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31.
A thermodynamic model is developed that describes the compositional variation of coexisting olivine, orthopyroxene, and ferrite (Fe3O4-MgFe2O4) as a function of and T. The ferrite phase has a cation distribution which varies from nearly inverse to nearly random with increasing T and is described with a model in which the number of sites per formula unit on which mixing occurs varies from 1.67 to 2.0. Given this model and the equilibrium phase composition data for coexisting olivine and ferrite at 1,300° C of Jamieson and Roeder (1984), the ferrite solution is described to an excellent approximation by a symmetric regular solution model with W ft =+14.0 ±0.3 kJ/mole. Orthopyroxene and olivine non-ideality are also considered. The T-dependence of the equilibrium constant for the oxidation reaction 6Fs+2Mt=6Fa+O2 and the two Fe/Mg exchange reactions between olivine-ferrite and olivine-orthopyroxene, are used to calculate the compositional variation of coexisting phases as a function of and T. The results are summarized on an isobaric (1 bar) –1/Tplot with the compositional variation of olivine, ferrite, and orthopyroxene shown by sets of isopleths. The ferrite isopleths intersect those of olivine and orthopyroxene at sufficiently high angles for this assemblage to serve as a sensitive geothermometer and oxygen-barometer. The model is applied to orthopyroxene-ferrite symplectite in coronas around olivine in a metamorphosed gabbro, to olivine-hosted orthopyroxene-ferrite symplectite in unmetamorphosed gabbros and norites and to olivine-hosted orthopyroxene-ferrite symplectites developed within the rims of lherzolite xenoliths.  相似文献   
32.
This article describes a web‐based data entry and GIS‐driven mapping system designed for an ethnographic and entomological survey of Chagas’ disease, an emerging zoonotic disease, and Triatoma dimidiata, a primary vector, in the Los Tuxtlas region of Veracruz, Mexico. To better understand this disease in the region, a collaborative, multi‐disciplinary study was initiated to conduct a spatial investigation of T. dimidiata and a community‐by‐community survey of local perceptions of the disease. In order to facilitate such a collaborative effort the CODES‐GIS was developed. This system allows for (near) real‐time mapping, analyses, disease reporting, and results sharing. CODES‐GIS provides a framework for a research team working in a remote area with limited technology, software, or GIS expertise to benefit from (near) real‐time spatial analyses performed at collaborating institutions. The system is bi‐directional, where field personnel can upload data to the system for field‐based map production. Likewise, laboratory personnel can upload diagnostics data for viewing by field personnel. In this way, the system provides a virtual link between the field and the laboratory to increase the speed at which results are returned to the local community. The CODES‐GIS is described along with a selection of study results.  相似文献   
33.
A new probabilistic approach is proposed to assess muricid species population abundances at scales relevant to both Ancient and Modern coastal fisheries. Motivated by the long‐term goal of reconstructing the dynamics of exploited murex populations during Antiquity, the objective was to estimate the population density of the banded dye‐murex, Hexaplex trunculus (Linnaeus, 1758) from successive captures with baited traps, using a method similar to the technique employed in the Mediterranean purple dye industry. The stochastic model developed simulates cumulative captures while accounting for high variability. It was calibrated with data acquired during a field trapping experiment (Crete Island, Greece). Traps’ catchability and Effective Area of Attraction (EAA) were estimated using the individual speed and behavioural response towards bait from laboratory experiments. Average density of H. trunculus was estimated as 2.2 ± 1.4 SE individuals per square metre, with no significant differences between seagrass and rocky habitats. The clearing time of successive capture experiments averaged 84 ± 6 SE hr. Clearing ca. 0.4 ha of subtidal area would be necessary to produce ca. 1.0 g of pure Tyrian purple pigment. The method described is generalizable to making population abundance estimates for similar groups, such as whelks, in modern fisheries.  相似文献   
34.
High-resolution magnetograph observations of the polar magnetic fields have been obtained at intervals of time since the end of 1986 at Big Bear Solar Observatory. The Big Bear data differ from the low-resolution, full-disk magnetograph observations in that the 2 arc sec resolution makes it possible to resolve concentrated field upward of 100 G. The purpose of this ongoing observation is to examine the evolution of polar fields during the expected polarity reversal as cycle 22 passes its maximum phase, and secondly, to study the polar magnetic field: its true field strength, distribution, and how it compares to other parts of the quiet Sun.We find that the >70° net polar flux of both poles has not reversed as of the end of 1989. However, in the lower latitudes of both poles, 50° to 70°, there are signs reminiscent of those preceding the reversals in cycles 19 and 20. These include: decreasing field intensity in the old polarity fluctuations in net flux between the old and new polarities.We find that the net average longitudinal polar fields (above 50°) are 1–2 G, in agreement with results found in cycles 19 and 20. For individual elements, however, the strongest observed field strength poleward of 70° is over 100 G.We compare the polar fields with the equatorial limb as a function of latitute and longitude, respectively, and find the polar fields are comparable to (or stronger than) the quiet equatorial limb. When the observed mean flux density of the polar field as a function of latitude is corrected for limb-darkening and projection effects (assuming the field is radial), the result is nearly constant. These results suggest that despite the high latitudes, the polar fields have field strength and distribution similar to other parts of the quiet Sun.  相似文献   
35.
San Francisco Bay has been considered an HNLC or HNLG (high nutrient low chlorophyll or low growth) region with nonlimiting concentrations of inorganic nutrients yet low standing stocks of phytoplankton. Most of the studies leading to this conclusion come from the South Bay and little is known about nutrient processes and phytoplankton productivity in the northern and central parts of the estuary. Data collected over 3 yr (1999–2003) in Suisun, San Pablo, and Central Bays describe the availability of dissolved inorganic nitrogen (DIN), silicate, and phosphate and the seasonal variability in phytoplankton abundance. Rate measurements of fractionated nitrogen productivity provide the relative contributions of different forms of DIN (ammonium and nitrate) and different sized phytoplankton to the development of seasonal phytoplankton blooms. Regional differences in bloom dynamics are observed with Suisun Bay, the least saline, highest nutrient, most turbid region having less phytoplankton biomass and productivity than San Pablo and Central Bays, except in the abnormally wet spring of 2000. Spring blooms in San Francisco Bay are driven primarily by high rates of nitrate uptake by larger phytoplankton cells following a period of increased ammonium uptake that depletes the ambient ammonium. The smaller occasional fall blooms are apparently flueled mostly by ammonium uptake by small sized phytoplankton. The data suggest that the HNLC condition in the northern and central parts of San Francisco Bay is due primarily to light availability modulated by the interaction between ammonium and nitrate, and the relative amounts of the two forms of the DIN pool available to the phytoplankton.  相似文献   
36.
37.
Abstract— Activities of chromite in multicomponent spinels with compositions similar to those of H chondrites were experimentally determined by equilibrating Pt‐alloys with spinel at known temperature and fO2. Our results are consistent with predictions based on the spinel solid solution model incorporated into the MELTS program. Therefore, we combined literature formulations for the activities of components in spinel, the ferromagnesian silicates, and alloys with measured and literature (bulk alloy) compositions of the meteoritic phases to constrain T‐fO2 conditions for the H‐group chondrites Avanhandava (H4), Allegan (H5), and Guareña (H6). Log10fO2 values based on the assemblage of olivine + orthopyroxene + metal are 2.19–2.56 log units below the iron‐wüstite (IW) buffer for any equilibration temperature between 740 and 990 °C, regardless of petrographic type. Only lower limits on fO2 could be determined from spinel + metal equilibria because of the extremely low concentrations of Cr in the alloys of equilibrated H chondrites (≤3 ppb). Log10fO2 values required by spinel + metal equilibria are inconsistent with those for olivine + orthopyroxene + metal if equilibration temperatures were at or above those inferred from olivine‐spinel thermometry. This probably indicates that the closure for spinel + metal equilibria occurred under retrograde conditions at temperatures below ~625 °C for Allegan and Guareña and below ~660 °C for Avanhandava.  相似文献   
38.
Frances Wall 《Geology Today》2004,20(5):181-184
Geology Today often features letters from geologists working on active volcanoes. Some of the most famous letters from a volcano were written by Sir William Hamilton from Vesuvius in Italy, during the 18th century and earned him the title of 'the first volcanologist'.  相似文献   
39.
40.
Ti valence measurements in MgAl2O4 spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti+4. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti+3‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti+4‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ25Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ25Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ25Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti+4 concentrations in spinel.  相似文献   
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