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41.
Effective moisture and chloride ion diffusivity coefficients for concrete are determined by computational homogenization, where concrete is modeled on the mesoscale as a heterogenous three‐phase composite material. By imposing moisture and chloride ion gradients on a representative volume element, effective macroscale properties are obtained through finite element analysis. A parametric study of the effects of the ballast content was carried out. The numerical results correspond well with an estimate of the Hashin–Shtrikman type available in the literature. The computational homogenization strategy proposed here also includes the interfacial transition zone, and its influence on the effective diffusivity coefficients is assessed. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
42.
The Huygens Probe provided a wealth of data concerning the atmosphere of Titan. It also provided tantalizing evidence of a small amount of surface liquid. We have developed a detailed surface energy balance for the Probe landing site. We find that the daily averaged non-radiative fluxes at the surface are 0.7 W m?2, much larger than the global average value predicted by McKay et al. (1991) of 0.037 W m?2. Considering the moist surface, the methane and ethane detected by the Probe from the surface is consistent with a ternary liquid of ethane, methane, and nitrogen present on the surface with mole fractions of methane, ethane, and nitrogen of 0.44, 0.34, and 0.22, respectively, and a total mass load of ~0.05 kg m?2. If this liquid is included in the surface energy balance, only a small fraction of the non-radiative energy is due to latent heat release (~10?3 W m?2). If the amount of atmospheric ethane is less than 0.6×10?5, the surface liquid is most likely evaporating over timescales of 5 Titan days, and the moist surface is probably a remnant of a recent precipitation event. If the surface liquid mass loading is increased to 0.5 kg m?2, then the liquid lifetime increases to ~56 Titan days. Our modeling results indicate a dew cycle is unlikely, given that even when the diurnal variation of liquid is in equilibrium, the diurnal mass variation is only 3% of the total liquid. If we assume a high atmospheric mixing ratio of ethane (>0.6×10?5), the precipitation of liquid is large (38 cm/Titan year for an ethane mixing ratio of 2×10?5). Such a flux is many orders of magnitude in excess of the photochemical production rate of ethane.  相似文献   
43.
In this paper, Shell’s in-house reservoir simulator MoReS is applied to a recently introduced CO2 sequestration benchmark problem entitled “Estimation of the CO2 Storage Capacity of a Geological Formation” (Class et al. 2008). The principal objective of this benchmark is the simulation of CO2 distribution within a modeling region, and leakage of CO2 outside of it, for a period of 50 years. This study goes beyond the benchmarking exercise to investigate additional factors with direct relevance to CO2 storage capacity estimations: water and gas relative permeabilities, permeability anisotropy, presence of sub-seismic features (conductive fractures, thin shale layers), regional hydrodynamic gradient, CO2-enriched brine convection (due to brine density differences), and injection rates. The effects of hydrodynamic gradients and gravitationally induced convection only become significant over 100 s of years. This study has thus extended simulation time to 1,000 years. It is shown that grid resolution significantly impacts results. Vertical-grid refinement results in larger and thinner CO2 plumes. Lateral-grid refinement delays leakage out of the model domain and reduces injection pressure for a given injection rate. Sub-seismic geological features such as fractures/faults and shale layers are demonstrated to have impact on CO2 sequestration. Fractures located up-dip from the injector may lead to more leakage while the opposite may happen in the presence of fractures perpendicular to the dip. Thin shale layers produce stacked CO2 blankets. They should be explicitly represented instead of being upscaled using a reduced vertical to horizontal permeability ratio. Results are seen to be far more sensitive to gas relative permeability and hysteresis than to variations in the water relative permeability models used. For a multi-injectors project, there is scope to optimize the phasing of injections to avoid potential fracturing near injectors.  相似文献   
44.
Probability density functions for daily precipitation data are used as a validation tool comparing station measurements to seven transient regional climate model runs, with a horizontal resolution of 25 km and driven by the SRES A1B scenario forcing, within the ENSEMBLES project. The validation is performed for the control period 1961–1990 for eight predefined European subregions, and a ninth region enclosing all eight subregions, with different climate characteristics. Models that best match the observations are then used for making climate change projections of precipitation distributions during the twenty-first century for each subregion separately. We find, compared to the control period, a distinct decrease in the contribution to the total precipitation for days with moderate precipitation and a distinct increase for days with more intense precipitation. This change in contribution to the total precipitation is found to amplify with time during all of the twenty-first century with an average rate of 1.1% K?1. Furthermore, the crossover point separating the decreasing from the increasing contributions does not show any significant change with time for any specific subregion. These results are a confirmation and a specification of the results from a previous study using the same station measurements but with a regional climate model ensemble within the PRUDENCE project.  相似文献   
45.
Late glacial palaeoceanography of Hinlopen Strait, northern Svalbard   总被引:3,自引:0,他引:3  
Timing and structure of the Late and post-glacial development of the northern Svalbard margin, together with the initial influx of Atlantic water into the Arctic Ocean are still very poorly constrained. We investigated a sediment core (NP94-51) from a high accumulation area on the continental shelf north of Hinlopen Strait with the purpose of resolving the timing and structure of the last deglaciation. Detailed analyses of ice-rafted detritus, benthic and planktonic foraminiferal fauna, diatom flora, grain size and radiocarbon dates are used to reconstruct the palaeoceanographic evolution of the area. Our results indicate that the disintegration of Hinlopen Strait ice and possibly the northern margin of the Svalbard Ice Sheet commenced between 13.7 and 13.9 14C Ky BP. Influx of subsurface Atlantic waters into the area (12.6 14C Ky BP) and the retreat of the sea ice cover, with the accompanying opening of the surface waters (10.8 14C Ky BP), happened at different times and both much later than the disintegration of the ice sheets. The transition into the Holocene shows a two-step warming.  相似文献   
46.
The rocks of western Ny-Friesland, northern Svalbard, are part of a tectonostratigraphy including four thrust sheets, each composed mainly of orthogneisses overlain by younger metasedimentary rocks. Previous geochronological studies have shown that the orthogneisses are dominated by ca. 1750 Mya granitoids. This study of a quartz-monzonite in one of the thrust sheets, the Nordbreen Nappe, yields a single-zircon U-Pb ion-microprobe age of 2709 Ø 28 My. This is the oldest rock unit so far reported in the Svalbard Caledonides. However, age-determinations on detrital zircons in the metasediments of western Ny-Friesland have shown that Late Archean rocks were prominent sources. The new ages presented here provide the first evidence of a local source for these sedimentary rocks.  相似文献   
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An ensemble of regional climate modelling simulations from the European framework project PRUDENCE are compared across European sub-regions with observed daily precipitation from the European Climate Assessment dataset by characterising precipitation in terms of probability density functions (PDFs). Models that robustly describe the observations for the control period (1961–1990) in given regions as well as across regions are identified, based on the overlap of normalised PDFs, and then validated, using a method based on bootstrapping with replacement. We also compare the difference between the scenario period (2071–2100) and the control period precipitation using all available models. By using a metric quantifying the deviation over the entire PDF, we find a clearly marked increase in the contribution to the total precipitation from the more intensive events and a clearly marked decrease for days with light precipitation in the scenario period. This change is tested to be robust and found in all models and in all sub-regions. We find a detectable increase that scales with increased warming, making the increase in the PDF difference a relative indicator of climate change level. Furthermore, the crossover point separating decreasing from increasing contributions to the normalised precipitation spectrum when climate changes does not show any significant change which is in accordance with expectations assuming a simple analytical fit to the precipitation spectrum.  相似文献   
50.
Cyprinid fish have pharyngeal teeth that mash ingested food. Here we show that roach (Rutilus rutilus L.), a common cyprinid in Swedish boreal lakes, often break the mandibles of ingested Chaoborus larvae into smaller fragments. The presence/absence of roach in historic fish communities could therefore possibly be determined from the proportion of fragmented Chaoborus mandibles in lake sediments, which we assessed using the following three approaches. (1) Roach that were fed Chaoborus larvae in laboratory aquaria evacuated a significantly higher fraction of fragmented prey mandibles than perch (Perca fluviatilis L.). (2) Surface sediments from lakes in an acidified region in southwestern Sweden showed significantly higher proportions of fragmented mandibles for lakes containing roach compared to lakes devoid of cyprinid fish. (3) A paleo-study in Lake Lysevatten, into which roach were introduced in the 1880s and were extirpated in the 1960s, showed significantly higher proportions of fragmented mandibles in sediment layers from the roach period. We conclude that mandible fragmentation was related to roach presence, and propose that the proportion of fragmented Chaoborus mandibles in lake sediments may provide important information when historical cyprinid alterations are of interest, as in paleo-studies on acidification, eutrophication, or fish introductions.  相似文献   
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