Non-Energy Resources,Connecticut Coastal Waters,Year 9 and 10 Activities     

Ralph S. Lewis  Mary L. Digiacomo-Cohen  Nancy Friedrich Neff  Richard Hyde 《Marine Georesources & Geotechnology》2013,31(2-3)

The Connecticut effort in year 9 of the Continental Margins Program concentrated on a 13.6-mi2 area south of the Housatonic River. This area was chosen for a side-scan sonar survey because it lies on and adjacent to the bathymetric expressions of two fairly large, subcropping, potential sources of coarse material. Previous seismic work in the area indicated that outcrops or subcrops of these potential source deposits could be delineated using their bathymetric expression. Owing to the limited resolution of the seismic data, a correlation between bottom type and underlying source deposits could not be made with the seismics alone. Results from the November 1993 side-scan survey show that although the source deposits have discernible bathymetric expressions, they are not cropping out as much as expected. As a result, bottom type is not necessarily determined by subcropping deposits in this particular area. Year 10 work was concentrated in Fishers Island Sound, where three areas of potential interest for near-shore gravel resources had previously been identified. These areas were surveyed, during the spring of 1996, using the RoxAnn Seabed Classification System. A small video camera and a Van Veen grab sampler were used to calibrate and verify the RoxAnn data. Although previous sampling had indicated the presence of gravel or gravelly sediment in all of the survey areas, the RoxAnn results showed less gravel than anticipated. Vibrant eelgrass beds and other habitat indicators were detected in all of the survey areas. Given the variable sediment results, and the high habitat potential of the areas surveyed, the likelihood of developing a sand and gravel supply from the near shore of Fishers Island Sound appears quite low.  相似文献   

Year-round variability of ambient noise in temperate freshwater habitats and its implications for fishes     

Sonja Amoser  Friedrich Ladich 《Aquatic Sciences - Research Across Boundaries》2010,72(3):371-378

Changes in habitat acoustics over the year can potentially affect fish hearing and orientation to sound, especially in temperate climates. This is the first study where year-round changes in ambient noise in aquatic habitats were assessed. Seven different European freshwater habitats were chosen for this study. Sound pressure level (SPL) and spectral composition of the ambient noise varied in both quiet stagnant habitats (lakes, backwaters) and in flowing habitats (streams, rivers). Linear equivalent SPL (L_{Leq, 60s}) tended to be lower in stagnant habitats (means: 91.6–111.7 dB) than in flowing habitats (means: 111.2–133.4 dB). The changes in SPL were smallest in the river (means: 4.2–4.4 dB, maxima: 8.5–10.1 dB), whereas significantly higher values were measured in stagnant habitats and the stream (means: 9.9–14.9 dB, maxima: 25.1–30.9 dB). The spectral compositions of the ambient noise determined at different times of the year were highly correlated to each other at the river sites (mean cross-correlation coefficients: 0.85 and 0.94) and were weaker or not correlated at the other study sites (means: 0.24–0.76). The changes in ambient noise spectra were negatively correlated to changes in SPL, indicating that large changes in SPLs were accompanied by large changes in spectral composition and vice versa. Comparison of these eco-acoustical data with a preceding study (Amoser and Ladich in J Exp Biol 208:3533–3542, 2005) indicates that the auditory sensitivity in hearing specialists is affected by changes in ambient noise levels and spectra throughout a year and that this effect tends to be more pronounced in stagnant waters and the stream than at river sites. On the other hand, absolute noise levels result in a higher degree of masking in flowing waters.  相似文献   

Comparison of an Electrochemical and Luminescence‐Based Oxygen Measuring System for Use in the Biodegradability Testing According to Closed Bottle Test (OECD 301D)     

Judith Friedrich  Andreas Längin  Klaus Kümmerer 《洁净——土壤、空气、水》2013,41(3):251-257

The effects of persistent organic pollutants on the aquatic environment still can hardly be assessed. Therefore, ready biodegradability is a desired key characteristic of chemicals. Accordingly, biodegradation testing is of utmost importance and is a vital part within the risk assessment for organic chemicals. In the closed bottle test (CBT; OECD 301D) the degree of biological degradation of a chemical is assessed by monitoring the oxygen consumption so far with a Clark electrode as standard method. However, this method is time‐consuming, laborious and led to frequent fluctuations of the test results, which limited their validity. Due to these shortcomings, an optical system that enables contact‐free measuring of the oxygen concentration in a closed bottle, based on dynamic luminescence quenching, was examined. The test results were compared to those obtained with the “classical” electrochemical technique (Clark electrode). At first, a basic standard for the handling of the new instrument in the laboratory was developed. Then possible influencing factors, reliability, comparability, and reproducibility of the test results were investigated by running the CBTs in parallel with the electrode and optode method. The findings proved the new optode method to be unambiguously superior to the electrode technique. The frequency of fluctuations of the test results and time and effort necessary for the test run could considerably be reduced. The degradation kinetics of the test substances could be followed easily in the CBT by increasing the measuring points without much additional effort.  相似文献   

A Raman spectroscopic study on the structural disorder of monazite–(Ce)     

Katja Ruschel  Lutz Nasdala  Andreas Kronz  John M. Hanchar  Daniel M. T?bbens  Radek ?koda  Friedrich Finger  Andreas M?ller 《Mineralogy and Petrology》2012,105(1-2):41-55

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.  相似文献   

Magmato-sedimentary Carboniferous to Jurassic evolution of the western Tauern window,Eastern Alps (constraints from U-Pb zircon dating and geochemistry)     

Veselá Petra  Söllner Frank  Finger Friedrich  Gerdes Axel 《International Journal of Earth Sciences》2011,100(5):993-1027

New geochronological U-Pb (LA-ICP-MS) zircon data and geochemical analyses from the Variscan orthogneisses and metavolcanic rocks in the western Tauern window are presented and used to reconstruct the pre-Alpine evolution of this area. The late- and post-Variscan stage in the Tauern window was characterised by distinct magmatic pulses accompanied by the formation of volcano-sedimentary basins. The magmatic activity started in the Visean (335.4 ± 1.5 Ma) with the intrusion of a K-rich, durbachitic biotite-granite (protolith of the Ahorn gneiss). Following a period of exhumation and erosion, Westfalian–Stefanian volcanics were deposited (Grierkar meta-rhyodacite: 309.8 ± 1.5 Ma; Venntal meta-rhyolite: 304.0 ± 3.0 Ma). A renewed magmatic pulse occurred in the Early Permian, producing large volumes of tonalites and granodiorites (Tux meta-granodiorite: 292.1 ± 1.9 Ma). The youngest magmatism is characterised by pyroclastic and tuffitic deposits (Pfitsch meta-rhyolite: 280.5 ± 2.6 Ma; Schönach valley meta-andesite: 279.0 ± 4.8 Ma). This volcanism was probably related to crustal extensional faulting within an intra-continental graben and horst setting, asthenospheric upwelling and heat flow increase due to the onset of the Permian rifting. The Permo-Triassic peneplanation and subsidence is documented by shallow marine and evaporitic deposits. Probably in the Middle Jurassic times, the area was flooded and in the Late Jurassic the whole area was covered by limestones, representing post-rift sediments on the southern European continental margin.  相似文献   

Long-term plankton studies at the lower Rhine/Germany     

Günther Friedrich  Marlies Pohlmann 《Limnologica》2009,39(1):14-39

The river Rhine has lain under considerable anthropogenic stress of its water quality for 100 years. As early as 1905 the first results of studies of the plankton in the Rhine were published. Due to the long residence time of the water a real potamoplankton can develop and at the end of the Lower Rhine it reaches its highest density. The paper consists of two parts. At first an overview is given about the history of plankton studies in the Rhine. The second part is the presentation of results from a monitoring at the Lower Rhine from 1979 to 2004.First systematic studies started at the beginning of the 20th century at the beginning of pollution. Our studies started during a phase of recreation from extreme pollution and eutrophication. Samples were taken at four stations: Bad Honnef, km 640, entrance to North Rhine-Westphalia, Düsseldorf, km 732, Duisburg, km 792 downstream large industrial effluents and big cities, Kleve-Bimmen, km 865 at the border to the Netherlands.In the 1970s nutrients were high, especially phosphate 0.65 mg PO₄-P L⁻¹ in 1979. After 1980 phosphate dropped to 0.11 mg PO₄-P L⁻¹ in 2004 (mean values of the growing season). Ammonia was reduced from about 0.52 (1979) to 0.02 (2004) mg NH₄-N L⁻¹. Nitrate remained between 3.72 (1989) and 2.26 (2004) mg NO₃-N L⁻¹ at a relatively high level. Oxygen concentrations were very low during the 1960s and 1970s, sometimes only 4 mg L⁻¹ O₂. During our studies the oxygen increased up to 9 mg L⁻¹ O₂ with a tendency to 11 mg L⁻¹ O₂ in the last years. Chlorophyll a was estimated to be between 59 (1979) and 31μg L⁻¹ (1986) with short peaks up to 170 μg L⁻¹ (1989). Since 1992 the mean values have varied between 30 (1993) and 21 μg L⁻¹ (2004).The floristic phytoplankton composition is characterised by the dominance of the centric diatom Stephanodiscus hantzschii. Other diatoms like Skeletonema subsalsum, Skeletonema potamos and Asterionella formosa were regularly present in smaller quantities. The second dominant group was coccale green algae. During the 1980s they formed up to 35% of the biomass. Since the 1990s their contribution to the phytoplankton became much smaller. This change corresponds with the increase of wastewater treatment and the diminution of nutrients. All the other groups of algae were present in minor quantities. During the time of higher trophy in the 1970s and 1980s the phytoplankton formed two peaks, in recent years only one peak has developed, depending on different flow conditions during the growing season and lower trophic state in the upstream parts of the river.Excellent correspondence exists between cell number, biovolume and chlorophyll a content and the results of delayed fluorescence (DF) measurement. The trophic status in the Lower Rhine may be estimated as (moderate) eutrophic. The ecological status of the phytoplankton is good based on the requirements of the European Water Framework Directive (WFD).The zooplankton consists mainly of rotatoria and larvs of Dreissena polymorpha. Grazing on phytoplankton seems to be mainly due to the large quantities of benthic Dreissena and the newly introduced mussel Corbicula.  相似文献   

Unusual exsolution phenomena in omphacite and partial replacement of phengite by phlogopite + kyanite in an eclogite from the Erzgebirge   总被引：4，自引：0，他引：4  

Esther Schmädicke  Wolfgang Friedrich Müller 《Contributions to Mineralogy and Petrology》2000,139(6):629-642

In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and >29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P > 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes. Received: 4 January 1999 / Accepted: 20 April 2000  相似文献   

昔日全球环境变化的自然磁记录     

M.E.Evans  F.Heller  J.Bloemendal  N.Thouveny 《江苏国土资源》2000,25(5)

沉积物的岩石磁学参量反映了它在海洋及大陆范围内沉积时的古环境及古气候条件.尽管对这种现象的认识还不彻底,但人们对于那些导致磁性增强或减弱的作用已有了很好的了解.这些作用包括可变的陆源物质沉积通量,铁磁性矿物在原地的有机及无机形成,以及这些矿物成岩过程中的分解.至少在过去的700万年间,在大量的沉积记录中观察到了磁性矿物集合体的周期性出现,这些周期性出现涉及到了标准的米兰柯维奇理论的轨道频率,证实了岩石磁学同过去全球变化间的关系.但是,磁信号的定量解译仍然处在幼年期,并且受到了信号形成过程中复杂的相互作用的干扰.  相似文献   

Mikroskopische und mikroanalytische Untersuchungen an metallischen Kügelchen aus Tiefseesedimenten des Zentralen Pazifik     

G. Friedrich  A. Schmitz-Wiechowski 《Marine Geology》1976,20(3):239-250

Metallic spherules from Central Pacific Ocean sediments (“Valdivia” expedition VA 05-1, 1973) were studied by means of the ore microscope and by electron microprobe. The data suggest that most of the spherules are of meteoritic origin, i.e. ablation drops from meteorites as suggested in former studies on spherules from marine environment by Schmidt and Keil (1966), Finkelmann (1970, 1972) and others. The metallic spherules contain up to about 60% Ni, 37% Fe and 3% Co. Unusually high contents of Cr (up to 12%) were noted in some spherules.  相似文献   

Editorial     

Friedrich Seifert 《Physics and Chemistry of Minerals》1985,12(6):315-315

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