A moderate melting model for the Vøring margin (Norway) based on structural observations and a thermo-kinematical modelling: Implication for the meaning of the lower crustal bodies   总被引：2，自引：1，他引：1  

Laurent Gernigon  Francis Lucazeau  Frederic Brigaud  Jean-Claude Ringenbach  Sverre Planke  Bernard Le Gall 《Tectonophysics》2006,412(3-4):255-278

High P-wave velocities (7.1–7.8 km/s) lower crustal bodies (LCBs) imaged along volcanic margins are commonly interpreted as plume and breakup-related thick mafic underplating. This interpretation is partly challenged in this paper based on new seismic observations and modelling of the outer Vøring Basin (Norway). An exceptional strong amplitude reflection, the T Reflection, is particularly well defined below the North Gjallar Ridge (NGR) between 7and 8 s TWT. The T Reflection is located near the volcanic lava flows emplaced during the NE Atlantic breakup ( 55–54 Ma ago) and coincides with the top of the LCB, forming a mid-crustal dome. Based on structural and temporal relationships, we show that the dome clearly influences the structural development of the NGR and predates the continental breakup at least by 10–15 Ma. Using a thermo-kinematical model, we tried also to investigate and quantify the relationships between the extension, LCB and the magmatic production. Modelling suggests that significant Paleocene–Early Eocene magmatism can be produced without any temperature anomaly in the mantle if differential stretching occurs during the breakup initiation. The conclusion of 2D thermo-kinematical parametric analysis is that the magmatic model predicts, either little extension (β < 2) with no melting or high extension (β > 5) with significant melting along the outer Vøring Basin. We suggest that the continental part of the LCB could not necessarily be breakup-related and so magmatic, as has often been stated previously. It is concluded here that the continental part of the LCB observed beneath the outer Vøring Basin may be partly (or fully) attributed to inherited, high-pressure granulite/eclogite lower crustal rocks. The real amount of mafic material emplaced along the outer Vøring Basin could be 20–40% less than thought.  相似文献   

Ultra-low rare earth element content in accreted ice from sub-glacial Lake Vostok, Antarctica     

Paolo Gabrielli  Frederic Planchon  Carlo Barbante  Claude F. Boutron  Sergey Bulat  Sungmin Hong  Paolo Cescon 《Geochimica et cosmochimica acta》2009,73(20):5959-5974

This paper reports the first rare earth element (REE) concentrations in accreted ice refrozen from sub-glacial Lake Vostok (East Antarctica). REE were determined in various sections of the Vostok ice core in order to geochemically characterize its impurities. Samples were obtained from accreted ice and, for comparison, from the upper glacier ice of atmospheric origin (undisturbed, disturbed and glacial flour ice). REE concentrations ranged between 0.8-56 pg g⁻¹ for Ce and 0.0035-0.24 pg g⁻¹ for Lu in glacier ice, and between <0.1-24 pg g⁻¹ for Ce and <0.0004-0.02 pg g⁻¹ for Lu in accreted ice. Interestingly, the REE concentrations in the upper accreted ice (AC₁; characterized by visible aggregates containing a mixture of very fine terrigenous particles) and in the deeper accreted ice (AC₂; characterized by transparent ice) are lower than those in fresh water and seawater, respectively. We suggest that such ultra-low concentrations are unlikely to be representative of the real REE content in Lake Vostok, but instead may reflect phase exclusion processes occurring at the ice/water interface during refreezing. In particular, the uneven spatial distribution (on the order of a few cm) and the large range of REE concentrations observed in AC₁ are consistent with the occurrence/absence of the aggregates in adjacent ice, and point to the presence of solid-phase concentration/exclusion processes occurring within separate pockets of frazil ice during AC₁ formation. Interestingly, if the LREE enrichment found in AC₁ was not produced by chemical fractionation occurring in Lake Vostok water, this may reflect a contribution of bedrock material, possibly in combination with aeolian dust released into the lake by melting of the glacier ice. Collectively, this valuable information provides new insight into the accreted ice formation processes, the bedrock geology of East Antarctica as well as the water chemistry and circulation of Lake Vostok.  相似文献   

Evaluation of the ECMWF 32-day ensemble predictions during 2009 season of western North Pacific tropical cyclone events on intraseasonal timescales     

Russell L. Elsberry  Mary S. Jordan  Frederic Vitart 《Asia-Pacific Journal of Atmospheric Sciences》2011,47(4):305-318

The performance of the ECMWF 32-day ensemble predictions of western North Pacific tropical cyclone events (formation plus track) made once a week during the 2009 season is evaluated with the same procedures as for the 2008 season. Seventeen of the 23 tropical cyclones during the 2009 season occurred during multiple storm scenarios that are more difficult to predict, and many of the deficient track predictions involved unusual and rapidly changing tracks that typically involve interactions with adjacent synoptic circulations that are not predictable on intraseasonal timescales (10–30 days). Such incorrect predictions of the duration and tracks of these multiple cyclones were found to degrade the performance in predicting subsequent tropical cyclone formations and tracks during the 32-day integration. Predominantly northward tracks throughout the life cycle tended to be less predictable on intraseasonal timescales. Given these caveats, the overall performance of the ECMWF ensemble for the 12 typhoons was more successful than during the 2008 season. However, the performance for three tropical storms during the 2009 season was less successful due to the difficult track forecast scenarios. A surprisingly good performance was found in predicting the formation location and early track segments of eight minimal tropical storms or tropical depressions. The less satisfactory aspect for many of the late season tropical depressions was that the ECMWF ensemble continued to predict member vortices for extended periods after the system had actually dissipated.  相似文献   

Orbital,rotational, and climate interactions     

Jacques Laskar  Frederic Joutel 《Celestial Mechanics and Dynamical Astronomy》1993,57(1-2):293-294

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European projects for innovative GNSS-related applications     

Paolo?MulassanoEmail author  Fabio?Dovis  Frederic?Collomb 《GPS Solutions》2004,7(4):268-270

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Molecular implications of hydrophobic organic partitioning theory     

Russell F. Christman  Frederic K. Pfaender 《洁净——土壤、空气、水》2006,34(4):367-374

Recent normal phase silica followed by reverse phase XAD separation has led to the identification of several flavonoid and condensed tannin structures in Suwannee River Fulvic Acid (SFRA) (Leenheer, J. A., Rostad, C. (2004) Scientific Investigations Report 2004–5276, U.S. Geological Survey). We have used the molecular properties of one of these structures to define ideal behavior during partitioning of PAHs assuming that these structures function as an immiscible liquid solvent bound to finely dispersed mineral particles. Existing data for the partitioning of PAHs into NOM compared well to this ideal behavior under Raoult/Henry and Flory‐Huggins treatments, and activity coefficients of pyrene in the hypothetical NOM phase and the free energy of transfer were estimated. If experimental data on partitioning of PAHs into synthesized samples of these structures is similar to NOM uptake data, it will be attractive to assume that, a) much smaller components of the NOM complex than suggested by gross molecular weight may be important in environmental properties such as solubility enhancement, and b) the effective molar volumes within the NOM complex responsible for solubility enhancement may be solute, or solute class dependent.  相似文献   

Analysis of organic matter by flash pyrolysis-gas chromatography–mass spectrometry in the presence of Na-smectite: When clay minerals lead to identical molecular signature     

Pierre Faure  Laurent Jeanneau  Frederic Lannuzel 《Organic Geochemistry》2006,37(12):1900

Different studies have already pointed out the influence of clays during the analysis of pure organic compounds (especially alkanols, alkanoic acids) as well as macromolecules (humic acids) by flash pyrolysis-gas chromatography–mass spectrometry (PyGC–MS). Especially, the occurrence of clay minerals favors the generation of aromatic units such as alkylbenzenes and polycyclic aromatic hydrocarbons. So as to better identify the nature of the organic compounds which are sensitive to the presence of clays during flash pyrolysis, a humic acid mixed in variable proportions of a Na-homoionic clay was tested. The smectite/humic acid mixtures containing from 10% to 100% humic acid allowed us to identify the progressive disappearance or appearance of specific compounds after PyGC–MS.n-Alk-1-enes disappear when the clay proportion is higher than 67%. For higher contents of Na-smectite, n-alkanes become less and less abundant with a preferential consumption of high molecular weight n-alkanes, whereas the aromatic hydrocarbon proportion increases. Moreover, the distribution of each aromatic hydrocarbon family (alkylbenzenes and alkylnaphthalenes) has been investigated. The pyrogram of pure humic acid exhibits a specific distribution of alkylbenzenes and alkylnaphthalenes reflecting the structure of the organic macromolecule. With the increase in clay proportion, these distributions are modified and lead to other distributions with a preferential predominance of thermally stable isomers.Pyrograms of humic acid and undecanoic acid in the presence of 90% of Na-smectite are similar, especially concerning alkylbenzene and alkylnaphthalene distributions. Therefore, clays (Na-smectite in our experiments) in high proportion modify initial organic products by recombination reactions and lead to the generation of new compounds of very similar distribution, whatever the nature of the initial organic matter. Such results underline the very important catalytic properties of clay minerals on functionalized organic matter during flash pyrolysis.  相似文献   

In-ground environmental radioactivity monitoring in the Culpeper Basin,Virginia, using LiF thermoluminescence dosimeters     

Frederic R. Siegel  Roy C. Lindholm  J. Eduardo Vaz 《Environmental Geology》1982,4(2):67-74

A new environmental in-ground radioactivity monitoring technique using LiF thermoluminescence dosimeters was tested in the Culpeper Basin, Northern Virginia. The dosimeters were buried at a depth of 0.45 m (∼ 18 in.) for approximately four months. There was a significant positive correlation (at the 99.9% confidence level) between the total accumulated radioactivity signal from the dosimeters and the on-site 100 second gamma-ray spectrometer measurements. The minimum-maximum dose rate from the buried thermoluminescence dosimeter measurements was 0.06 to 1.08 mR per day (or 2.5 to 44.5μR per hour). There are two factors which permit better background levels of radioactivity to be established by thermoluminescence dosimeters compared with other methods for environmental monitoring programs. First is the great sensitivity of thermoluminescence dosimeters in terms of minimum dose rate that can be registered (mR per month orμR per hour). Second is the fact that accumulation of radioactivity signal over a long period of time tends to eliminate short-term environmental changes that affect measurements with gamma-ray spectrometers and scintillation counters.  相似文献   

Exploration for Mississippi-Valley type stratabound Zn ores with stream suspensates and stream sediments, Virginia, U.S.A.     

Frederic R. Siegel 《Journal of Geochemical Exploration》1990,38(3)

Suspended and equivalent active sediments were collected from streams at 84 sites at the eastern and western sides of a ridge with stratabound Zn mineralization, Rockingham County, Virginia (USA). The purpose was to evaluate the relative effectiveness of suspended and bottom sediment in the geochemical exploration for Mississippi-Valley type Zn ores. The orebody is composed of sphalerite and minor amounts of galena with some chalcopyrite, strikes parallel to the enclosing dolomite beds at N34°E, and cuts vertically across the 30°SE dip. Oxidation of the ore extends to about 100 m in depth.Zinc was effective in detecting the mineralized zone. Zinc in the suspensates provided a denser anomaly system (7 strong and 2 moderate samples) than Zn in the <150 μm size of the bottom sediment, either totally dissolved (4 strong and 1 moderate anomalies) or extracted with cold 3% HCl (5 strong and 3 moderate anomalies). The magnitude of the high values for suspensate Zn was considerably higher than those for the other sample types studied. Suspensate Zn was complemented by 3 strong suspensate Cu anomalies. The suspensate Zn anomaly dispersion was about 850 m, 400 m of which was upstream from the mineralization. Lead was detected only in the cold acid extraction and in combination with Cu and Zn gave an extensive overlapping multielement anomaly string that targeted the ore zone and had a dispersion downstream from the mineralization of more than 1000 m. The Pb anomalies extended about 900 m upstream and 400 m downstream from the ore zone. Together with suspensate Zn, the Pb anomalies suggest a continuation of mineralization upstrike from the known orebody.The major anomaly systems are along the eastern side of the ridge with comparatively few anomalies present in the drainage along the western side. The concentration of anomalies in the eastern drainage and anomaly disposition with respect to known mineralization result from structural control on the hydromorphic dispersion of metals from the orebody.  相似文献   

Increased concentrations of potassium in heartwood of trees in response to groundwater contamination     

Don A. Vroblesky  Thomas M. Yanosky  Frederic R. Siegel 《Environmental Geology》1992,19(2):71-74

The wood of tuliptrees (Liriodendron tulipifera L.) growing above groundwater contamination from a hazardous-waste landfill in Maryland contained elevated concentrations of potassium (K). The groundwater contamination also contained elevated concentrations of dissolved K, as well as arsenic (As), cadmium (Cd), chloride (Cl), iron (Fe), manganese (Mn), zinc (Zn), and organic solvents. The dissolved K is derived from disposed smoke munitions. The excess K in the tuliptrees is concentrated in the heartwood, the part of the xylem most depleted in K in trees growing outside of the contamination. These data show that the uptake and translocation of K by tuliptrees can be strongly influenced by the availability of K in groundwater contamination and suggest the utility of this species as an areal indicator of groundwater contamination.  相似文献