Mineralogy,chemistry, and grain size composition of recent sediments in the northern Tyrrhenian Sea: Contribution to the study of sediment transport and distribution     

Leonardo Leoni  Franco Sartori  Maurizio Saitta  Vincenzo Damiani  Ornella Ferretti  Monique Viel 《Environmental Geology》1991,17(1):23-46

As a contribution to an environmental study on Tuscany's marine shelf, textural, mineralogical, and chemical characteristics of recent sediments in the northern Tyrrhenian Sea between Elba Island and Livorno have been analyzed. The data provide clear information on sediment sources and movement patterns. The main sediment source appears to be the Cecina River; very subordinate is the contribution of the Fine River. As to sediment movement patterns, the surveyed basin appears to be divided into two subbasins: (1) a greater, southern subbasin, bounded by Tuscany mainland, Elba Island and Elba Ridge, and Capraia Isle, and Vada Shoals; and (2) a smaller, northern subbasin, enclosed between Vada Shoals and Meloria Shoals (off Livorno port).In the former the coarse-grade Cecina River sediments are transported southward along most of the mainland coast by littoral drift and coastal current; a northward flowing countercurrent seems to be active only in the southernmost part. Silts and clays are distributed in concentric belts around basin's central part, being transported mainly by slow circular water movements. In the marginal western zone, very little terrigenous influx is coupled with a high biologic productivity, and biogenic debris sedimentation prevails there.In the northern subbasin the sediment contribution from Fine River is more appreciable. Here the environmental energies are very low and the coarse sediments are restricted to a few small pocket beaches where they are deposited by local creeks. Most of the subbasin area is occupied by sapropelitic muds, again distributed by slow small-scale gyres.  相似文献   

Photoluminescence properties of S<Subscript>2</Subscript> molecule trapped in Melanophlogite     

Fabrizio Messina  Michela Todaro  Gianpiero Buscarino  Lavinia Vaccaro  Marco Cannas  Franco M. Gelardi 《Physics and Chemistry of Minerals》2016,43(3):171-179

We studied the photoluminescence properties of a sample of SiO₂-clathrate Melanophlogite, a crystalline microporous material which is found in nature as a rare mineral. Upon β irradiation, the material displays an intense light emission under near-UV illumination. We studied in detail this optical activity by steady-state and time-resolved photoluminescence measurements as a function of temperature. The spectroscopic properties we find can be ascribed to a population of quasi-free molecules trapped within each of the two different types of cage available in the structure of this clathrate, although the spectroscopic properties of the guest molecules are affected by their interactions with the host matrix. Based on the available data, we attribute the observed photoluminescence to trapped S₂ molecules, emitting from their excited ³Σ _u ^? or ³Π _u electronic states, depending on the cage they are trapped in and on temperature. Our results have an impact on the fundamental understanding of host–guest interactions characteristic of microporous systems such as clathrates. Indeed, the data highlight that even a relatively weak coupling between quasi-free S₂ molecules and the two types of cages provided by the Melanophlogite host has a surprisingly complex influence on the optical properties of the guest.  相似文献   

Facies and Late Triassic fossils in the Roisan zone,Austroalpine Dent Blanche and Mt Mary-Cervino nappe system,NW Alps     

Gloria Ciarapica  Leonsevero Passeri  Franco Bonetto  Giorgio Vittorio Dal Piaz 《Swiss Journal of Geoscience》2016,109(1):69-81

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An analysis of the impact of SST drift in the ECMWF system 3 on simulation of the Indian summer climatology     

Shailendra Rai  Fred Kucharski  Franco Molteni 《Meteorology and Atmospheric Physics》2016,128(5):629-638

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Phosphorus metabolism in anthropogenically transformed lagoon ecosystems: The Comacchio lagoons (Ferrara, Italy)     

Yuri I. Sorokin  Franco Dallocchio  Fernando Gelli  Luciano Pregnolato 《Journal of Sea Research》1996,35(4):243-250

Inorganic phosphorus dynamics were investigated with the use of ³²P in the hypertrophic Comacchio lagoons (NE Adriatic) during an extremely dense, quasi-permanent bloom of picocyanobacteria. Concentrations of dissolved inorganic phosphate (DIP) in waters of the blooming lagoons were usually near the detection limit (0.01 μmoles·dm⁻³). DIP uptake rates by microplankton at near-ambient concentrations (0.01 to 0.1 μmoles·dm⁻³) were in the range of 9.6 to 16.1 nmoles P·dm⁻³·min⁻¹, and turnover times were 1.5 to 3 min. The turnover time was >40 h in the eutrophic coastal waters of the adjacent Adriatic Sea. The uptake rate of DIP depended on its initial concentration. In water samples artificially enriched with DIP, the uptake rate rose to its maximum of 0.10 to 0.13 μmoles P·dm⁻³·min⁻¹ (or 6 to 7 μmoles·dm⁻³·h⁻¹) when the initial concentration of DIP was elevated to 10 to 20 μmoles·dm⁻³. The potential capacity of microplankton in the water samples to consume and retain DIP was estimated at 25 μmoles·dm⁻³. Specific features are discussed of phosphorus metabolism in the anthropogenically transformed lagoon ecosystem with an anomalous food web with few animals.  相似文献   

Tides — fundamentals, analysis and prediction     

A.S. Franco 《Ocean Engineering》1982,9(4):407-408

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Benthic foraminifera of the Holocene transgressive west-central Florida inner shelf: paleoenvironmental implications     

Tessa M. Hill  Gregg R. Brooks  David S. Duncan  Franco S. Medioli   《Marine Geology》2003,200(1-4):263-272

The sedimentology, stratigraphic position, and benthic foraminiferal biostratigraphy of early- to mid-Holocene deposits from the west-central Florida shelf suggest that barrier islands developed along this coast as early as 8.3 ka, in an environment that was more arid than today. Predominant foraminifera of three paralic sedimentary facies deposited between 5.3 and 8.3 ka include miliolids, Elphidium spp., and Ammonia spp., all of which are common in back-barrier environments. Foraminiferal assemblages also suggest that early back-barrier sediments were deposited in a hypersaline environment, similar to that of the arid Laguna Madre of the western Gulf of Mexico. Modern back-barrier foraminifera in the Tampa Bay region are indicative of the humid subtropical climate of today. Thus, the climate of west-central Florida at approximately 8 ka was more arid than today, which is consistent with recent studies showing that climate in the Gulf of Mexico was dryer and cooler during this time period.  相似文献   

On depth and temperature biases in bathythermograph data: Development of a new correction scheme based on analysis of a global ocean database     

Viktor Gouretski  Franco Reseghetti 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(6):812-833

The World Ocean Database 2005 as of May 2009 is used to estimate temperature and sample depth biases of expendable (XBT) and mechanical (MBT) bathythermographs by comparing bathythermograph temperature profiles with more accurate bottle and conductivity/temperature/depth (CTD) data. It is shown that the application of depth corrections estimated earlier from side-by-side XBT/CTD inter-comparisons, without accounting for a pure thermal bias, leads to even larger disagreement with the CTD and bottle reference temperatures. Our calculations give evidence for a depth-variable XBT fall-rate correction with the manufacturer-derived depth being underestimated in the upper 200 m and overestimated below this depth. These results are in agreement with side-by-side inter-comparisons and direct fall-rate estimates. Correcting XBT sample depths by a multiplicative factor which is constant with depth does not allow an effective elimination of the total temperature bias throughout the whole water column. The analysis further suggests a dependence of the fall rate on the water temperature which was reported earlier in the literature. Comparison among different correction schemes implies a significant impact of systematic biases on the estimates of the global ocean heat content anomaly.  相似文献   

A revisitation of TRIX for trophic status assessment in the light of the European Water Framework Directive: application to Italian coastal waters     

Pettine M  Casentini B  Fazi S  Giovanardi F  Pagnotta R 《Marine pollution bulletin》2007,54(9):1413-1426

The trophic status classification of coastal waters at the European scale requires the availability of harmonised indicators and procedures. The composite trophic status index (TRIX) provides useful metrics for the assessment of the trophic status of coastal waters. It was originally developed for Italian coastal waters and then applied in many European seas (Adriatic, Tyrrhenian, Baltic, Black and Northern seas). The TRIX index does not fulfil the classification procedure suggested by the WFD for two reasons: (a) it is based on an absolute trophic scale without any normalization to type-specific reference conditions; (b) it makes an ex ante aggregation of biological (Chl-a) and physico-chemical (oxygen, nutrients) quality elements, instead of an ex post integration of separate evaluations of biological and subsequent chemical quality elements. A revisitation of the TRIX index in the light of the European Water Framework Directive (WFD, 2000/60/EC) and new TRIX derived tools are presented in this paper. A number of Italian coastal sites were grouped into different types based on a thorough analysis of their hydro-morphological conditions, and type-specific reference sites were selected. Unscaled TRIX values (UNTRIX) for reference and impacted sites have been calculated and two alternative UNTRIX-based classification procedures are discussed. The proposed procedures, to be validated on a broader scale, provide users with simple tools that give an integrated view of nutrient enrichment and its effects on algal biomass (Chl-a) and on oxygen levels. This trophic evaluation along with phytoplankton indicator species and algal blooms contribute to the comprehensive assessment of phytoplankton, one of the biological quality elements in coastal waters.  相似文献   

Stability of C₆₀ and C₇₀ fullerenes toward corpuscular and γ radiation     

Franco Cataldo  Giovanni Strazzulla  Susana Iglesias-Groth 《Monthly notices of the Royal Astronomical Society》2009,394(2):615-623

The stability of C₆₀ and C₇₀ fullerenes in the interstellar medium deposited on dust surface or embedded in meteorites and comets has been simulated with γ irradiation and with He⁺ ion bombardment. It is shown by vibrational spectroscopy that a γ radiation dose of 2.6 MGy (1 Gy = 1 joule absorbed energy per kilogram) causes partial oligomerization of both C₆₀ and C₇₀ fullerenes. Oligomers are made by fullerene cages chemically connected each other which can yield back free fullerenes by a thermal treatment. The amount of irreversibly polymerized fullerenes caused by 2.6 MGy as deduced as the toluene insoluble fraction has been determined as 1.7 and 15 per cent by weight, respectively, for C₆₀ and C₇₀ fullerene. The radiation dose generated by radionuclides decay and expected to be delivered to fullerenes buried at a depth of more than 20 m in comets and meteorites is about 3 MGy per 10⁹ yr. Since fullerenes are by far resistant to such radiation dose they can survive for at least some billion years inside comets and meteorites and in fact have been detected inside certain carbonaceous chondrites. On the other hand, the direct exposure of fullerenes to cosmic rays for instance when they are adsorbed or deposited on the surface of carbon dust corresponds to the delivery of a radiation dose comprised between 30 and 65 MGy per 10⁹ yr. Experimental bombardment of both C₆₀ and C₇₀ fullerenes for instance with He⁺ ions has shown that the complete amorphization occurs at about 250 MGy. Thus in ∼4 Gyr exposure to cosmic rays it is expected a complete amorphization.  相似文献