UV-B radiation: a health risk in the Arctic?     

Frances P. Noonan  Edward C. de  Fabo 《Polar research》1999,18(2):361-365

Seasonal stratospheric ozone depletion in the Arctic has raised the question of whether the associated increases in ultraviolet-B (290-320 nm) constitute a significant health risk in Arctic populations. Increases in skin cancer in Europe and the USA from excess UV-B resulting from ozone depletion have been predicted. Skin cancer is, however, rare in Inuit populations.
UV-B also causes a selective down regulation of the immune system which may be a natural regulatory mechanism evolved to prevent autoimmune attack on sunlight-altered skin. The action spectrum for UV-B immunosuppression implicated a unique skin photoreceptor molecule, urocanic acid (UCA), which isomerizes from the trans to the cis isomer on exposure to UV-B, the cis isomer being immunosuppressive. This form of immunosuppression is important in skin cancer and possibly in infectious diseases.
The epidemiology of non-Hodgkin's lymphoma shows a relationship with UV exposure, postulated to be via the immunosuppressive effects of UV-B. Cancers which show an excess in Inuit populations include nasopharyngeal and salivary gland cancer. Genetic factors appear to be involved, but these are thought to be virally related cancers possibly associated with the high viral load in these populations. In several studies on non-Arctic populations, salivary gland cancer has been linked to ultraviolet exposure. A potential role for UV-B exposure in these cancers in the Arctic needs to be explored.
In view of the high levels of POPS in some Arctic regions, potential interactions between the immunosuppression caused by some of these pollutants and the effects of UV-B need to be investigated.  相似文献   

Liebermannite,KAlSi3O8, a new shock-metamorphic,high-pressure mineral from the Zagami Martian meteorite          下载免费PDF全文

Chi Ma  Oliver Tschauner  John R. Beckett  George R. Rossman  Clemens Prescher  Vitali B. Prakapenka  Hans A. Bechtel  Alastair MacDowell 《Meteoritics & planetary science》2018,53(1):50-61

In this paper, we discuss the occurrence of liebermannite (IMA 2013-128), KAlSi₃O₈, a new, shock-generated, high-pressure tetragonal hollandite-type structure silicate mineral, in the Zagami basaltic shergottite meteorite. Liebermannite crystallizes in space group I4/m with Z = 2, cell dimensions of a = 9.15 ± 0.14 (1σ) Å, c = 2.74 ± 0.13 Å, and a cell volume of 229 ± 19 Å³ (for the type material), as revealed by synchrotron diffraction. In Zagami, liebermannite likely formed via solid-state transformation of primary igneous K-feldspar during an impact event that achieved pressures of ~20 GPa or more. The mineral name is in honor of Robert C. Liebermann, a high-pressure mineral physicist at Stony Brook University, New York, USA.  相似文献   

Late prehistoric soil fertility,irrigation management,and agricultural production in northwest coastal Peru     

Lee Nordt  Frances Hayashida  Tom Hallmark  Corey Crawford 《Geoarchaeology》2004,19(1):21-46

The Pampa de Chaparrí (Pampa) in hyperarid northwest coastal Peru is an ideal area to study late prehispanic agricultural technology and production because irrigation canals and furrowed fields have been preserved since abandonment approximately 500 years ago. We collected 55 samples for soil characterization, fertility, and micromorphic analyses and compared these results to a noncultivated control soil previously sampled in an adjacent valley. Natural soil fertility levels for maize, cotton, and bean production were generally high during late prehispanic cultivation in the Pampa. Maintaining adequate nitrogren levels for production, however, would have required external inputs from livestock manure, guano, or leguminous plants. The management of low soil salinity levels was possible because of rapidly permeable soils and irrigation waters low in salt. Based on available water capacity and climate conditions, the Blaney‐Criddle Equation yields evapotranspiration rates indicating that irrigation frequency was necessary in a range of every 10–16 days during the growing season. © 2004 Wiley Periodicals, Inc.  相似文献   

Kaitianite,Ti3+2Ti4+O5, a new titanium oxide mineral from Allende     

Chi Ma  John R. Beckett 《Meteoritics & planetary science》2021,56(1):96-107

Kaitianite, Ti³⁺₂Ti⁴⁺O₅, is a new titanium oxide mineral discovered in the Allende CV3 carbonaceous chondrite. The type grain coexists with tistarite (Ti₂O₃) and rutile. Corundum, xifengite, mullite, osbornite, and a new Ti,Al,Zr‐oxide mineral are also present, although not in contact. The chemical composition of type kaitianite is (wt%) Ti₂O₃ 56.55, TiO₂ 39.29, Al₂O₃ 1.18, MgO 1.39, FeO 0.59, V₂O₃ 0.08 (sum 99.07), yielding an empirical formula of (Ti³⁺_1.75Al_0.05Ti⁴⁺_0.10Mg_0.08Fe_0.02)(Ti⁴⁺_1.00)O₅, with Ti³⁺ and Ti⁴⁺ partitioned, assuming a stoichiometry of three cations and five oxygen anions pfu. The end‐member formula is Ti³⁺₂Ti⁴⁺O₅. Kaitianite is the natural form of γ‐Ti₃O₅ with space group C2/c and cell parameters a = 10.115 Å, b = 5.074 Å, c = 7.182 Å, β = 112°, V = 341.77 Å³, and Z = 4. Both the type kaitianite and associated rutile likely formed as oxidation products of tistarite at temperatures below 1200 K, but this oxidation event could have been in a very reducing environment, even more reducing than a gas of solar composition. Based on experimental data on the solubility of Ti³⁺ in equilibrium with corundum from the literature, the absence of tistarite in or on Ti³⁺‐rich corundum (0.27–1.45 mol% Ti₂O₃) suggests that these grains formed at higher temperatures than the kaitianite (>1579–1696 K, depending on the Ti concentration). The absence of rutile or kaitianite in or on corundum suggests that any exposure to the oxidizing environment producing kaitianite in tistarite was too short to cause the precipitation of Ti‐oxides in or on associated corundum.  相似文献   

Correlations and zoning patterns of phosphorus and chromium in olivine from H chondrites and the LL chondrite Semarkona          下载免费PDF全文

M. C. McCanta  J. R. Beckett  E. M. Stolper 《Meteoritics & planetary science》2016,51(3):520-546

Phosphorus zoning is observed in olivines in high‐FeO (type IIA) chondrules in H chondrites over the entire range of petrologic grades: H3.1–H6. Features in P concentrations such as oscillatory and sector zoning, and high P cores are present in olivines that are otherwise unzoned in the divalent cations. Aluminum concentrations are low and not significantly associated with P zoning in chondrule olivines. In highly unequilibrated H chondrites, phosphorus zoning is generally positively correlated with Cr. Atomic Cr:P in olivine is roughly 1:1 (3:1 for one zone in one olivine in RC 075), consistent with Cr³⁺ charge‐balancing P⁵⁺ substituting for Si⁴⁺. Normal igneous zonation involving the dominant chrome species Cr²⁺ was observed only in the LL3.0 chondrite Semarkona. In more equilibrated chondrites (H3.5–H3.8), Cr spatially correlated with P is occasionally observed but it is diffuse relative to the P zones. In H4–H6 chondrites, P‐correlated Cr is absent. One signature of higher metamorphic grades (≥H3.8) is the presence of near matrix olivines that are devoid of P oscillatory zoning. The restriction to relatively high metamorphic grade and to grains near the chondrule–matrix interface suggests that this is a response to metasomatic processes. We also observed P‐enriched halos near the chondrule–matrix interface in H3.3–H3.8 chondrites, likely reflecting the loss of P and Ca from mesostasis and precipitation of Ca phosphate near the chondrule surface. These halos are absent in equilibrated chondrites due to coarsening of the phosphate and in unequilibrated chondrites due to low degrees of metasomatism. Olivines in type IA chondrules show none of the P‐zoning ubiquitous in type IIA chondrules or terrestrial igneous olivines, likely reflecting sequestration of P in reduced form within metallic alloys and sulfides during melting of type IA chondrules.  相似文献   

The significance of quality of life and sustainability at the urban–rural fringe in the making of place-based community     

Marie Mahon  Frances Fahy  Micheál Ó Cinnéide 《GeoJournal》2012,77(2):265-278

Understandings of community in urban–rural fringe locations in Ireland are explored in this paper. As a specific space at the interface between the urban and the rural the fringe incorporates processes of rapid physical, social, and demographic change. These give rise to a range of complex and often competing dynamics, that impact on people and place in a variety of ways. Among the main preoccupations and concerns in these rapidly evolving fringe locations are those relating to what can broadly be described as ‘quality of life’. How this concept is understood across different groups situated within the spatial setting of the fringe, and how it influences the development of a sustainable community there, are central to this discussion. Drawing on household interviews from four case-study locations surrounding Galway City, Ireland, this paper examines how quality of life is experienced across a range of social and spatial dimensions that relate to these locations, and the extent to which they provide a common set of interests around which community may be built. From a wider knowledge perspective, it contributes to debates about how the concept of community provides explanatory power regarding the way in which individuals are associated with one another on the basis of a set of shared interests or concerns within a particular spatial setting.  相似文献   

Zoning of phosphorus in igneous olivine   总被引：2，自引：2，他引：0  

Margaret S. Milman-Barris  John R. Beckett  Michael B. Baker  Amy E. Hofmann  Zachary Morgan  Meghan R. Crowley  Daniel Vielzeuf  Edward Stolper 《Contributions to Mineralogy and Petrology》2008,155(6):739-765

We describe P zoning in olivines from terrestrial basalts, andesites, dacites, and komatiites and from a martian meteorite. P₂O₅ contents of olivines vary from below the detection limit (≤0.01 wt%) to 0.2–0.4 wt% over a few microns, with no correlated variations in Fo content. Zoning patterns include P-rich crystal cores with skeletal, hopper, or euhedral shapes; oscillatory zoning; structures suggesting replacement of P-rich zones by P-poor olivine; and sector zoning. Melt inclusions in olivines are usually located near P-rich regions but in direct contact with low-P olivine. Crystallization experiments on basaltic compositions at constant cooling rates (15–30°C/h) reproduce many of these features. We infer that P-rich zones in experimental and natural olivines reflect incorporation of P in excess of equilibrium partitioning during rapid growth, and zoning patterns primarily record crystal-growth-rate variations. Occurrences of high-P phenocryst cores may reflect pulses of rapid crystal growth following delayed nucleation due to undercooling. Most cases of oscillatory zoning in P likely reflect internal factors whereby oscillating growth rates occur without external forcings, but some P zoning in natural olivines may reflect external forcings (e.g., magma mixing events, eruption) that result in variable crystal growth rates and/or P contents in the magma. In experimental and some natural olivines, Al, Cr, and P concentrations are roughly linearly and positively correlated, suggesting coupled substitutions, but in natural phenocrysts, Cr zoning is usually less intense than P zoning, and Al zoning weak to absent. We propose that olivines grow from basic and ultrabasic magmas with correlated zoning in P, Cr, and Al superimposed on normal zoning in Fe/Mg; rapidly diffusing divalent cations homogenize during residence in hot magma; Al and Cr only partially homogenize; and delicate P zoning is preserved because P diffuses very slowly. This interpretation is consistent with the fact that zoning is largely preserved not only in P but also in Al, Cr, and divalent cations in olivines with short residence times at high temperature (e.g., experimentally grown olivines, komatiitic olivines, groundmass olivines, and the rims of olivine phenocrysts grown during eruption). P zoning is widespread in magmatic olivine, revealing details of crystal growth and intra-crystal stratigraphy in what otherwise appear to be relatively featureless crystals. Since it is preserved in early-formed olivines with prolonged residence times in magmas at high temperatures, P zoning has promise as an archive of information about an otherwise largely inaccessible stage of a magma’s history. Study of such features should be a valuable supplement to routine petrographic investigations of basic and ultrabasic rocks, especially because these features can be observed with standard electron microprobe techniques.  相似文献   

The role of culture and traditional knowledge in climate change adaptation: Insights from East Kimberley,Australia     

Sonia Leonard  Meg Parsons  Knut Olawsky  Frances Kofod 《Global Environmental Change》2013,23(3):623-632

Indigenous peoples offer alternative knowledge about climate variability and change based on their own locally developed knowledges and practices of resource use. In this article we discuss the role of traditional ecological knowledge in monitoring and adapting to changing environmental conditions. Our case study documents a project to record the seasonal knowledge of the Miriwoong people in northern Australia. The study demonstrates how indigenous groups’ accumulate detailed baseline information about their environment to guide their resource use and management, and develop worldviews and cultural values associated with this knowledge. We highlight how traditional ecological knowledge plays a critical role in mediating indigenous individuals and communities’ understandings of environmental changes in the East Kimberley region of north-west Australia, and how these beliefs may influence future decision-making about how to go about adapting to climate change at a local level.  相似文献   

Testing the survival of microfossils in artificial martian sedimentary meteorites during entry into Earth’s atmosphere: The STONE 6 experiment     

Frédéric Foucher  Frances Westall  Franz Brandstätter  René Demets  John Parnell  Charles S. Cockell  Howell G.M. Edwards  Jean-Michel Bény  André Brack 《Icarus》2010,207(2):616-279

If life ever appeared on Mars, could we find traces of primitive life embedded in sedimentary meteorites? To answer this question, a 3.5-byr-old volcanic sediment containing microfossils was embedded in the heat shield of a space capsule in order to test survival of the rock and the microfossils during entry into the Earth’s atmosphere (the STONE 6 experiment). The silicified volcanic sediment from the Kitty’s Gap Chert (Pilbara, Australia) is considered to be an excellent analogue for Noachian-age volcanic sediments. The microfossils in the chert are also analogues for potential martian life. An additional goal was to investigate the survival of living microorganisms (Chroococcidiopsis) protected by a 2-cm thick layer of rock in order to test whether living endolithic organisms could survive atmospheric entry when protected by a rocky coating.Mineralogical alteration of the sediment due to shock heating was manifested by the formation of a fusion crust, cracks in the chert due to prograde and retrograde changes of α quartz to β quartz, increase in the size of the fluid inclusions, and dewatering of the hydromuscovite-replaced volcanic protoliths. The carbonaceous microfossils embedded in the chert matrix survived in the rock away from the fusion crust but there was an increase in the maturity index of the kerogen towards the crust. We conclude that this kind of sediment can survive atmospheric entry and, if it contains microfossils, they could also survive. The living microorganisms were, however, completely carbonised by flame leakage to the back of the sample and therefore non-viable. However, using an analytical model to estimate the temperature reached within the sample thickness, we conclude that, even without flame leakage, the living organisms probably need to be protected by at least 5 cm of rock in order to be shielded from the intense heat of entry.  相似文献   

Structure, charge distribution, and electron hopping dynamics in magnetite (Fe₃O₄) (1 0 0) surfaces from first principles     

Frances N. Skomurski  Sebastien Kerisit  Kevin M. Rosso 《Geochimica et cosmochimica acta》2010,74(15):4234-7290

For the purpose of improving fundamental understanding of the redox reactivity of magnetite, quantum-mechanical calculations were applied to predict Fe²⁺ availability and electron hopping rates at magnetite (1 0 0) surfaces, with and without the presence of adsorbed water. Using a low free energy surface reconstruction (½-Fe_tet layer relaxed into the Fe_oct (1 0 0) plane), the relaxed outermost layer of both the hydrated and vacuum-terminated surfaces were found to be predominantly enriched in Fe²⁺ within the octahedral sublattice, irrespective of the presence of adsorbed water. At room temperature, mobile electrons move through the octahedral sublattice by Fe²⁺-Fe³⁺ valence interchange small polaron hopping, calculated at 10¹⁰-10¹² hops/s for bulk and bulk-like (i.e., near-surface) environments. This process is envisioned to control sustainable overall rates of interfacial redox reactions. These rates decrease by up to three orders of magnitude (10⁹ hops/s) at the (1 0 0) surface, and no significant difference is observed for vacuum-terminated versus hydrated cases. Slower hopping rates at the surface appear to arise primarily from larger reorganization energies associated with octahedral Fe²⁺-Fe³⁺ valence interchange in relaxed surface configurations, and secondarily on local charge distribution patterns surrounding Fe²⁺-Fe³⁺ valence interchange pairs. These results suggest that, with respect to the possibility that the rate and extent of surface redox reactions depend on Fe²⁺ availability and its replenishment rate, bulk electron hopping mobility is an upper-limit for magnetite and slower surface rates may need to be considered as potentially rate-limiting. They also suggest that slower hopping mobilities calculated for surface environments may be amenable to Fe²⁺-Fe³⁺ site discrimination by conventional spectroscopic probes.  相似文献