The nature of chemical bond of magnetite and consequences     

F. Frölich  H. Stiller 《Pure and Applied Geophysics》1963,55(1):91-100

Summary Types of chemical bonding in magnetite are discussed. Magnetite spinel lattice is characterized by tetrahedral covalent bonds and octahedral electrovalent bonds. The consequences for oxidation processes are studied in connection with hitherto existing experimental and theoretical results.

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Zusammenfassung Der Charakter der chemischen Bindung im Magnetit wird diskutiert. Für das Spinellgitter des Magnetits sind tetraedrische kovalente und oktaedrische elektrovalente Bindungen typisch. Die Auswirkungen dieses Bindungszustandes auf den Ablauf der Oxydationsvorgänge wird überprüft an Hand der bisher vorliegenden experimentellen und theoretischen Teilergebnisse.

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Dr. Dr. habil.F. Frölich, Dr.H. Stiller, Geomagnetic InstituteFotsdam, German Academy of Science at Berlin, Mitteilung Nr. 133.  相似文献   

Bemerkungen zu den neueren Arbeiten über das Hercyn im rheinischen Schiefergebirge     

Fr. Drevermann 《International Journal of Earth Sciences》1915,6(1-2):105-113

Ohne Zusammenfassung  相似文献   

Die Erdkunde an den deutschen Hochschulen für Lehrerbildung     

Knieriem  Fr. 《International Journal of Earth Sciences》1937,28(1-2):78-80

Ohne Zusammenfassung  相似文献   

Upper cretaceous and paleogene sediments from the Northern Kerguelen Plateau     

François Fröhlich  Emmanuelle Wicquart 《Geo-Marine Letters》1989,9(3):127-133

Upper Cretaceous and Paleogene pelagic sediments sampled from the Northern Kerguelen Plateau during cruise MD35 of theMarion Dufresne are described and correlated with the Late Paleogene sequence drilled at site ODP 737 (Leg 119). Taking into account geophysical data obtained by the cruise MD26, a Lower Cretaceous age is computed for the unsampled acoustic basement. A major tectonic/volcanic event in the Late Paleogene, related to rifting, gave rise to a marked unconformity and hiatus termed the “Acoustic Discordance.” Tertiary sediment facies changes were strongly influenced by the evolution of the Antarctic environment.  相似文献   

Nuclear field shift effect as a possible cause of Te isotopic anomalies in the early solar system—An alternative explanation of Fehr et al. (2006 and 2009)     

Frédéric Moynier  Toshiyuki Fujii  Francis Albarède 《Meteoritics & planetary science》2009,44(11):1735-1742

Abstract— We explore the possibility that Te isotopic anomalies measured in Ca‐Al‐rich inclusions (Fehr et al. 2009) and in leachates of carbonaceous chondrites (Fehr et al. 2006) may be due to mass‐independent effects controlled by nuclear field shift rather than to nucleosynthetic processes. Fehr et al.'s spectrum of mass‐independent anomalies of Te isotopes shows a smooth correlation with mass number and nuclear charge distribution. Ratios of even to odd isotopes, as the ¹²⁵Te/¹²⁶Te ratio used by these authors for normalization are particularly prone to nuclear field shift effects. We show that the alternative normalization of isotopic ratios to ¹³⁰Te/¹²⁶Te strongly reduces the trend of isotopic fractionation with mass number, leaving only ¹²⁵Te as truly anomalous. For both normalizations (¹²⁵Te/¹²⁶Te and ¹³⁰Te/¹²⁶Te), Fehr et al.'s results fit the theory of Bigeleisen (1996), which suggests that the nuclear field shift effect can potentially account for the observed Te isotope abundances, as an alternative to nucleosynthetic processes. We propose that these mass‐independent effects may be acquired during accretion of sulfides from the solar nebula.  相似文献   

The quest for the solar g modes     

T. Appourchaux  K. Belkacem  A.-M. Broomhall  W. J. Chaplin  D. O. Gough  G. Houdek  J. Provost  F. Baudin  P. Boumier  Y. Elsworth  R. A. García  B. N. Andersen  W. Finsterle  C. Fröhlich  A. Gabriel  G. Grec  A. Jiménez  A. Kosovichev  T. Sekii  T. Toutain  S. Turck-Chièze 《Astronomy and Astrophysics Review》2010,18(1-2):197-277

Solar gravity modes (or g modes)—oscillations of the solar interior on which buoyancy acts as the restoring force—have the potential to provide unprecedented inference on the structure and dynamics of the solar core, inference that is not possible with the well-observed acoustic modes (or p modes). The relative high amplitude of the g-mode eigenfunctions in the core and the evanesence of the modes in the convection zone make the modes particularly sensitive to the physical and dynamical conditions in the core. Owing to the existence of the convection zone, the g modes have very low amplitudes at photospheric levels, which makes the modes extremely hard to detect. In this article, we review the current state of play regarding attempts to detect g modes. We review the theory of g modes, including theoretical estimation of the g-mode frequencies, amplitudes and damping rates. Then we go on to discuss the techniques that have been used to try to detect g modes. We review results in the literature, and finish by looking to the future, and the potential advances that can be made—from both data and data-analysis perspectives—to give unambiguous detections of individual g modes. The review ends by concluding that, at the time of writing, there is indeed a consensus amongst the authors that there is currently no undisputed detection of solar g modes.  相似文献   

Experimental and numerical behaviour of reinforced mortar plates subjected to accelerated corrosion     

Quang Thanh Nguyen  Sabine Caré  Yves Berthaud  Alain Millard  Frédéric Ragueneau 《国际地质力学数值与分析法杂志》2011,35(10):1141-1159

Most reinforced concrete structures are damaged due to corrosion of reinforcements in concrete. In normal conditions the pH near the reinforcements is around 12–13 which means that steel is in a passive state. But aggressive species, such as chloride ions or carbon dioxide, may penetrate into concrete and promote active corrosion. As a consequence (hydro)oxides are produced leading to degradation of concrete structures. For instance cracking of the concrete is generated due to the pressure induced by rust. In this paper, we study the inception and the propagation of cracking on reinforced mortar plates with rebars located either in the middle or at the corner. Additional experiments have been performed on cylindrical specimens to determine the local effect of rust pressure at the interface rust/mortar. The specimens have been subjected to imposed current density in order to enhance the corrosion and digital image intercorrelation has been used to determine displacement fields. The experiments have been compared to numerical modelling. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

O–H isotope ratios of high pressure ultramafic rocks: implications for fluid sources and mobility in the subducted hydrous mantle   总被引：2，自引：0，他引：2  

Gretchen L. Früh-Green  Marco Scambelluri  Franca Vallis 《Contributions to Mineralogy and Petrology》2001,141(2):145-159

We examine the O-H isotope signatures of Alpine ultramafic rocks and eclogitic metagabbros of the Erro-Tobbio peridotite Unit (western Italian Alps), which record a subduction and exhumation cycle. Localization of subduction-related deformation along serpentinite mylonite shear zones favoured preservation of pre-subduction mantle and low temperature (oceanic) alteration assemblages within undeformed (meta)peridotite that underwent partial static recrystallization to high-pressure metamorphic parageneses. Bulk rock and mineral separate (clinopyroxene and serpentine) oxygen isotope ratios of the serpentinized mantle peridotites (5-8‰) are slightly enriched in ¹⁸O compared with those of the high-pressure metaperidotites and the serpentinite mylonites (4.4-7.6‰). The lowest values occur in high-pressure veins (3.5-5.7‰) and eclogitic metagabbros (3.1-5.3‰). These variations are comparable to variations observed in modern oceanic rocks and in non-subducted ophiolites. Preservation of pre-eclogitic '¹⁸O signatures of the Erro-Tobbio rocks and a lack of oxygen isotope re-equilibration between different shear zones imply local-scale fluid flow at low water/rock ratios and closed system behaviour during high-pressure metamorphism. Different serpentine generations show a bimodal distribution in 'D values: pre-eclogitic lizardite and chrysotile range from -102 to -77‰; high-pressure antigorite in the mylonites and in low strain metaperidotites range from -71 to -57‰ and -83 to -60‰, respectively. Comparable ranges occur in antigorite in the associated high-pressure veins, suggesting that the hydrogen signatures were acquired prior to veining. We propose that the isotopic variations reflect multiple events of fluid uptake in different geodynamic environments. The H- and O-isotope ratios in the eclogitic mylonites suggest that initial hydration occurred over a range of temperatures during local interaction with altered seawater along oceanic shear zones. The ¹⁸O-enriched and H-depleted compositions of chrysotile and lizardite in the mantle peridotites suggest that a second hydration event may have occurred as a result of interaction with metamorphic fluids at the early stages of burial in a forearc setting, where slabs undergo large-scale, low-temperature fluid fluxing. The oceanic mantle is thus a candidate for continuous hydration during its oceanic and early subduction history. The Erro-Tobbio unit thus represents an example of cycling of internally-derived fluids, whereby the different structural and textural domains behaved as relatively closed systems to fluid circulation during high-pressure metamorphism.  相似文献   

Ice Sheet And Satellite Altimetry     

Frédérique Rémy  Benoît Legresy  Laurent Testut 《Surveys in Geophysics》2001,22(1):1-29

Since 1991, the altimeters of the ERS European Satellites allow the observation of 80% of the Antarctica ice sheet and the whole Greenland ice sheet: They thus offer for the first time a unique vision of polar ice caps. Indeed, surface topography is an essential data thanks to its capacity to highlight the physical processes which control the surface shape, or to test models. Moreover, the altimeter is also a radar which makes it possible to estimate the snow surface or subsurface characteristics, such as surface roughness induced by the strong katabatic wind or ice grain size. The polar ice caps may not be in a stationary state, they continue to respond to the climatic warming of the beginning of the Holocene, that is 18000 years ago, and possibly start to react to present climatic warming: the altimeter offers the unique means of estimating the variations of volume and thus the contribution of polar ice caps to present sea level change.  相似文献   

Hydrographische Bibliographie     

Fr. Model  H. Mädler 《Ocean Dynamics》1964,17(5):239-248

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