Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean     

Florian Scholz  Christian Hensen  Anja Reitz  Rolf L. Romer  Volker Liebetrau  Anette Meixner  Stephan M. Weise  Matthias Haeckel 《Geochimica et cosmochimica acta》2009,73(18):5444-5459

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.  相似文献   

Modelling of sediment supply from torrent catchments in the Western Alps using the sediment contributing area (SCA) approach     

Moritz Altmann  Florian Haas  Tobias Heckmann  Frédéric Liébault  Michael Becht 《地球表面变化过程与地形》2021,46(5):889-906

The production of coarse sediment in mountain landscapes depends mainly on the type and activity of geomorphic processes and topographic and natural conditions (e.g. vegetation cover) of these catchments. The supply of sediment from these slopes to mountain streams and its subsequent transport lead to sediment connectivity, which describes the integrated coupled state of these systems. Studies from the Northern Calcareous Alps show that the size of the sediment contributing area (SCA), a subset of the drainage area that effectively delivers sediment to the channel network, can be used as a predictor of sediment delivery to mountain streams. The SCA concept is delineated on a digital elevation model (DEM) using a set of rules related to the steepness and length of slopes directly adjacent to the channel network, the gradient of the latter and the vegetation cover. The present study investigates the applicability of this concept to the Western Alps to identify geomorphologically active areas and to estimate mean annual sediment yield (SY) in mainly debris-flow-prone catchments. We use a statistical approach that shows a parameter optimisation and a linear regression of SY on SCA extent. We use a dataset of ~25 years of assessed coarse sediment accumulation in 35 sediment retention basins. In the investigated catchments, sediment transport is governed by several factors, mainly by the extent of vegetation-free areas with a minimum slope of 23° that is coupled to the channel network with a very low gradient of the latter. With our improved framework, we can show that the SCA approach can be applied to catchments that are widely distributed, in a large spatial scale (hectare area) and very heterogeneous in their properties. In general, the investigated catchments show high connectivity, resulting in significant correlations between long-term average yield and the size of the SCA.  相似文献   

Late Holocene environmental changes reconstructed from stable isotope and geochemical records from a cushion‐plant peatland in the Chilean Central Andes (27°S)     

S. T. Kock  K. Schittek  B. Mchtle  H. Wissel  A. Maldonado  A. Lücke 《第四纪科学杂志》2019,34(2):153-164

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Learning from CDM SD tool experience for Article 6.4 of the Paris Agreement     

Karen Holm Olsen  Christof Arens  Florian Mersmann 《Climate Policy》2018,18(4):383-395

The Paris Agreement (PA) emphasizes the intrinsic relationship between climate change and sustainable development (SD) and welcomes the 2030 agenda for the global Sustainable Development Goals (SDGs). Yet, there is a lack of assessment approaches to ensure that climate and development goals are achieved in an integrated fashion and trade-offs avoided. Article 6.4 of the PA introduces a new Sustainable Mitigation Mechanism (SMM) with the dual aim to contribute to the mitigation of greenhouse gas emissions and foster SD. The Kyoto Protocol’s Clean Development Mechanism (CDM) has a similar objective and in 2014, the CDM SD tool was launched by the Executive Board of the CDM to highlight the SD benefits of CDM activities. This article analyses the usefulness of the CDM SD tool for stakeholders and compares the SD tool’s SD reporting requirements against other flexible mechanisms and multilateral standards to provide recommendations for improvement. A key conclusion is that the Paris Agreement’s SMM has a stronger political mandate than the CDM to measure that SD impacts are ‘real, measurable and long-term’. Recommendations for an improved CDM SD tool are a relevant starting point to develop rules, modalities, and procedures for SD assessment in Article 6.4 as well as for other cooperative mitigation approaches.

POLICY RELEVANCE

Research findings are relevant for developing the rulebook of modalities and procedures for Article 6.4 of the Paris Agreement, which introduces a new mechanism for mitigation of greenhouse gas emissions and sustainable development. Lessons learnt from the CDM SD tool and recommendations for enhanced SD assessment are discussed in context of Article 6 cooperative approaches, and make a timely contribution to inform negotiations on the rulebook agreed by the Conference of the Parties serving as the Meeting of the Parties to the Paris Agreement.  相似文献   

Edge-to-Stem Variability in Wet-Canopy Evaporation From an Urban Tree Row     

John T. Van StanII  Zachary Norman  Adrian Meghoo  Jan Friesen  Anke Hildebrandt  Jean-François Côté  S. Jeffrey Underwood  Gustavo Maldonado 《Boundary-Layer Meteorology》2017,165(2):295-310

Evaporation from wet-canopy (\(E_\mathrm{C}\)) and stem (\(E_\mathrm{S}\)) surfaces during rainfall represents a significant portion of municipal-to-global scale hydrologic cycles. For urban ecosystems, \(E_\mathrm{C}\) and \(E_\mathrm{S}\) dynamics play valuable roles in stormwater management. Despite this, canopy-interception loss studies typically ignore crown-scale variability in \(E_\mathrm{C}\) and assume (with few indirect data) that \(E_\mathrm{S}\) is generally \({<}2\%\) of total wet-canopy evaporation. We test these common assumptions for the first time with a spatially-distributed network of in-canopy meteorological monitoring and 45 surface temperature sensors in an urban Pinus elliottii tree row to estimate \(E_\mathrm{C}\) and \(E_\mathrm{S}\) under the assumption that crown surfaces behave as “wet bulbs”. From December 2015 through July 2016, 33 saturated crown periods (195 h of 5-min observations) were isolated from storms for determination of 5-min evaporation rates ranging from negligible to 0.67 \(\hbox {mm h}^{-1}\). Mean \(E_\mathrm{S}\) (0.10 \(\hbox {mm h}^{-1}\)) was significantly lower (\(p < 0.01\)) than mean \(E_\mathrm{C}\) (0.16 \(\hbox {mm h}^{-1}\)). But, \(E_\mathrm{S}\) values often equalled \(E_\mathrm{C}\) and, when scaled to trunk area using terrestrial lidar, accounted for 8–13% (inter-quartile range) of total wet-crown evaporation (\(E_\mathrm{S}+E_\mathrm{C}\) scaled to surface area). \(E_\mathrm{S}\) contributions to total wet-crown evaporation maximized at 33%, showing a general underestimate (by 2–17 times) of this quantity in the literature. Moreover, results suggest wet-crown evaporation from urban tree rows can be adequately estimated by simply assuming saturated tree surfaces behave as wet bulbs, avoiding problematic assumptions associated with other physically-based methods.  相似文献   

Structure of the South Powell Ridge (NE Antarctic Peninsula): new clues for changing tectonic regimes near the Scotia/Antarctica Plate boundary     

J. C. Balanyá  J. Galindo-Zaldívar  A. Jabaloy  G. Leitchenkov  A. Maldonado  J. Rodríguez-Fernández  O. Vinnikovskaya 《Geo-Marine Letters》1999,18(3):215-224

The structure of the South Powell Ridge (SPR), separating the Late Cenozoic ocean-floored Powell Basin and the Mesozoic Weddell Sea domain, is revealed by multichannel seismic data. The SPR appears as a basement high, bounded northward by transtensional faults and by normal and major reverse faults to the south. These margin features seem to be linked to the Powell Basin southern strike-slip margin and to the Jane Arc paleotrench, respectively. We suggest the ridge evolved from the Antarctic Peninsula passive margin to become the deformational front of the Scotia/Antarctica Plate boundary, later being welded to the Antarctic Plate. Received: 18 August 1997 / Revision received: 4 May 1998  相似文献   

Altimetry-derived tide model for improved tide and water level forecasting along the European continental shelf     

Hart-Davis  Michael G.  Laan  Stendert  Schwatke  Christian  Backeberg  Björn  Dettmering  Denise  Zijl  Firmijn  Verlaan  Martin  Passaro  Marcello  Seitz  Florian 《Ocean Dynamics》2023,73(8):475-491

Ocean Dynamics - With the continued rise in global mean sea level, operational predictions of tidal height and total water levels have become crucial for accurate estimations and understanding of...  相似文献   

Water Table Uncertainties due to Uncertainties in Structure and Properties of an Unconfined Aquifer          下载免费PDF全文

Juerg Hauser  Florian Wellmann  Mike Trefry 《Ground water》2018,56(2):251-265

We consider two sources of geology‐related uncertainty in making predictions of the steady‐state water table elevation for an unconfined aquifer. That is the uncertainty in the depth to base of the aquifer and in the hydraulic conductivity distribution within the aquifer. Stochastic approaches to hydrological modeling commonly use geostatistical techniques to account for hydraulic conductivity uncertainty within the aquifer. In the absence of well data allowing derivation of a relationship between geophysical and hydrological parameters, the use of geophysical data is often limited to constraining the structural boundaries. If we recover the base of an unconfined aquifer from an analysis of geophysical data, then the associated uncertainties are a consequence of the geophysical inversion process. In this study, we illustrate this by quantifying water table uncertainties for the unconfined aquifer formed by the paleochannel network around the Kintyre Uranium deposit in Western Australia. The focus of the Bayesian parametric bootstrap approach employed for the inversion of the available airborne electromagnetic data is the recovery of the base of the paleochannel network and the associated uncertainties. This allows us to then quantify the associated influences on the water table in a conceptualized groundwater usage scenario and compare the resulting uncertainties with uncertainties due to an uncertain hydraulic conductivity distribution within the aquifer. Our modeling shows that neither uncertainties in the depth to the base of the aquifer nor hydraulic conductivity uncertainties alone can capture the patterns of uncertainty in the water table that emerge when the two are combined.  相似文献   

Anisotropic dual-continuum representations for multiscale poroelastic materials: Development and numerical modelling     

Mark Ashworth  Florian Doster 《国际地质力学数值与分析法杂志》2020,44(17):2304-2328

Dual-continuum (DC) models can be tractable alternatives to explicit approaches for the numerical modelling of multiscale materials with multiphysics behaviours. This work concerns the conceptual and numerical modelling of poroelastically coupled dual-scale materials such as naturally fractured rock. Apart from a few exceptions, previous poroelastic DC models have assumed isotropy of the constituents and the dual-material. Additionally, it is common to assume that only one continuum has intrinsic stiffness properties. Finally, little has been done into validating whether the DC paradigm can capture the global poroelastic behaviours of explicit numerical representations at the DC modelling scale. We address the aforementioned knowledge gaps in two steps. First, we utilise a homogenisation approach based on Levin's theorem to develop a previously derived anisotropic poroelastic constitutive model. Our development incorporates anisotropic intrinsic stiffness properties of both continua. This addition is in analogy to anisotropic fractured rock masses with stiff fractures. Second, we perform numerical modelling to test the DC model against fine-scale explicit equivalents. In doing, we present our hybrid numerical framework, as well as the conditions required for interpretation of the numerical results. The tests themselves progress from materials with isotropic to anisotropic mechanical and flow properties. The fine-scale simulations show that anisotropy can have noticeable effects on deformation and flow behaviour. However, our numerical experiments show that the DC approach can capture the global poroelastic behaviours of both isotropic and anisotropic fine-scale representations.  相似文献   

Modelling the effects of Zostera noltei meadows on sediment dynamics: application to the Arcachon lagoon     

Katerina Kombiadou  Florian Ganthy  Romaric Verney  Martin Plus  Aldo Sottolichio 《Ocean Dynamics》2014,64(10):1499-1516

A three-dimensional model has been modified to describe the complex interactions between hydrodynamics, sediment dynamics and biological parameters in the presence of Zostera noltei. The model treats seagrass leafs as flexible blades that bend under hydrodynamic forcing and alter the local momentum and turbulence fluxes and, therefore, the benthic shear conditions; these changes cause related changes to the mass balance at the boundary of the bed, in turn affecting the suspended matter in the column and ultimately primary productivity and the growth of the dwarf-grass. Modelling parameters related to the impact of Z. noltei to the local flow and to erosion and deposition rates were calibrated using flume experimental measurements; results from the calibration of the model are presented and discussed. The coupled model is applied in the Arcachon Bay, an area with high environmental significance and large abundance of dwarf-grass meadows. In the present paper, results from preliminary applications of the model are presented and discussed; the effectiveness of the coupled model is assessed comparing modelling results with available field measurements of suspended sediment concentrations and seagrass growth parameters. The model generally reproduces sediment dynamics and dwarf-grass seasonal growth in the domain efficiently. Investigations regarding the effects of the vegetation to the near-bed hydrodynamics and to the sediment suspension in the domain show that dwarf-grass meadows play an important part to velocity attenuation and to sediment stabilisation, with flow and suspended sediment concentrations damping, compared to an unvegetated state, to reach 35–50 and 65 %, respectively, at peak seagrass growth.  相似文献