitation and lysimeter outflow water over about 3 years. The mean transit time of water T and dispersion parameter P_D, obtained from modeling, were higher for the silt soil in Ly2 than for the gravel soil in Ly1 (T of 362 vs. 129 d, P_D of 0.7 vs. 0.12). The consideration of preferential flow (PF) paths could substantially improve the model curve fits, with 13 and 11% contribution of PF for Ly1 and Ly2 as best estimates. Different assumptions were compared to estimate the input function, that is, stable water isotope content in the recharging water. Using the isotopic composition of precipitation as input (no modification) resulted in reasonable model estimations. Best model fits for the entire observation were obtained by weighting the recharging isotopes according to average precipitation within periods of 3 and 6 months, in correspondence to changing vegetation phases and seasonal influences. Input functions that consider actual evapotranspiration could significantly improve modeling at some periods, however, this led to deviations between modeled and observed δ¹⁸O at other periods. This may indicate the influence of variable flow, so that dividing the whole observation period into hydraulically characteristic sub-periods for lumped-parameter modeling (which implements steady-state flow) is recommended for possible further improvement.  相似文献   

Rock slope failure in a recently deglaciated permafrost rock wall at Piz Kesch (Eastern Swiss Alps), February 2014          下载免费PDF全文

Marcia Phillips  Andrea Wolter  Rachel Lüthi  Florian Amann  Robert Kenner  Yves Bühler 《地球表面变化过程与地形》2017,42(3):426-438

In February 2014, a rock pillar with a volume of around 150 000  m³ collapsed at Piz Kesch in the Eastern Swiss Alps. A reconstruction of the conditions prior to the event and of the event itself is presented on the basis of different sources of data. The methods applied include photogrammetry, terrestrial laser scanning, structural geological analysis, examination of meteorological data, carbon‐14 (¹⁴C) dating of organic material in permafrost ice from a tension crack and numerical modelling of likely modes of failure. Despite a complete lack of in situ measurements in the rock wall prior to the event and of direct observations during the event, the available data allow the determination of the approximate timing of the event as well as the structural predisposition, the probable mode of failure and the timescale of several millennia involved in the triggering of the failure of the rock pillar. The interdisciplinary analysis of this event contributes towards understanding the complex interaction of processes involved in large rock slope failures currently occurring in warming mountain permafrost regions. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Seasonality of stable isotope composition of atmospheric water input at the southern slopes of Mt. Kilimanjaro,Tanzania          下载免费PDF全文

Insa Otte  Florian Detsch  Adrian Gütlein  Martha Scholl  Ralf Kiese  Tim Appelhans  Thomas Nauss 《水文研究》2017,31(22):3932-3947

To understand the moisture regime at the southern slopes of Mt. Kilimanjaro, we analysed the isotopic variability of oxygen (δ¹⁸O) and hydrogen (δD) of rainfall, throughfall, and fog from a total of 2,140 samples collected weekly over 2 years at 9 study sites along an elevation transect ranging from 950 to 3,880 m above sea level. Precipitation in the Kilimanjaro tropical rainforests consists of a combination of rainfall, throughfall, and fog. We defined local meteoric water lines for all 3 precipitation types individually and the overall precipitation, δD_prec = 7.45 (±0.05) × δ¹⁸O_prec + 13.61 (±0.20), n  = 2,140, R ² = .91, p  < .001. We investigated the precipitation‐type‐specific stable isotope composition and analysed the effects of amount, altitude, and temperature. Aggregated annual mean values revealed isotope composition of rainfall as most depleted and fog water as most enriched in heavy isotopes at the highest elevation research site. We found an altitude effect of δ¹⁸O_rain = ?0.11‰ × 100 m^?1, which varied according to precipitation type and season. The relatively weak isotope or altitude gradient may reveal 2 different moisture sources in the research area: (a) local moisture recycling and (b) regional moisture sources. Generally, the seasonality of δ¹⁸O_rain values follows the bimodal rainfall distribution under the influences of south‐ and north‐easterly trade winds. These seasonal patterns of isotopic composition were linked to different regional moisture sources by analysing Hybrid Single Particle Lagrangian Integrated Trajectory backward trajectories. Seasonality of d excess values revealed evidence of enhanced moisture recycling after the onset of the rainy seasons. This comprehensive dataset is essential for further research using stable isotopes as a hydrological tracer of sources of precipitation that contribute to water resources of the Kilimanjaro region.  相似文献   

Rock magnetics of carbonate systems–investigating palaeodune archives on Fuerteventura (Canary Islands)     

Florian Schneider  Christopher-Bastian Roettig  Daniel Wolf  Philipp Baumgart  Ulrich Hambach  Dominik Faust 《第四纪科学杂志》2020,35(4):594-606

The mineral magnetic properties of Pleistocene aeolian dune sands from the island of Fuerteventura (Canary Islands, Spain) were studied in order to reconstruct the palaeoenvironmental evolution of Pleistocene climates during their formation. The palaeodunes on Fuerteventura mainly consist of carbonate sands admixed with dust and material of volcanic origin. Due to the low magnetic background caused by the diamagnetic character of carbonate sands, these archives offer a lot of potential for environmental magnetic studies to detect the imprint of dust, volcanic material and paedogenesis. Four sections of alternating palaeosurface–aeolianite sequences in palaeodune fields have been analysed by means of extensive rock magnetic measurements. These Quaternary archives consist of deposits originating from different sources. I. material blown from the shallow shelf, II. material of volcanic origin, and III. long-range transported dust. The rock magnetic findings enable a more detailed interpretation of the palaeosurfaces within the sequences. We are able to differentiate semiquantitatively between the different source materials on one hand and to distinguish on the other hand those from soil-forming processes. Soil formation is only weakly developed in the dust imprints in the palaeosol aeolianite sequences, linked to sparse vegetation cover during the Pleistocene on Fuerteventura.  相似文献