A simple pore water hydrogen diffusion syringe sampler     

Vroblesky DA  Chapelle FH  Bradley PM 《Ground water》2007,45(6):798-802

Molecular hydrogen (H(2)) is an important intermediate product and electron donor in microbial metabolism. Concentrations of dissolved H(2) are often diagnostic of the predominant terminal electron-accepting processes in ground water systems or aquatic sediments. H(2) concentrations are routinely measured in ground water monitoring wells but are rarely measured in saturated aquatic sediments due to a lack of simple and practical sampling methods. This report describes the design and development (including laboratory and field testing) of a simple, syringe-based H(2) sampler in (1) saturated, riparian sediments, (2) surface water bed sediments, and (3) packed intervals of a fractured bedrock borehole that are inaccessible by standard pumped methods.  相似文献   

Age, growth, and reproductive season of bluefish (Pomatomus saltatrix) in the Marmara region, Turkey     

Ceyhan  Tevfik; Akyol  Okan; Ayaz  Adnan; Juanes  Francis 《ICES Journal of Marine Science》2007,64(3):531-536

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Characterization of uranium-contaminated sediments from beneath a nuclear waste storage tank from Hanford, Washington: Implications for contaminant transport and fate     

Wooyong Um  Jonathan P. Icenhower  R. Jeffery Serne  Cleveland J. Dodge  Arokiasamy J. Francis 《Geochimica et cosmochimica acta》2010,74(4):1363-6031

The concentration and distribution of uranium (U) in sediment samples from three boreholes recovered near radioactive waste storage tanks at Hanford, Washington, USA, were determined in detail using bulk and micro-analytical techniques. The source of contamination was a plume that contained an estimated 7000 kg of dissolved U that seeped into the subsurface as a result of an accident that occurred during filling of tank BX-102. The desorption character and kinetics of U were also determined by experiment in order to assess the mobility of U in the vadose zone. Most samples contained too little moisture to obtain quantitative information on pore water compositions. Concentrations of U (and contaminant phosphate—P) in pore waters were therefore estimated by performing 1:1 sediment-to-water extractions and the data indicated concentrations of these elements were above that of uncontaminated “background” sediments. Further extraction of U by 8 N nitric acid indicated that a significant fraction of the total U is relatively immobile and may be sequestered in mobilization-resistant phases. Fine- and coarse-grained samples in sharp contact with one another were sub-sampled for further scrutiny and identification of U reservoirs. Segregation of the samples into their constituent size fractions coupled with microwave-assisted digestion of bulk samples showed that most of the U contamination was sequestered within the fine-grained fraction. Isotope exchange (²³³U) tests revealed that ∼51% to 63% of the U is labile, indicating that the remaining fund of U is locked up in mobilization-resistant phases. Analysis by Micro-X-ray Fluorescence and Micro-X-ray Absorption Near-Edge Spectroscopy (μ-XRF and μ-XANES) showed that U is primarily associated with Ca and is predominately U(VI). The spectra obtained on U-enriched “hot spots” using Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLIFS) provide strong evidence for uranophane-type [Ca(UO₂)₂(SiO₃OH)₂(H₂O)₅] and uranyl phosphate [Ca(UO₂)₂(PO₄)₂(H₂O)_10-12] phases. These data show that disseminated micro-precipitates can form in narrow pore spaces within the finer-grained matrix and that these objects are likely not restricted to lithic fragment environments. Uranium mobility may therefore be curtailed by precipitation of uranyl silicate and phosphate phases, with additional possible influence exerted by capillary barriers. Consequently, equilibrium-based desorption models that predict the concentrations and mobility of U in the subsurface matrix at Hanford are unnecessarily conservative.  相似文献   

The fate of technetium in reduced estuarine sediments: Combining direct and indirect analyses     

Ian T. Burke  Francis R. Livens  Jonathan R. Lloyd  Andrew P. Brown  Gareth T.W. Law  Joyce M. McBeth  Beverley L. Ellis  Richard S. Lawson  Katherine Morris 《Applied Geochemistry》2010

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Observation of the thermal structure and dynamics of the stratosphere and the mesosphere from space     

Alain Hauchecorne  Philippe Keckhut  Chantal Claud  Francis Dalaudier  Anne Garnier 《Comptes Rendus Geoscience》2010,342(4-5):323-330

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The Meteoritical Bulletin,No. 111     

Jérôme Gattacceca  Francis M. McCubbin  Jeffrey N. Grossman  Devin L. Schrader  Nancy L. Chabot  Massimo D'Orazio  Cyrena Goodrich  Ansgar Greshake  Juliane Gross  Katherine Helen Joy  Mutsumi Komatsu  Bingkui Miao 《Meteoritics & planetary science》2023,58(6):901-904

Meteoritical Bulletin 111 contains the 3094 meteorites approved by the Nomenclature Committee of the Meteoritical Society in 2022. It includes 11 falls (Antonin, Botohilitano, Cranfield, Golden, Great Salt Lake, Longde, Msied, Ponggo, Qiquanhu, Tiglit, Traspena), with 2533 ordinary chondrites, 165 HED, 123 carbonaceous chondrites (including 4 ungrouped), 82 lunar meteorites, 28 Rumuruti chondrites, 27 iron meteorites, 23 ureilites, 22 mesosiderites, 22 Martian meteorites, 21 primitive achondrites (one ungrouped), 17 ungrouped achondrites, 13 pallasites, 7 enstatite achondrites, 6 enstatite chondrites, and 5 angrites. Of the meteorites classified in 2022, 1787 were from Antarctica, 1078 from Africa, 180 from South America, 34 from Asia, 6 from North America, 4 from Europe, and 1 from Oceania.  相似文献   

Estimating gambling venue catchments for impact assessment using a calibrated gravity model     

Francis Markham  Bruce Doran  Martin Young 《International journal of geographical information science》2014,28(2):326-342

Gambling using electronic gaming machines (EGMs) has emerged as a significant public health issue. While social impact assessments are required prior to the granting of new gaming machine licenses in Australia, there are a few established techniques for estimating the spatial distribution of a venue’s clientele. To this end, we calibrated a Huff model of gambling venue catchments based on a geocoded postal survey (n = 7040). We investigated the impact of different venue attractiveness measures, distance measures, distance decay functions, levels of spatial aggregation and venue types on model fit and results. We then compared model estimates for different behavioural subgroups. Our calibrated spatial model is a significant improvement on previously published models, increasing R² from 0.23 to 0.64. Venue catchments differ radically in size and intensity. As different population subgroups are attracted to different venues, there is no single best index of venue attractiveness applicable to all subpopulations. The calibrated Huff model represents a useful regulatory tool for predicting the extent and composition of gambling venue catchments. It may assist in decision-making with regard to new license applications and evaluating the impact of health interventions such as mandated reductions in EGM numbers. Our calibrated parameters may be used to improve model accuracy in other jurisdictions.  相似文献   

In situ monitoring of karst springs in Wallonia (southern Belgium)   总被引：1，自引：1，他引：0  

Philippe Meus  Pierre Moureaux  Sébastien Gailliez  Jérémy Flament  Francis Delloye  Philippe Nix 《Environmental Earth Sciences》2014,71(2):533-541

The implementation of the Water Framework Directive, as well as the forthcoming entry into force of other European water policies focusing on water resources, require a thorough reorganization of groundwater resources monitoring in most European countries. In Wallonia, monitoring programs were initiated in 2005 to control the quantitative and chemical statuses of groundwater bodies, as well as the effectiveness of management plans aimed at achieving environmental objectives. In karst aquifers, springs are preferential monitoring targets even if, as a result of the high heterogeneity of this type of aquifer, the interpretation of time series and spatial data remains a challenge. Since 2006, a “springs” monitoring network has been progressively set up in the southern part of Belgium. Currently, in situ measurements of discharge, temperature, conductivity, turbidity and fluorescence of water are conducted at nine karstic outlets in the Devonian and the Carboniferous limestone aquifers of Wallonia. The main objective of this ongoing research is to evaluate the suitability and the robustness of such standard measurements to discriminate anthropogenic impacts from natural variations, at both short- and long-term scales. Discharge and temperature data revealed being useful in the assessment of regional hydro-climatic trends. Groundwater proved to be a better natural filter for the assessment of long-term climatic changes than mathematical filtering of noisy surface signals. Investigations of such data at a European scale could therefore give additional insight into the impacts of climate change on groundwater resources. Conductivity, turbidity and fluorescence data characterize the particulate, mineral and organic health of water and a better understanding of their natural dynamics could help in the early detection of anthropogenic deviations. However, the current reproducibility of these measurements is too low to ascertain observed trends and fluctuations, and further research is still needed.  相似文献   

A steepness index unit volume flood hydrograph approach for sub‐daily flow disaggregation     

Kim‐Seong Tan  Francis H. S. Chiew  Rodger B. Grayson 《水文研究》2007,21(20):2807-2816

The estimation of sub‐daily flows from daily flood flows is important for many hydrological and hydraulic applications. Flows during flood events often vary significantly within sub‐daily time‐scales, and failure to capture the sub‐daily flood characteristic can result in an underestimation of the instantaneous flood peaks, with possible risk of design failure. It is more common to find a longer record of daily flow series (observed or modelled using daily rainfall series) than sub‐daily flow data. This paper describes a novel approach, known as the steepness index unit volume flood hydrograph approach, for disaggregating daily flood flows into sub‐daily flows that takes advantage of the strong relationship between the standardized instantaneous flood peak and the standardized daily flood hydrograph rising‐limb steepness index. The strength of this relationship, which is considerably stronger than the relationship between the standardized flood peak and the event flood volume, is shown using data from six rivers flowing into the Gippsland Lakes in southeast Australia. The results indicate that the steepness index unit volume flood hydrograph approach can be used to disaggregate modelled daily flood flows satisfactorily, but its reliability is dependent on a model's ability to simulate the standardized daily flood hydrograph rising‐limb steepness index and the event flood volume. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Population growth in Bejing: trends and countermeasures     

Zhaoliang Hu  Francis Yee  George Chusheng Lin 《中国地理科学(英文版)》1991,1(3):212-220

Beijing’ population has experienced a dramatic increase eversince the founding of the People’s Republic of China. Population growthin Beijing can be broadly broken down into three major components:natural increase, immigration, and the growth of floating population. Thecontinuous growth of Beijing’s population is closely linked with its centralized multi-function. The comprehensive countermeasures to control Beijing’s population growth are proposed, for example, decentralizing economicfunctions, including developing the suburbs, developing the metropolitan areaand creating counter-magnetic centers, reforming the administrative and economic systems.  相似文献