Fe-Ni-Co-O-S Phase Relations in Peridotite-Seawater Interactions   总被引：4，自引：0，他引：4  

Klein  Frieder; Bach  Wolfgang 《Journal of Petrology》2009,50(1):37-59

Serpentinization of abyssal peridotites is known to produceextremely reducing conditions as a result of dihydrogen (H₂,aq)release upon oxidation of ferrous iron in primary phases toferric iron in secondary minerals by H₂O. We have compiled andevaluated thermodynamic data for Fe–Ni–Co–O–Sphases and computed phase relations in fO₂,g–fS₂,g andaH₂,aq–aH₂S,aq diagrams for temperatures between 150 and400°C at 50 MPa. We use the relations and compositions ofFe–Ni–Co–O–S phases to trace changesin oxygen and sulfur fugacities during progressive serpentinizationand steatitization of peridotites from the Mid-Atlantic Ridgein the 15°20'N Fracture Zone area (Ocean Drilling ProgramLeg 209). Petrographic observations suggest a systematic changefrom awaruite–magnetite–pentlandite and heazlewoodite–magnetite–pentlanditeassemblages forming in the early stages of serpentinizationto millerite–pyrite–polydymite-dominated assemblagesin steatized rocks. Awaruite is observed in all brucite-bearingpartly serpentinized rocks. Apparently, buffering of silicaactivities to low values by the presence of brucite facilitatesthe formation of large amounts of hydrogen, which leads to theformation of awaruite. Associated with the prominent desulfurizationof pentlandite, sulfide is removed from the rock during theinitial stage of serpentinization. In contrast, steatitizationindicates increased silica activities and that high-sulfur-fugacitysulfides, such as polydymite and pyrite–vaesite solidsolution, form as the reducing capacity of the peridotite isexhausted and H₂ activities drop. Under these conditions, sulfideswill not desulfurize but precipitate and the sulfur contentof the rock increases. The co-evolution of fO₂,g–fS₂,gin the system follows an isopotential of H₂S,aq, indicatingthat H₂S in vent fluids is buffered. In contrast, H₂ in ventfluids is not buffered by Fe–Ni–Co–O–Sphases, which merely monitor the evolution of H₂ activitiesin the fluids in the course of progressive rock alteration.The co-occurrence of pentlandite–awaruite–magnetiteindicates H₂,aq activities in the interacting fluids near thestability limit of water. The presence of a hydrogen gas phasewould add to the catalyzing capacity of awaruite and would facilitatethe abiotic formation of organic compounds. KEY WORDS: serpentinization; ODP Expedition 209; sulfide; oxygen fugacity; sulfur fugacity; hydrothermal system; metasomatism; Mid-Atlantic Ridge  相似文献   

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics     

Jürgen Oberst  Valéry Lainey  Christophe Le Poncin-Lafitte  Veronique Dehant  Pascal Rosenblatt  Stephan Ulamec  Jens Biele  J?rn Spurmann  Ralph Kahle  Volker Klein  Ulrich Schreiber  Anja Schlicht  Nicolas Rambaux  Philippe Laurent  Beno?t Noyelles  Bernard Foulon  Alexander Zakharov  Leonid Gurvits  Denis Uchaev  Scott Murchie  Cheryl Reed  Slava G. Turyshev  Jesus Gil  Mariella Graziano  Konrad Willner  Kai Wickhusen  Andreas Pasewaldt  Marita W?hlisch  Harald Hoffmann 《Experimental Astronomy》2012,34(2):243-271

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   

Subarctic catchment water storage and carbon cycling – Leading the way for future studies using integrated datasets at Pallas,Finland     

Hannu Marttila  Annalea Lohila  Pertti Ala-Aho  Kashif Noor  Jeffrey M. Welker  Danny Croghan  Kaisa Mustonen  Leo-Juhani Meriö  Anna Autio  Filip Muhic  Hannah Bailey  Mika Aurela  Jussi Vuorenmaa  Timo Penttilä  Valtteri Hyöky  Eric Klein  Anton Kuzmin  Pasi Korpelainen  Timo Kumpula  Anssi Rauhala  Bjørn Kløve 《水文研究》2021,35(9):e14350

Subarctic ecohydrological processes are changing rapidly, but detailed and integrated ecohydrological investigations are not as widespread as necessary. We introduce an integrated research catchment site (Pallas) for atmosphere, ecosystems, and ecohydrology studies in subarctic conditions in Finland that can be used for a new set of comparative catchment investigations. The Pallas site provides unique observational data and high-intensity field measurement datasets over long periods. The infrastructure for atmosphere- to landscape-scale research in ecosystem processes in a subarctic landscape has recently been complemented with detailed ecohydrological measurements. We identify three dominant processes in subarctic ecohydrology: (a) strong seasonality drives ecohydrological regimes, (b) limited dynamic storage causes rapid stream response to water inputs (snowmelt and intensive storms), and (c) hydrological state of the system regulates catchment-scale dissolved carbon dynamics and greenhouse (GHG) fluxes. Surface water and groundwater interactions play an important role in regulating catchment-scale carbon balances and ecosystem respiration within subarctic peatlands, particularly their spatial variability in the landscape. Based on our observations from Pallas, we highlight key research gaps in subarctic ecohydrology and propose several ways forward. We also demonstrate that the Pallas catchment meets the need for sustaining and pushing the boundaries of critical long-term integrated ecohydrological research in high-latitude environments.  相似文献   

Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites     

David T. Adamson PhD  PE  Grayson Uhlir BS  Sharon R. Rauch BA  Tessa Klein BS  Anthony S. Danko PhD  PE 《Ground Water Monitoring & Remediation》2021,41(3):29-40

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.  相似文献   

Radio Emission of Flares and Coronal Mass Ejections     

A. Nindos  H. Aurass  K.-L. Klein  G. Trottet 《Solar physics》2008,253(1-2):3-41

We review recent progress on our understanding of radio emission from solar flares and coronal mass ejections (CMEs) with emphasis on those aspects of the subject that help us address questions about energy release and its properties, the configuration of flare?–?CME source regions, coronal shocks, particle acceleration and transport, and the origin of solar energetic particle (SEP) events. Radio emission from electron beams can provide information about the electron acceleration process, the location of injection of electrons in the corona, and the properties of the ambient coronal structures. Mildly relativistic electrons gyrating in the magnetic fields of flaring loops produce radio emission via the gyrosynchrotron mechanism, which provides constraints on the magnetic field and the properties of energetic electrons. CME detection at radio wavelengths tracks the eruption from its early phase and reveals the participation of a multitude of loops of widely differing scale. Both flares and CMEs can ignite shock waves and radio observations offer the most robust tool to study them. The incorporation of radio data into the study of SEP events reveals that a clear-cut distinction between flare-related and CME-related SEP events is difficult to establish.  相似文献   

Early Jurassic basal sauropodomorpha dominated tracks from Guizhou,China: Morphology,ethology, and paleoenvironment     

Lida Xing  Martin G. Lockley  Dongjie Tang  Hendrik Klein  Guangzhao Peng  Yong Ye  Baoqiao Hao 《地学前缘(英文版)》2019,10(1):229-240

The newly discovered large(350 m^2) Yantan dinosaur tracksite, in the Lower Jurassic Ziliujing Formation of Guizhou Province, China, reveals at least 250 footprints of which ~97 can be resolved into trackways of sauropodomorphs. All the trackways are sub parallel likely indicating gregarious behavior. One theropod track(cf. Grallator) was recorded. The sauropodomorph tracks predominantly represent quadrupedal progression(Morphotype A), and footprint morphology is similar to the ichnospecies Liujianpusshunan, characterized by outward pes rotation. Three trackways indicate bipedal progression, and two of these(Morphotype B) indicate inward pes rotation, accompanied by elongate pes digit scratch marks. For the latter phenomenon three possible scenarios are discussed:(1) significant rotation changes accompanying changes in gait,(2) swimming behavior,(3) formation of undertracks.Sedimentological evidence indicates the tracks were made on a linguloid rippled, muddy, immature sandstone substrate characterized by significant differences in substrate consistency across the trackbearing surface. Microbially induced sedimentary structures(MISS) characterized by distinctive wrinkle marks indicate a stressed, probably semi-arid, paleoenvironment that was not conducive to habitation by invertebrate organisms. This is consistent with other evidence that Lower Jurassic sauropodomorph tracks are often associated with semi-arid paleoenvironments.  相似文献   

Morphometric and geological conditions for sediment accumulation in the Udava River,Outer Carpathians,Slovakia     

Dušan Barabas  Ján Bóna  Daniel Klein  Lenka Balážovičová 《地理学报(英文版)》2017,27(8):981-998

The accumulation of sediment in river channels is a phenomenon that is not only influenced by the channel morphology, but also by the physical and geographical characteristics and the endogenous and exogenous processes taking place in the catchment. This paper presents an analysis of the impact the changes in lithological conditions have on the morphological and morphometric parameters of the Udava River channel and their relation to the channel accumulation forms representative of the river’s longitudinal profile as well as of its planform. Results document when accumulation forms occur and what is their spatial distribution within the longitudinal and cross-sectional river profiles. More resistant structures created sections with a lower degree of sedimentation, while in depression segments the degree of sedimentation was higher. With the increase in longitudinal slope, the impact of channel width on the average channel bar size increased. Also a difference in the accumulation was observed between the left and right bank which could be possibly explained by the impact of Coriolis force.  相似文献   

Paleoenvironmental and Human Behavioral Implications of the Boegoeberg 1 Late Pleistocene Hyena Den, Northern Cape Province, South Africa     

Richard G. Klein  Kathryn Cruz-Uribe  David Halkett  Tim Hart  John E. Parkington 《Quaternary Research》1999,52(3):393

Boegoeberg 1 (BOG1) is located on the Atlantic coast of South Africa, 850 km north of Cape Town. The site is a shallow rock shelter in the side of a sand-choked gully that was emptied by diamond miners. Abundant coprolites, chewed bones, and partially digested bones implicate hyenas as the bone accumulators. The location of the site, quantity of bones, and composition of the fauna imply it was a brown hyena nursery den. The abundance of Cape fur seal bones shows that the hyenas had ready access to the coast. Radiocarbon dates place the site before 37,000 ¹⁴C yr ago, while the large average size of the black-backed jackals and the presence of extralimital ungulates imply cool, moist conditions, probably during the early part of the last glaciation (isotope stage 4 or stage 3 before 37,000 ¹⁴C yr ago) or perhaps during one of the cooler phases (isotope substages 5d or 5b) within the last interglaciation. Comparisons of the BOG1 seal bones to those from regional Middle Stone Age (MSA) and Later Stone Age (LSA) archeological sites suggest (1) that hyena and human seal accumulations can be distinguished by a tendency for vertebrae to be much more common in a hyena accumulation and (2) that hyena and LSA accumulations can be distinguished by a tendency for hyena-accumulated seals to represent a much wider range of individual seal ages. Differences in the way hyenas and people dismember, transport, and consume seal carcasses probably explain the contrast in skeletal part representation, while differences in season of occupation explain the contrast in seal age representation. Like modern brown hyenas, the BOG1 hyenas probably occupied the coast year-round, while the LSA people focused their coastal visits on the August–October interval when nine-to-eleven-month-old seals were abundant. The MSA sample from Klasies River Mouth Cave 1 resembles BOG1 in seal age composition, suggesting that unlike LSA people, MSA people obtained seals more or less throughout the year.  相似文献   

Effect of selection and sequencing of representative wave conditions on process-based predictions of equilibrium embayed beach morphology     

Christopher J. Daly  Karin R. Bryan  Mauricio R. Gonzalez  Antonio H. F. Klein  Christian Winter 《Ocean Dynamics》2014,64(6):863-877

In order to decrease the simulation time of morphodynamic models, often-complex wave climates are reduced to a few representative wave conditions (RWC). When applied to embayed beaches, a test of whether a reduced wave climate is representative or not is to see whether it can recreate the observed equilibrium (long-term averaged) bathymetry of the bay. In this study, the wave climate experienced at Milagro Beach, Tarragona, Spain was discretized into ‘average’ and ‘extreme’ RWCs. Process-based morphodynamic simulations were sequenced and merged based on ‘persistent’ and ‘transient’ forcing conditions, the results of which were used to estimate the equilibrium bathymetry of the bay. Results show that the effect of extreme wave events appeared to have less influence on the equilibrium of the bay compared to average conditions of longer overall duration. Additionally, the persistent seasonal variation of the wave climate produces pronounced beach rotation and tends to accumulate sediment at the extremities of the beach, rather than in the central sections. It is, therefore, important to account for directional variability and persistence in the selection and sequencing of representative wave conditions as is it essential for accurately balancing the effects beach rotation events.  相似文献   

Mars reconnaissance lander: Vehicle and mission design     

H.R. Williams  J.C. Bridges  R.M. Ambrosi  M.-C. Perkinson  J. Reed  L. Peacocke  N.P. Bannister  S.D. Howe  R.C. O'Brien  A.C. Klein 《Planetary and Space Science》2011,59(13):1621-1631

There is enormous potential for more mobile planetary surface science. This is especially true in the case of Mars because the ability to cross challenge terrain, access areas of higher elevation, visit diverse geological features and perform long traverses of up to 200 km supports the search for past water and life. Vehicles capable of a ballistic ‘hop’ have been proposed on several occasions, but those proposals using in-situ acquired propellants are the most promising for significant planetary exploration. This paper considers a mission concept termed Mars Reconnaissance Lander using such a vehicle. We describe an approach where planetary science requirements that cannot be met by a conventional rover are used to derive vehicle and mission requirements.The performance of the hopper vehicle was assessed by adding estimates of gravity losses and mission mass constraints to recently developed methods. A baseline vehicle with a scientific payload of 16.5 kg and conservatively estimated sub-system masses is predicted to achieve a flight range of 0.97 km. Using a simple consideration of system reliability, the required cumulative range of 200 km could be achieved with a probability of around 80%. Such a range is sufficient to explore geologically diverse terrains. We therefore plot an illustrative traverse in Hypanis Valles/Xanthe Terra, which encounters crater wall sections, periglacial terrain, aqueous sedimentary deposits and a traverse up an ancient fluvial channel. Such a diversity of sites could not be considered with a conventional rover. The Mars Reconnaissance Lander mission and vehicle presents some very significant engineering challenges, but would represent a valuable complement to rovers, static landers and orbital observations.  相似文献