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631.
Macronutrients, photosynthetic pigments, and particle export were assessed in two eddies during the E-Flux I and III cruises to investigate linkages between biogeochemical properties and export flux in Hawaiian lee cyclonic eddies. Cyclone Noah (E-Flux I), speculated to be in the ‘decay’ stage, exhibited modest increases in macronutrients and photosynthetic pigments at the eddy center compared to ambient waters. Cyclone Opal (E-Flux III) also exhibited modest increases in macronutrient concentrations, but a 2-fold enhancement in total chlorophyll a (TChl a) concentration within the eddy center. As indicated by fucoxanthin concentrations, the phytoplankton community in the deep chlorophyll maximum (DCM) of Opal was comprised mainly of diatoms. During an 8-day time series in the center of Opal, TChl a concentration and fucoxanthin in the DCM decreased by 50%, which was potentially triggered by silicic acid limitation. Despite the presence of a substantial diatom bloom, Opal did not deliver the expected export of particulate carbon and nitrogen, but rather a large biogenic silica export (4-fold increase relative to export in surrounding waters). Results suggest that controls on the life cycle of a Hawaiian lee cyclone are likely a combination of physical (eddy dynamics), chemical (nutrient limitation), and biological (growth and grazing imbalance) processes. Comparisons between Noah and Opal and previously studied cyclones in the region point to a relationship between the spin-up duration of a cyclone and the resulting biological response. Nonetheless, Hawaiian lee cyclones, which strongly influence the biogeochemistry of areas 100's of km in scale in the subtropical North Pacific Ocean, still remain an enigma.  相似文献   
632.
Methane-derived rocks in Monferrato and the Tertiary Piedmont Basin (NW Italy) consist of seep carbonates, formed by gas seepage at the seafloor, and macroconcretions resulting from the cementation of buried sediments crossed by gas-rich fluids. These rocks are characterized by both negative δ13C values and a marked enrichment in δ18O. Petrographic features not commonly described and that point to enigmatic depositional and diagenetic conditions have been observed in both types of rocks: inhomogeneous distribution of cements within cavities; dolomite crystals floating within cavity-filling calcite spar; non-gravitational fabrics of internal sediments plastering cavity walls; open framework within microbial crusts. These features suggest the former presence of gas hydrates in sediments. During their dissociation, new space was formed and filled with authigenic carbonates or injected sediments. Analogous mechanisms of clathrate freeze-and-thaw processes have been inferred for the genesis of zebra and stromatactis structures and particular kinds of carbonate breccias. The term melt-seal structure is proposed for this kind of diagenetic structure. The fabrics of gas hydrates and the geochemical conditions of sediments, in turn depending on the relative rates of supply of methane-rich fluids and normal seawater, conditioned the final aspect of the rocks.  相似文献   
633.
Programmable imaging spectrometers can be adjusted to fit specific application requirements that differ from the instrument initial spectral design goals. Sensor spectral characteristics and its signal-to-noise ratio (SNR) can be changed by applying customized online binning patterns.We present a software utility that generates application driven spectral binning patterns by using an SNR dependent sensor model. The utility, named BinGO (BInning patterN Generator and Optimiser), is used to produce predefined binning patterns that either (a) allow an existing imaging spectrometer to optimize its spectral characteristics for a specific application, (b) allow an existing imaging spectrometer to spectral and/or spatially emulate another instrument, or (c) design new multispectral or imaging spectrometer missions (i.e. spaceborne, airborne, terrestrial). We present a variety of BinGO case studies, including the simulation of airborne (APEX) [Itten, K.I. et al., 2008. APEX — The hyperspectral ESA Airborne Prism Experiment. Sensors 8(1), 1–25], spaceborne (SENTINEL III) [Nieke, J., Frerick, J., Stroede, J., Mavrocordatos, C., Berruti, B., 2008. Status of the optical payload and processor development of ESA’s Sentinel 3 mission. In: Proceedings of the Geoscience and Remote Sensing Symposium IGARSS 2008, pp. 427–430], as well as scientific and performance optimized approaches. We conclude that the presented approach can successfully be used to increase the efficiency of spectral information retrieval by using imaging spectroscopy data and to simulate various missions and requirements, finally supporting proper trade-off decisions to be made between performance optimization and scientific requirements. In addition, if specific sensor parameters are known, BinGO can also model other imaging spectrometers.  相似文献   
634.
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