Decadal evolution of anthropogenic CO₂ in the northwestern Mediterranean Sea from the mid-1990s to the mid-2000s     

Franck Touratier  Catherine Goyet 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(10):1708-1716

Monthly observations accumulated over more than a decade at the DYFAMED time-series station allow us to estimate the temporal evolution of anthropogenic CO₂ in the western Mediterranean Sea. This objective is reached by using recognized interpolation procedures to reconstruct the incomplete distributions of measured total dissolved inorganic carbon and total alkalinity. These reconstructed fields, associated with those available for dissolved oxygen and temperature, are used to estimate the distribution of anthropogenic CO₂. This is done with the recently developed Tracer combining Oxygen, inorganic Carbon, and total alkalinity (TrOCA) approach. The main results indicate that (1) the concentrations of anthropogenic CO₂ are much higher than those found in the Atlantic Ocean (the minimum concentration at the DYFAMED site is 50 μmol kg⁻¹), and (2) the temporal trend for anthropogenic CO₂ is decreasing, especially in the intermediate and the deep layers of the water column at the DYFAMED site. This decrease in anthropogenic CO₂ is significantly correlated with a decrease in the dissolved oxygen and with an increase in both salinity and temperature. These trends are discussed in the light of recent published works that propose explanations for the observed increases in salinity and temperature that occurred in the western basin since the 1950s. We conclude that the decrease in anthropogenic CO₂ probably resulted from an invasion of old water masses. Different hypotheses on the origin of these water masses are considered and several arguments indicate that the eastern Mediterranean transient (EMT) could have played an important role in the observed decrease in anthropogenic CO₂ concentrations at the DYFAMED site.  相似文献   

Magnetic record of El Niño Southern Oscillation in Late Pleistocene sediments from Mucubají lake (western Venezuela)     

Juan Andrés Arévalo Groening  Vincenzo Costanzo-Alvarez  Milagrosa Aldana  Eduardo Carrillo  Franck Audemard 《Studia Geophysica et Geodaetica》2017,61(2):336-360

El Niño Southern Oscillation (ENSO) is an internal forcing of the climate system. This event has an actual frequency of 2 to 8 years. Evidence from a paleoclimate proxy database of gray scale (GS), in samples from Pallcacocha lake in Ecuador, indicates that the ENSO had a frequency of 35 to 75 years during the Late Pleistocene. In this work we explored the possible relationship between the ENSO proxies (GS) from Pallcacocha and magnetic parameters from sediments sampled at the Mucubají lake in Mérida, Venezuela (i.e. mass-specific magnetic susceptibility, magnetic remanence S ratio and susceptibilitynormalized saturation isothermal remanent magnetization). After applying a Lanczos bandpass filter to the rock magnetic and the GS data, in order to remove, as much as possible, frequencies associated to any periodic event other than ENSO, we found significant correlations between GS and magnetic parameters for the period between 12450 and 10560 cal. yrs BP. These relationships were obtained using an Adaptive Neuro Fuzzy Inference System (ANFIS), a hybrid algorithm that combines fuzzy logic with neural networks. The results show that the magnetic parameters obtained in Mucubají are able to explain 50.5% of the total variance of the ENSO proxy in a range of 35 to 75 years in Pallcacocha, which is roughly the same percentage of the total variance of the temperature in the Venezuelan Andes, explained by the ENSO at present times. In this way we have inferred a possible influence of the ENSO in the Venezuelan Andes during the Late Pleistocene.  相似文献   

On the dynamics and energetics of the earth's core     

S. Franck 《Astronomische Nachrichten》1984,305(5):276-276

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Influence of food supply on the δ13C signature of mollusc shells: implications for palaeoenvironmental reconstitutions     

Franck Lartaud  Laurent Emmanuel  Marc de Rafelis  Stephane Pouvreau  Maurice Renard 《Geo-Marine Letters》2010,30(1):23-34

Compared to oxygen isotopes, the carbon isotope composition of biogenic carbonates is less commonly used as proxy for palaeoenvironmental reconstructions because shell δ¹³C is derived from both dissolved inorganic (seawater) and organic carbon sources (food), and interactions between these two pools make it difficult to unambiguously identify any independent effect of either. The main purpose of this study was to demonstrate any direct impact of variable food supply on bivalve shell δ¹³C signatures, using low/high rations of a ¹³C-light mixed algal diet fed to 14-month-old (adult) cultured Japanese Crassostrea gigas under otherwise essentially identical in vitro conditions during 3 summer months (May, June and July 2003, seawater temperature means at 16, 18 and 20 °C respectively) in experimental tanks at the Argenton laboratory along the Brittany Atlantic coast of France. At a daily ration of 12% (versus 4%) oyster dry weight, the newly grown part of the shells (hinge region) showed significantly lower δ¹³C values, by 3.5‰ (high ration: mean of −5.8  ± 1.1‰, n = 10; low ration: mean of −2.3  ± 0.7‰, n = 6; ANOVA Scheffe’s test, p < 0.0001). This can be explained by an enhanced metabolic activity at higher food supply, raising ¹³C-depleted respiratory CO₂ in the extrapallial cavity. Based on these δ¹³C values and data extracted from the literature, and assuming no carbon isotope fractionation between food and shell, the proportion of shell metabolic carbon would be 26  ± 7 and 5  ± 5% for the high- and low-ration C. gigas shells respectively; with carbon isotope fractionation (arguably more realistic), the corresponding values would be 69  ± 14 and 24  ± 9%. Both groups of cultured shells exhibited lower δ¹³C values than did wild oysters from Marennes-Ol éron Bay in the study region, which is not inconsistent with an independent influence of diet type. Although there was no significant difference between the two food regimes in terms of δ¹⁸O shell values (means of 0.1  ± 0.3 and 0.4  ± 0.2‰ at high and low rations respectively, non-significant Scheffe’s test), a positive δ¹³C vs. δ¹⁸O relationship recorded at high rations supports the interpretation of a progressive temperature-mediated rise in metabolic activity fuelled by higher food supply (in this case reflecting increased energy investment in reproduction), in terms not only of δ¹³C (metabolic signal) but also of δ¹⁸O (seawater temperature signal). Overall, whole-shell δ¹⁸O trends faithfully recorded summer/winter variations in seawater temperature experienced by the 17-month-old cultured oysters.  相似文献   

The South Eastern Durance fault permanent network: Preliminary results     

Philippe Volant  Catherine Berge-Thierry  Pierre Dervin  Marc Cushing  Georgianna Mohammadioun  Franck Mathieu 《Journal of Seismology》2000,4(2):175-189

The Durance fault area is located in South EasternFrance. This fault system is characterized byhistorical earthquakes (one every century, since 1509,with a magnitude between 5.0 and 5.3). This is theonly fault in France with such a periodic historicalseismic activity. In order to study an active fault ina moderate seismic context, the IPSN (Institute forNuclear Safety and Protection) decided to install apermanent network in 1992, surrounding the fault area.Such a permanent seismic network has been installed inthe french Pyrenees in the Arette area (Gagnepain etal., 1980). While the Arette network covers a regionaffected by several major faults, our network isdevoted to the study of the specific Durance fault.Major historical earthquakes are clearly associatedwith this structure. From an instrumental point ofview, few earthquakes have been recorded since 1962with the national network. Our network shows a smallseismic activity, with the epicenters well alignedalong the fault direction. Moreover, focal mechanismscomputed for two events agree with the regionalmicrostructural studies (Cushing et al., 1997).Finally, a study of the shear wave splittingunderlines preferential S wave polarization for twostations. The H/V ratio on noise microtremors has beencomputed for each station in order to check theirpositions in term of site effects. It does not exhibitany amplification effect (except for two stations).The comparisons with H/V ratio on earthquake datasetshow the important biases we can obtain with realearthquakes.  相似文献   

Continental growth and volatile exchange during Earth''s evolution     

Siegfried Franck  Christine Bounama 《Physics of the Earth and Planetary Interiors》1997,100(1-4):189-196

We investigate the thermal and degassing history of the Earth with the help of a parameterized mantle convection model including the volatile exchange between mantle and surface reservoirs. The weakening of mantle silicates by dissolved volatiles is described by a functional relationship between creep rate and water fugacity. We use flow law parameters of diffusion creep in olivine under dry and wet conditions. The mantle degassing rate is considered as directly proportional to the seafloor spreading rate, which is also dependent on the mantle heat flow and the continental area. To calculate the spreading rate, we assume three different continental growth models: constant growth, delayed growth, and the one proposed by Reymer and Schubert (1984, Tectonics, 3: 63–77). The rate of regassing also depends on the seafloor spreading rate, as well as on other factors. Both mechanisms (degassing and regassing) are coupled self-consistently with the help of a parameterized convection model under implementation of a temperature and volatile-content dependent mantle viscosity. We calculate time series for the Earth's evolution over 4.6 Gyr for the average mantle temperature, the mantle heat flow, the mantle viscosity, the Rayleigh number, the Urey ratio, the volatile loss, and the seafloor spreading rate. In those numerical simulations with continental growth from the beginning and a high initial average mantle temperature water is outgassed rapidly. In the delayed continental growth model there is a very early outgassing event and the delayed continental growth has no remarkable influence on the thermal and outgassing history. A similar situation is found for the linear continental growth model but not for the Reymer and Schubert (1984) model.  相似文献   

From oblique subduction to intra-continental transpression: Structures of the southern Kermadec-Hikurangi margin from multibeam bathymetry,side-scan sonar and seismic reflection     

Jean-Yves Collot  Jean Delteil  Keith B. Lewis  Bryan Davy  Geoffroy Lamarche  Jean-Christophe Audru  Phil Barnes  Franck Chanier  Eric Chaumillon  Serge Lallemand  Bernard Mercier de Lepinay  Alan Orpin  Bernard Pelletier  Marc Sosson  Bertrand Toussaint  Chris Uruski 《Marine Geophysical Researches》1996,18(2-4):357-381

The southern Kermadec-Hikurangi convergent margin, east of New Zealand, accommodates the oblique subduction of the oceanic Hikurangi Plateau at rates of 4–5 cm/yr. Swath bathymetry and sidescan data, together with seismic reflection and geopotential data obtained during the GEODYNZ-SUD cruise, showed major changes in tectonic style along the margin. The changes reflect the size and abundance of seamounts on the subducting plateau, the presence and thickness of trench-fill turbidites, and the change to increasing obliquity and intracontinental transpression towards the south. In this paper, we provide evidence that faulting with a significant strike-slip component is widespread along the entire 1000 km margin. Subduction of the northeastern scrap of the Hikurangi Plateau is marked by an offset in the Kermadec Trench and adjacent margin, and by a major NW-trending tear fault in the scarp. To the south, the southern Kermadec Trench is devoid of turbidite fill and the adjacent margin is characterized by an up to 1200 m high scarp that locally separates apparent clockwise rotated blocks on the upper slope from strike-slip faults and mass wasting on the lower slope. The northern Hikurangi Trough has at least 1 km of trench-fill but its adjacent margin is characterized by tectonic erosion. The toe of the margin is indented by 10–25 km for more than 200 km, and this is inferred to be the result of repeated impacts of the large seamounts that are abundant on the northern Hikurangi Plateau. The two most recent impacts have left major indentations in the margin. The central Hikurangi margin is characterized by development of a wide accretionary wedge on the lower slope, and by transpression of presubduction passive margin sediments on the upper slope. Shortening across the wedge together with a component of strike-slip motion on the upper slope supports an interpretation of some strain partitioning. The southern Hikurangi margin is a narrow, mainly compressive belt along a very oblique, apparently locked subduction zone.  相似文献   

Predicting the impact of land use on the major element and nutrient fluxes in coastal Mediterranean rivers: The case of the Têt River (Southern France)     

Javier Garcia-Esteves  Wolfgang Ludwig  Philippe Kerhervé  Jean-Luc Probst  Franck Lespinas 《Applied Geochemistry》2007

This study presents a detailed discrimination between the natural and anthropogenic sources of dissolved major elements in the Têt River, a typical small coastal river in the south of France. The main objectives were to quantify the materials that were released by human activities in the basin, and to determine the specific element inputs for the major land use forms. The dissolved material fluxes were estimated by weekly monitoring over a hydrological year (2000–2001) along the major water gauging stations, and the flux relationships were examined in the context of anthropogenic and natural basin characteristics as determined by a Geographical Information System (GIS). Intensive agricultural land use in the form of fruit tree cultures and vineyards has a strong control on the dissolved element fluxes in the river. Area specific element releases for these cultures are greatest for SO₄, with an estimated average of about 430 ± 18 keq km⁻² a⁻¹. This is ?11 times the natural SO₄ release by rock weathering. Also for K, NO₃, PO₄ and Mg, the specific releases were ?6 times the natural weathering rates (respectively about 44, 60, 4 and 265 keq km⁻² a⁻¹). Waste-waters are the other major source of anthropogenic elements in the river. They have an important role for the fluxes of inorganic P and N, but they are also a considerable source of Cl and Na to the river. For example, the average annual release of Cl is around 150 moles/inhabitant in the rural basin parts. Further downstream, however, where population density strongly increases, industrial effluents can enhance this value (>300 moles/inhabitant). The waste-waters contribute more than 70% of the dissolved inorganic N export to the sea, although their contribution to the average DOC export is almost negligible (3%).  相似文献   

High resolution simulation of recent Arctic and Antarctic stratospheric chemical ozone loss compared to observations     

Om Prakash Tripathi  Sophie Godin-Beekmann  Franck Lefèvre  Marion Marchand  Andrea Pazmiño  Alain Hauchecorne  Florence Goutail  Hans Schlager  C. Michael Volk  B. Johnson  G. König-Langlo  Stefano Balestri  Fred Stroh  T. P. Bui  H. J. Jost  T. Deshler  Peter von der Gathen 《Journal of Atmospheric Chemistry》2006,55(3):205-226

Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1^∘ × 1^∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1^∘ × 1^∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO₃, N₂O, and NO _y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10⁻³ to 10⁻² cm⁻³) refines the agreement with in situ ozone, N₂O and NO _y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl₂O₂ absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl₂O₂ absorption cross-sections.  相似文献   

Short‐term changes in the plan shape of a sandy beach in response to sheltering by a nearshore mud bank,Cayenne, French Guiana     

Edward J. Anthony  Antoine Gardel  Franck Dolique  Daniel Guiral 《地球表面变化过程与地形》2002,27(8):857-866

Montjoly is a headland‐bound embayed sandy beach in Cayenne, French Guiana, that shows long‐term plan shape equilibrium in spite of periodic changes in accretion and erosion that alternately affect either end of the beach. These changes are caused by mud banks that move alongshore from the Amazon. The mechanisms involved in changes in the plan shape of the beach in response to the passage of one of these mud banks were monitored between 1997 and 2000 from airborne video imagery and field work. The beach longshore drift to the northwest, driven by the incident easterly to northeasterly swell usually affecting this coast, became temporarily reversed as the mud bank, migrating from east to west, initially sheltered the southeastern end of the beach. The difference in exposure to waves engendered a negative wave height gradient alongshore towards the southeast, resulting in the setting up of a cell circulation and counter‐active longshore drift from the exposed northwestern sector to the southeast. Sand eroded from the exposed sector accumulated first in the southeastern, and then the central sectors of the beach. The effect of increasing beach sheltering by the mudbank moving west is highlighted on the videographs by an ‘arrested’ pattern of beach shoreline development. The videographs show hardly any changes in beach plan shape since January 1999, due to sheltering of the beach from wave attack by the mud bank. It is expected that the eroded sector will recover in the future as the mud bank passes, leading to re‐establishment of the northwesterly sand drift. This temporally phased bi‐directional drift within the confines of the bounding headlands results in a rare example of mud‐bank‐induced beach rotation, and probably explains the long‐term equilibrium plan shape of Montjoly beach. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献