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41.
42.
The pK1* and pK2* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK1* have been determined from emf measurements for the cell:
Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag
where X is the mole fraction of CO2 in the gas. The values of pK2* have been determined from emf measurements on the cell:
Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag
The results have been fitted to the equations:
lnK*1 = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S0.5 + 0.08468345S − 0.00654208S1
InK*2 = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S0.5 + 0.1130822S − 0.00846934S1.5
where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK1* and σ = 0.0070 in lnK2*.Our new results are in good agreement at S = 35 (±0.002 in pK1*and ±0.005 in pK2*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H2|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.  相似文献   
43.
Two processes are generally explained as causes of temporal changes in the stoichiometric silicon/nitrogen (Si/N) ratios of sinking particles and of nutrient consumption in the surface water during the spring diatom bloom: (1) physiological changes of diatom under the stress of photosynthesis of diatom and (2) differences of regeneration between silicon and nitrogen. We investigated which process plays an important role in these changes using a one-dimensional ecosystem model that explicitly represents diatom and the other non-silicious phytoplankton. The model was applied to station A7 (41°30′ N, 145°30′ E) in the western North Pacific, where diatom regularly blooms in spring. Model simulations show that the Si/N ratios of the flux exported by the sinking particles at 100 m depth and of nutrient consumptions in the upper 100 m surface water have their maxima at the end of the spring diatom bloom, the values and timings of which are significantly different from each other. Analyses of the model results show that the differences of regeneration between silicon and nitrogen mainly cause the temporal changes of the Si/N ratios. On the other hand, the physiological changes of diatoms under stress can hardly cause these temporal changes, because the effect of the change in the diatom's uptake ratio of silicon to nitrogen is cancelled by that in its sinking rate.  相似文献   
44.
Several large deployments of neutrally buoyant floats took place within the Antarctic Intermediate (AAIW), North Atlantic Deep Water (NADW), and the Antarctic Bottom Water (AABW) of the South Atlantic in the 1990s and a number of hydrographic sections were occupied as well. Here we use the spatially and temporally averaged velocities measured by these floats, combined with the hydrographic section data and various estimates of regional current transports from moored current meter arrays, to determine the circulation of the three major subthermocline water masses in a zonal strip across the South Atlantic between the latitudes of 19°S and 30°S. We concentrate on this region because the historical literature suggests that it is where the Deep Western Boundary Current containing NADW bifurcates. In support of this notion, we find that a net of about 5 Sv. of the 15–20 Sv that crosses 19°S does continue zonally eastward at least as far as the Mid-Atlantic Ridge. Once across the ridge it takes a circuit to the north along the ridge flanks before returning to the south in the eastern half of the Angola Basin. The data suggest that the NADW then continues on into the Indian Ocean. This scheme is discussed in the context of distributions of dissolved oxygen, silicate and salinity. In spite of the many float-years of data that were collected in the region a surprising result is that their impact on the computed solutions is quite modest. Although the focus is on the NADW we also discuss the circulation for the AAIW and AABW layers.  相似文献   
45.
With the development of high-resolution multibeam echosounder systems (MBES) for surveying shallow-water areas a new tool is available to monitor rapid changes in seabed morphology as, e.g., caused by the dumping of dredge spoil in coastal waters. In this study, four data sets of repeated bathymetric surveys with a MBES were processed and analyzed. The data were collected in a 1.94-km2 dumping site in the outer Weser Estuary (German Bight). Between June and December 1998, 2.6 million m3 of dredged sediment were deposited there. The bathymetric maps generated in the course of this study reveal features such as subaqueous dunes, scour holes, and mounds of dumped dredge spoil. The mean water depth decreased by about 1 m during the dumping period. Furthermore, difference grids showing changes in sediment volume allowed a calculation of the sediment budget for the monitored area. After a time period of only 5 months, 0.5 million m3 of the originally dumped 2.6 million m3 of dredge spoil had already been removed from the dumping site.  相似文献   
46.
In order to estimate primary production from ocean color satellite data using the Vertical Generalized Production Model (VGPM; Behrenfeld and Falkowski, 1997), we propose a two-phytoplankton community model. This model is based on the two assumptions that changes in chlorophyll concentration result from changes of large-sized phytoplankton abundance, and chlorophyll specific productivity of phytoplankton tends to be inversely proportional to phytoplankton size. Based on the analysis of primary production data, P opt B , which was one parameter in the VGPM, was modeled as a function of sea surface temperature and sea surface chlorophyll concentration. The two-phytoplankton community model incorporated into the VGPM gave good estimates in a relatively high productive area. Size-fractionated primary production was estimated by the two-phytoplankton community model, and P opt B of small-sized phytoplankton was 4.5 times that of large-sized phytoplankton. This result fell into the ranges observed during field studies.  相似文献   
47.
An improved Ewing heat probe frame   总被引:3,自引:0,他引:3  
The standard Ewing heat probe frame has been improved through the design of a new takedown model whose parts are held together by lynch pins. When a 600 lb (272 kg) unit of this type is taken apart, the heaviest single piece of the dismantled unit weighs only 75 lb (34 kg).This makes it feasible for one person to handle, transport, and assemble the new unit. A central, main support member of a heat probe using this frame can be suspended over the side of a research vessel while the heavier temperature recorder and ballast weights are attached by means of the quickaction lynch pins. This makes it possible to use this device on relatively small vessels which are not designed for coring work, having a minimum of free deck space and without launching platforms or hydraulic A-frame booms.  相似文献   
48.
Long-term Sensor Drift Found in Recovered Argo Profiling Floats   总被引:5,自引:0,他引:5  
We recovered three Argo profiling floats after 2 to 2.5 years of operation, and recalibrated their temperature, conductivity, and pressure sensors. The results demonstrate that these floats exhibited a significant drift in salinity of −0.0074 to −0.0125, primarily due to the conductivity sensor drift. Combined with the recalibration result for another previously recovered float, the indication is that the negative salinity drift increases nearly in proportion to the operating period of floats. The increasing rate is −0.0041 (±0.0015) year−1, which yields a salinity drift of −0.016 (±0.006) for the expected float lifetime of four years. The present result suggests that reducing the float surfacing time would improve the accuracy of the salinity measurements.  相似文献   
49.
Frank Rske 《Ocean Modelling》2006,11(3-4):235-297
A global dataset based on the ECMWF Re-Analyses (ERA) is presented that can be used as surface boundary conditions for ocean models with sea-ice components. The definition of these conditions is based on bulk formulae. To study the mean ocean circulation, a mean annual cycle on a daily basis was constructed from ERA for all relevant parameters including wind stress. Continental runoff is considered by using information about the catchment areas of the rivers and about the main drainage basins. The bulk formulae were extended by using sea ice concentration.To estimate meridional heat transports (MHT) and to avoid any drift in ocean model simulations, the heat and fresh water budgets have been closed by applying an inverse procedure to fine-tune the fluxes towards observed transports. To improve the MHTs on the Southern Hemisphere the winds and the short wave radiation at southern higher latitudes should be corrected. Furthermore, tests were performed concerning short wave radiation which was increased in the tropics and decreased in the subsidence zones.The heat and fresh water fluxes are assessed by using a scheme of Macdonald and Wunsch based on hydrographic sections. The net heat fluxes of ERA and of the forcing dataset are consistent with the heat flux divergences and convergences estimated by this scheme except for parts of the South Atlantic and the Indian Ocean sector of the Southern Ocean where none of these datasets is consistent with these estimates. In the subtropical South Indian Ocean the forcing dataset is consistent with these estimates while ERA are not. The flux components of ERA and the forcing dataset were compared to several observational datasets (SRB, SOC, HOAPS, GPCP, and CMAP). For each component, at least one of these datasets (especially HOAPS) supports the effects of the inverse procedure and the bulk formulae almost globally with some regional exceptions: short wave radiation in the tropical oceans and the subtropical North Atlantic, latent heat flux at higher latitudes, and precipitation in the northern North Atlantic.Comparisons to the NCAR/NCEP Re-Analyses (NRA) (versions 1 and 2) and the ECHAM model in place of ERA lead to similar results. In the North Atlantic the net heat fluxes of the model based datasets approach the hydrographic estimate with increasing resolution. Applied to any ocean/sea-ice model and compared to ERA, the forcing dataset would induce only a relative small net sea-surface buoyancy loss.A comparison of the forcing dataset to measurements made using one buoy deployed in the western Pacific warm pool and five buoys deployed in the subduction region of the Northeast Atlantic shows that at the site of the first buoy the net heat fluxes of the forcing dataset are in poorer agreement than those of ERA. At the sites of two subduction buoys both datasets show the same level of agreement within the error bars specified. At the sites of the three remaining subduction buoys the forcing dataset shows a marginal improvement on ERA.  相似文献   
50.
Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r 2 > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.  相似文献   
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