Note from the editors     

Bernd Lehmann  Larry Meinert 《Mineralium Deposita》2003,38(6):651-651

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Rivers, chemical weathering and Earth's climate   总被引：4，自引：0，他引：4  

Bernard Dupr  Cline Dessert  Priscia Oliva  Yves Goddris  Jrme Viers  Louis Franois  Romain Millot  Jrme Gaillardet 《Comptes Rendus Geoscience》2003,335(16):1141-1160

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).  相似文献   

Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone   总被引：1，自引：0，他引：1  

Moritz F. Lehmann  Peter Reichert  Alberto Barbieri 《Geochimica et cosmochimica acta》2003,67(14):2529-2542

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.  相似文献   

Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions     

M. Krämer  Ri. Müller  H. Bovensmann  J. Burrows  J. Brinkmann  E. P. Röth  J.-U. Grooß  Ro. Müller  Th. Woyke  R. Ruhnke  G. Günther  J. Hendricks  E. Lippert  K. S. Carslaw  Th. Peter  A. Zieger  Ch. Brühl  B. Steil  R. Lehmann  D. S. McKenna 《Journal of Atmospheric Chemistry》2003,45(1):51-77

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.  相似文献   

Fast space-domain evaluation of geodetic surface integrals     

R. Lehmann 《Journal of Geodesy》1997,71(9):533-540

Geodetic surface integrals play an important role in the numerical solution of geodetic boundary-value problems. In many cases they can be evaluated using fast methods in the frequency domain (FFT). However, this is not possible in general, because the domain of integration may be non-trivial (as is the surface of the Earth), the kernel function may not be of convolution type, or the data distribution may be heterogeneous. Therefore, fast evaluation strategies are also required in the space domain. They are more difficult to design because only one property is left where a more or less fast evaluation strategy can be built upon: the potential type of the kernel function. Consequently, the idea is not to replace well-established frequency domain techniques, but to supplement them. Our approach to this problem goes in two directions: (1) we use advanced cubature methods where the integration nodes automatically densify in the vicinity of the evaluation points; (2) we use powerful computer hardware, namely MIMD computers with distributed memory. This enables us to evaluate geodetic surface integrals of any practical complexity in reasonable time and accuracy. This is shown in a numerical example. Received: 7 May 1996 / Accepted:17 March 1997  相似文献   

Foreword     

I. Ethem Gönenç 《International Journal of Salt Lake Research》1997,6(2):89-89

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Three-dimensional Rayleigh hysteresis of oriented core samples from the German Continental Deep Drilling Program: susceptibility tensor, Rayleigh tensor, three-dimensional Rayleigh law   总被引：2，自引：0，他引：2  

H. Markert  A. Lehmann 《Geophysical Journal International》1996,127(1):201-214

Rayleigh hysteresis, as defined by the well-known Rayleigh relations, has been observed not only when magnetization of pyrrhotite-bearing KTB-samples is measured in parallel to a weak dc magnetic field, but also in experiments where field and measuring directions have been adjusted strictly perpendicularly to each other. Nine-tupels of independent Rayleigh hysteresis loops could thus be compiled. Their characteristic coefficients X ^ijk of initial susceptibility together with the Rayleigh loss coefficients α^jk have been proved to determine completely the samples' weak-field magnetic anisotropy. Interpreting the coefficient matrices ( X ^ijk) and (α^jk) as the tensor of initial susceptibility and the Rayleigh tensor, respectively, generalization of the isotropic Rayleigh relations in terms of corresponding tensor relationships has been suggested for the anisotropic case. Application to the KTB samples showed 3-D Rayleigh hysteresis measurements to be an excellent tool for rock magnetic analysis in terms of ore content and crystalline texture. In particular, a magnetocrystalline double texture of the basal planes of pyrrhotite precipitates and their [1120] directions of easy magnetization have been clearly detected. Surprisingly, the welt-known theorem α= const. X ²_I, formulated by Néel (1942) for the isotropic case, has been found to hold true even in tensor generalization (α_jk) = const ( X ²_jk). To reach sufficient resolution for the measurements performed, a sensitive vibrating coil magnetometer (VCM) has been developed.  相似文献   

The Distribution of Redox Sensitive Elements (U, As, Sb, V and Mo) along a River-Wetland-Lake System (Balaton Region, Hungary)     

Françoise Elbaz-Poulicheet  Attila Nagy  Tibor Cserny 《Aquatic Geochemistry》1997,3(3):267-282

The distribution of redox sensitive elements (U, As,Sb, Mo and V) has been investigated in Lake Balatonand two man-made reservoirs (Lake Kis-Balaton-1 andKis-Balaton-2) built along the River Zala, the mainriver discharging into it. These elements underwentremoval in Lake Kis Balaton-2 (KB-2) during anoxicconditions (May and September).Similarities were found between the distributions ofdissolved As and Sb. Both elements had elevateddissolved concentrations in Lake Kis-Balaton-1 (KB-1)and in Lake Balaton in September. This increasedmobility could be due to a change of speciation (viareduction and the formation of methylated species).Such changes in speciation are well documented in theliterature and are generally enhanced during periodsof warmth and high primary productivity.Dissolved V and Mo distributions also showedsimilarities with higher concentrations in LakeBalaton than in other parts of the system.Although removal is not clearly detected from thedissolved concentrations, U, As, Sb and Mo aresignificantly enriched in the organic-rich sedimentsof Lake KB-1, while V is mainly associated with thealumino-silicate fraction. In Lake KB-1, theconcentrations of all elements in SPM (suspendedparticulate matter) are lower than in the depositedsediments (except for As) suggesting that enrichmentprocesses are occuring in the deposited sediments.Additionnally the cycling of As and Mo can be alsopartly controlled by uptake and scavenging processesin the water column, as suggested by the elevated Asand Mo concentrations observed in SPM seasonnally forAs in Lake KB-1 and at Z.mouth-1 station and for Mo atZ.mouth-1 station and Lake Balaton.  相似文献   

ASPI experiment: measurements of fields and waves on board the INTERBALL-1 spacecraft     

S. Klimov  S. Romanov  E. Amata  J. Blecki  J. Büchner  J. Juchniewicz  J. Rustenbach  P. Triska  L. J. C. Woolliscroft  S. Savin  Yu. Afanas’yev  U. de Angelis  U. Auster  G. Bellucci  A. Best  F. Farnik  V. Formisano  P. Gough  R. Grard  V. Grushin  G. Haerendel  V. Ivchenko  V. Korepanov  H. Lehmann  B. Nikutowski  M. Nozdrachev  S. Orsini  M. Parrot  A. Petrukovich  J. L. Rauch  K. Sauer  A. Skalsky  J. Slominski  J. G. Trotignon  J. Vojta  R. Wronowski 《Annales Geophysicae》1997,15(5):514-527

The plasma-wave experiment ASPI (analysis of spectra of plasma waves and instabilities) on board the INTERBALL spacecraft is a combined wave diagnostics experiment. It performs measurements of the DC and AC magnetic field vector by flux-gate and searchcoil sensors, the DC and AC electric field vector by Langmuir double probes and the plasma current by Langmuir split probe. Preliminary data analysis shows the low noise levels of the sensors and the compatibility of new data with the results of previous missions. During several months of in-orbit operation a rich collection of data was acquired, examples of which at the magnetopause and plasma sheet are presented in second part of the paper.  相似文献   

An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems     

Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.  相似文献