Arsenic mobility in the ambient sulfidic environment: Sorption of arsenic(V) and arsenic(III) onto disordered mackinawite     

Mariëtte Wolthers  Laurent Charlet  Peter R. van der Linde 《Geochimica et cosmochimica acta》2005,69(14):3483-3492

Arsenate, As(V), sorption onto synthetic iron(II) monosulfide, disordered mackinawite (FeS), is fast. As(V) sorption decreases above the point of zero surface charge of FeS and follows the pH-dependent concentration of positively charged surface species. No redox reaction is observed between the As(V) ions and the mineral surface over the time span of the experiments. This observation shows that As(V) dominantly forms an outer-sphere complex at the surface of mackinawite. Arsenite, As(III), sorption is not strongly pH-dependent and can be expressed by a Freundlich isotherm. Sorption is fast, although slower than that of As(V). As(III) also forms an outer-sphere complex at the surface of mackinawite. In agreement with previous spectroscopic studies, complexation at low As(V) and As(III) concentration occurs preferentially at the mono-coordinated sulfide edge sites. The K_d (L g⁻¹) values obtained from linear fits to the isotherm data are ∼9 for As(V) and ∼2 for As(III). Stronger sorption of As(V) than As(III), and thus a higher As(III) mobility, may be reflected in natural anoxic sulfidic waters when disordered mackinawite controls arsenic mobility.  相似文献   

A synoptic decomposition of rainfall over the Cape south coast of South Africa     

Christien J. Engelbrecht  Willem A. Landman  Francois A. Engelbrecht  Johan Malherbe 《Climate Dynamics》2015,44(9-10):2589-2607

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Correction to: Ferric/ferrous ratio in silicate melts: a new model for 1 atm data with special emphasis on the effects of melt composition     

Alexander?BorisovEmail authorView author&#;s OrcID profile  Harald?Behrens  Francois?Holtz 《Contributions to Mineralogy and Petrology》2018,173(12):107

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A field comparison of two methods for the determination of copper complexation: Bacterial bioassay and fixed-potential amperometry     

Janet G. Hering  William G. Sunda  Randolph L. Ferguson  Francois M.M. Morel 《Marine Chemistry》1987,20(4)

Complexation of copper added to seawater was determined by bacterial bioassay and fixedpotential amperometry. Consistent results were obtained by these two fundamentally different methods. The results of this study support the validity of both techniques and the field applicability of fixed-potential amperometry.The intercomparison studies were performed on samples collected at the N.Y.C. sewage sludge dumpsite and in relatively unpolluted coastal waters. In this limited study, the calculated free cupric ion concentrations at ambient total copper concentrations were similar at both sites.  相似文献   

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France     

Philippe Lesage  Pierre Antoine Blum  Marcel Vadell  Jean Francois Fels 《Pure and Applied Geophysics》1983,121(5-6):889-902

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.  相似文献   

Numerical analyses of deformability tests in jointed rock — “Joint Perturbation” and “No Tension” Finite Element solutions     

Francois E. Heuzé  Richard E. Goodman  Ann Bornstein 《Rock Mechanics and Rock Engineering》1971,3(1):13-24

SummaryNumerical Analyses of Deformability Tests in Jointed Rock — Joint Perturbation and No Tension Finite Element Solutions Sound design of structures in or upon rock requires a thorough knowledge of the rock mass deformability. Field test data interpretation has generally relied upon analytical or Finite Element linear elastic solutions. However, when testing in jointed rock, these can no longer be readily used since the medium cannot resist the tension induced upon loading. Accordingly, other solutions are required. If the discontinuities of the rock mass can all be mapped and their surface properties determined, the Finite Element model will use a Joint Perturbation solution where the joint elements have variable stiffnesses to account for movements along the fractures. If the discontinuities cannot be satisfactorily mapped, a global approach is provided by a No Tension analysis of the stress transfer type. The two techniques are compared in the case of bore hole jack deformability tests and found to agree remarkably well, indicating an appreciable difference from results of linear elasticity.

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ZusammenfassungNumerische Analyse von Verformungsversuchen in geklüfteten Fels — Lösungen mittels Kluft-Perturbation und No Tension Analysis auf Grund der Methode der Finiten Elemente Der Entwurf von Bauwerken in oder auf Fels erfordert eine genaue Kenntnis des Formänderungsverhaltens der Felsmasse. Im allgemeinen basiert die Interpretation der Ergebnisse von Feldversuchen auf den Lösungen des zugehörigen Randwertproblems der linearen Elastostatik mittels klassischer analytischer Methoden oder der Methode der Finiten Elemente. Wenn die Versuche aber in geklüftetem Fels durchgeführt werden, müssen die theoretischen Methoden modifiziert werden, da das Medium keine Zugspannungen aufnehmen kann. Zwei Fälle können unterschieden werden. Erstens: die Kluftflächen der Felsmasse können geometrisch erfaßt und ihre Oberflächeneigenschaften können bestimmt werden; in diesem Falle kann die Finite-Elemente-Lösung eine Kluft-Perturbations-Methode verwenden, in welcher spezielle Kluft-Elemente verschiedener Steifigkeiten normal und tangential zu den Kluftflächen die Bewegungen entlang derselben bestimmen. Zweitens: die Diskontinuitäten der Felsmasse können nicht hinreichend beschrieben werden; für diesen Fall ist vorgekehrt durch die Finite-Element-Analyse vom Typ der Spannungsumlagerung unter Ausschaltung der Zugspannungen (No Tension Analysis), um das globale Verhalten der geklüfteten Felsmasse zu erfassen. Die Lösungen dieser beiden Methoden wurden für den Fall der Bohrloch-Verformungs-Tests verglichen; der Vergleich zeigt ausgezeichnete Übereinstimmung, im Gegensatz zu den Lösungen als lineares Elastizitätsproblem.

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RésuméLa méthode des Eléments Finis appliquée aux résultats d'essais de vérins cylindriques dans les roches fissurées — solutions dites Joint Pertubé et Sans Traction La construction de structures sur ou dans des roches nécessite une connaissance approfendie de la déformabilité du massif rocheux. L'analyse des résultats d'essais en place se fait généralement à l'aide de solutions analytiques ou par Eléments Finis, qui supposent une élasticité linéaire du milieu. De fait, dans les roches fissurées, ces solutions sont inadéquates puisque le milieu ne peut résister aux sollicitations de traction. Il s'agit donc d'utiliser d'autres méthodes d'analyse. Lors qu'il est possible de déterminer la géométrie et les propriétés de toutes les discontinuités, l'on pourra utiliser une solution par Eléments Finis, dite Joint Perturbé dans laquelle la rigidité de surface du joint (ou fissure) peut varier lorsque des movements prennent place au niveau du joint. Si cela est impossible, il faudra utiliser une approche globale dite Sans Traction qui redistribue les contraintes de traction et les dissipe. On compare ces deux types de solutions dans le cas des essais de vérins cylindriques unidirectionnels. Leurs résultats sont identiques et ont nettement différents de ceux obtenus avec une solution élastique linéaire.

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Research supported by the National Aeronautics and Space Administration — Contract NAS 8-21432.

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With 8 Figures  相似文献   

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign     

Josef Gochermann  Walter F. Wargau  Claus Tappert  Theodor Schmidt-Kaler  Robert S. Stobie  Fred Marang  Greg Roberts  Francois G. van Wyk  Peter Rucks 《Experimental Astronomy》1999,9(1):1-15

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.  相似文献   

Finite element models for rock fracture mechanics     

Anthony R. Ingraffea  Francois E. Heuze 《国际地质力学数值与分析法杂志》1980,4(1):25-43

A finite element model for the prediction of discrete fracture propagation in rock structures loaded in compression is presented. The model integrates any one of three theories for mixed-mode fracture initiation; it contains an energy balance algorithm for predicting crack increment length, and incorporates recent developments in finite element stress-intensity factor computation. The predictions of the model are compared with the observed fracture response of a real rock structure. Results show that the model accurately predicts both stable and unstable fracture progagations observed experimentally.  相似文献   

Radiation pressure and dust particle dynamics     

Francois Mignard 《Icarus》1982,49(3):347-366

The dynamics of small dust grains orbiting a planet are investigated when solar radiation pressure forces are added to the planet's gravitational central field. In the first part a set of differential equations is derived in a reference frame linked to the solar motion. The complete solution of these equations is given for particles lying in the planet's orbital plane, and we show that the orbital eccentricity may undergo considerable variation. At the same time the pericenter longitude librates or circulates according to initial conditions. With this result we establish a criterion for any orbiting particle (because of its highly eccentric orbit) to collide with its planet's atmosphere. The case of inclined orbit is studied through a numerical integration and allows us to draw conclusions related to the stability of the orbital plane. All solutions are periodic, with the period being independent of the initial conditions. This last point permits us to investigate the different time scales involved in that problem. Finally, the Poynting-Robertson drag is included, along with the radial radiation pressure forces, and the secular trend is considered. A coupling effect between the two components is ascertained, yielding a systematic behavior in the eccentricity and thus in the pericenter distance. Our solutions generalize the results of S. J. Peale (1966, J. Geophys. Res.71, 911–933) and J. A. Burns, P. Lamy, and S. Soter (1979, Icarus40, 1–48) by allowing eccentricities to be large (of order 1) and inclinations to be nonzero and by considering Poynting-Robertson drag.  相似文献   

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献