A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions     

David J. Barber  John R. Beckett  Julie M. Paque  Edward Stolper 《Meteoritics & planetary science》1994,29(5):682-690

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is   相似文献   

Umbral oscillations and penumbral waves in Hα     

R. L. Moore  Frances Tang 《Solar physics》1975,41(1):81-88

We present examples of umbral oscillations observed on Big Bear H filtergram movies and investigate the relation between umbral oscillations and running penumbral waves occurring in the same sunspot. Umbral oscillations near the center of the umbra are probably physically independent of the penumbral waves because the period of these umbral oscillations (150 s) is shorter than the penumbral wave period (270 s) but not a harmonic. We also report dark puffs which emerge from the edge of the umbra and move outward across the penumbra, and which have the same period as the running penumbral waves. We interpret these dark puffs to be the extension of chromospheric umbral oscillations at the edge of the umbra. It is suggested that the dark puffs and the running penumbral waves have a common source: photospheric oscillations just inside the umbra.  相似文献   

Accessibility Measures in Spatial Mismatch Models     

Eugene D. Perle  Harald Bauder  Nancy Beckett 《The Professional geographer》2002,54(1):106-110

Implicit in all spatial mismatch models is the concept of accessibility. However, there is an immense variety of measures utilized in the literature to index the concept, and it is not clear how much of the disparity in findings between studies is attributable to alternative measures. This research note attempts to provide some evidence on the impact of alternative measures of accessibility in employment probability models.  相似文献   

Markets, ethnicity and environment in a vulnerable landscape: the case of small-scale vegetable production on the Jos Plateau, Nigeria, 1991–2001     

Gina Porter  Frances Harris†  Fergus Lyon‡  Jasper Dung§  A A Adepetu§ 《The Geographical journal》2003,169(4):370-381

This paper explores changing socio-environmental interactions in the vegetable producing areas of the Jos Plateau over the decade 1991–2001. It considers the pressures of market forces and ethnic competition and the tensions which arise as interactions between the two are played out in a fragile physical, social and institutional environment. The region has seen a remarkable expansion in irrigated vegetable production, as dry season surveys in 1991 and 2001 attest. Local farmers appear extremely positive in their perceptions of change, pointing not only to expanded production, but also to other improvements, like growing percentages of children in school and improved transport. But behind this rosy view of change there are tensions and a series of unresolved questions which may soon have to be addressed. We examine the changing nature of socio-environmental interactions over the decade and ask whether and how current levels of production can be sustained in the context of a currently largely unregulated production system and growing competition for land. Given the important role of the Plateau as a source of temperate fruit and vegetables in West Africa, these questions have significance far beyond the Plateau region itself.  相似文献   

Feature     

Frances Wall 《Geology Today》2003,19(6):206-211

Numerous world class mineral deposits make the Kola Peninsula a 'Mecca' for mineralogists, and key economic deposits make it one of Russia's most important industrial areas. For geologists there is the challenge of explaining how this situation has come about.  相似文献   

Late Holocene δC and pollen records of paleosalinity from tidal marshes in the San Francisco Bay estuary, California     

Frances Malamud-Roam  B. Lynn Ingram 《Quaternary Research》2004,62(2):134-145

Records of stable carbon isotopes (δ¹³C) are presented from cores collected from four San Francisco Bay marshes and used as a proxy for changes in estuary salinity. The δ¹³C value of organic marsh sediments are a reflection of the relative proportion of C₃ vs. C₄ plants occupying the surface, and can thus be used as a proxy for vegetation change on the marsh surface. The four marshes included in this study are located along a natural salinity gradient that exists in the San Francisco Bay, and records of vegetation change at all four sites can be used to infer changes in overall estuary paleosalinity. The δ¹³C values complement pollen data from the same marsh sites producing a paleoclimate record for the late Holocene period in the San Francisco Bay estuary. The data indicate that there have been periods of higher-than-average salinity in the Bay estuary (reduced fresh water inflow), including 1600-1300 cal yr B.P., 1000-800 cal yr B.P., 300-200 cal yr B.P., and ca. A.D. 1950 to the present. Periods of lower-than-average salinity (increased fresh water inflow) occurred before 2000 cal yr B.P., from 1300 to 1200 cal yr B.P. and ca. 150 cal yr B.P. to A.D. 1950. A comparison of the timing of these events with records from the California coast, watershed, and beyond the larger drainage of the Bay reveals that the paleosalinity variations reflected regional precipitation.  相似文献   

Low Food Availability Narrows the Tolerance of the Copepod Eurytemora affinis to Salinity,but Not to Temperature     

Bruce G. Hammock  Sarah Lesmeister  Ida Flores  Gideon S. Bradburd  Frances H. Hammock  Swee J. Teh 《Estuaries and Coasts》2016,39(1):189-200

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A new technique for understanding magnetosphere–ionosphere coupling using directional derivatives of SuperDARN convection flow     

S. N. M. Azizul Hoque  Frances Fenrich 《Journal of Astrophysics and Astronomy》2018,39(6):70

The purpose of this paper is to present and evaluate a new technique to better understand ionospheric convection and it’s magnetospheric drivers using convection maps derived from the Super Dual Auroral Radar Network (SuperDARN). We postulate that the directional derivative of the SuperDARN ionospheric convection flow can be used as a technique for understanding solar wind–magnetosphere–ionosphere coupling by identifying regions of strong acceleration/deceleration of plasma flow associated with drivers of magnetospheric convection such as magnetic reconnection. Thus, the technique may be used to identify the open–closed magnetic field line boundary (OCB) in certain circumstances. In this study, directional derivatives of the SuperDARN ionospheric convection flow over a four and a half hour interval on Nov. 04, 2001, is presented during which the interplanetary magnetic field was predominantly southward. At each one-minute time point in the interval the positive peak in the directional derivative of flow is identified and evaluated via comparison with known indicators of the OCB including the poleward boundary of ultraviolet emissions from three FUV detectors onboard the IMAGE spacecraft as well as the SuperDARN spectral widths. Good comparison is found between the location of the peak in the directional derivative of SuperDARN flow and the poleward boundary of ultraviolet emissions confirming that acceleration of ionospheric plasma flow is associated with magnetic reconnection and the open–closed boundary.  相似文献   

Heavy-mineral variability in bottom sediments of the lower Chesapeake Bay,Virginia     

Frances Firek  G.L. Shideler  Peter Fleischer 《Marine Geology》1977,23(3):217-235

Heavy minerals in bottom-sediment samples of the lower Chesapeake Bay show distribution patterns and interrelationships that denote characteristic mineral suites associated with defined geographic provinces. The Baymouth province has a garnet—hornblende—pyroxene suite, which is largely attributed to the influx of littoral and shelf sediments; the Eastern Shore province has a similar suite, derived largely from coastal erosion of the Eastern Shore peninsula. The Northern and Combined River provinces have a zircon—tourmaline—staurolite assemblage, which reflects derivation from an Appalachian Piedmont—Atlantic Coastal Plain sourceland. The Western Shore province is associated with a zircon—epidote—staurolite assemblage, apparently derived jointly from tributary influx and coastal erosion of the western shore. Factor analysis identified two major factors that account for 63% of the total variation in the relative amounts of the seven most common heavy minerals. The dominant factor (44%) is based on a zircon—hornblende—staurolite—pyroxene relationship, which indicates that mineral stability, as influenced by sediment maturity, is a major contributing factor. The second factor (19%) based on a tourmaline—epidote—staurolite—garnet relationship indicates that provenance is another major cause of heavy-mineral variability within the lower bay.  相似文献   

A suggested origin of MARID xenoliths in kimberlites by high pressure crystallization of an ultrapotassic rock such as lamproite   总被引：1，自引：0，他引：1  

Frances G. Waters 《Contributions to Mineralogy and Petrology》1987,95(4):523-533

Chemical, mineralogical and isotopic studies have been made on nodules of the MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside) xenolith suite in southern African kimberlites. All are ultramafic and ultrapotassic (MgO= 20–25%, K₂O=4–9%), with bulk compositions reflecting the wide variation in relative proportions of the five minerals amongst the nodules. They are comparable in major element compositions to magnesian lamproites, in particular the ultrabasic olivine-lamproites of Western Australia. In a number of high pressure experimental studies on ultra-potassic rocks, the phases produced between 25–30 kbar from compositions comparable to those of MARID rocks (in the presence of additional water), were predominantly phlogopite and diopside (±K-richterite, ±ilmenite, ±rutile). Furthermore the compositions of experimental minerals produced in the synthetic-biotite-mafurite-H₂O system by Edgar et al. (1976) are similar to those in MARID rocks.It is suggested on the basis of these observations and the textural appearance of MARID rocks that they are magmatic compositional equivalents of MgO-rich lamproites that crystallized at high pressures. While lamproites have higher average concentrations of incompatible elements, (including REE), some MARID rocks have comparable abundances. It is suggested that late stage vapour-rich melts carrying substantial REE and other incompatible elements escaped from crystallizing MARID magmas into surrounding subcontinental lithosphere, thus resulting in lower levels of these elements in most MARID rocks. In contrast faster crystallization of lamproitic rocks under volcanic/ hypabyssal conditions would prevent similar losses.The MARID proto-magmas are thought to be either partial melts of metasomatised phlogopite peridotite, or small volume asthenospheric melts which are modified and further enriched by incorporation of small partial melts of enriched subcontinental lithosphere during magma ascent.  相似文献