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31.
A well crystallized and homogeneous specimen of lizardite from Monte Fico, Elba, Italy, has been studied by Mössbauer and Fourier transform infrared (FTIR) spectrometries. One of the aims was the determination of the oxidation state and the distribution of iron in the structure of this reference sample. Mössbauer data indicate the presence of octahedral ferrous iron, octahedral ferric iron and tetrahedral ferric iron (59.9, 31.3 and 8.8% of total iron, respectively). The existence of only one octahedral site, previously suggested by X-ray structure refinement, is confirmed. The occurrence of tetrahedrally coordinated iron is indicated also by FTIR spectrometry, in particular by the presence of an absorption band at 790 cm–1. Based also on new electron microprobe data, the improved crystal chemical formula for lizardite from Monte Fico is: (Mg2.74Fe2+ 0.10Fe3+ 0.05Al0.11)Σ=3.00 ?· (Si1.94Al0.05Fe3+ 0.01)Σ=2.00O5.05(OH)3.95.  相似文献   
32.
The P-uptake by Myriophyllum spicatum and Cladophora glomerata is investigated in the small phytotron at 5 and 15° in permanent light (11,5 klx) and in permanent darkness. Parallel to this, the gas-metabolism-physiological behaviour is determined by means of IRGA methods. A nutrient solution acc. to. Knop with P from KH2PO4 in the concentrations of 0.01, 0.05 and 0.1 mg/1 P was used as the nutrient medium. Both species take P from the medium till the species – and development – specific pool is filled (6 … 7.5 mg/g P). Towards the end of the period of vegetation one can expect a P-exudation. The P-uptake is temperature-dependent: Cladophora attains the highest P-storage at low temperatures, Myriophyllum, at higher temperatures. Due to their longer phases of growth and lower proneness to traumas, submerse spermatophyta are superior to filamentous algae with respect to the long-time elimination effects.  相似文献   
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The carbon-dioxide assimilation of Fontinalis antipyretica is inhibited by 100 mg/1Zn2+ or Pb2+, without a lethal effect being caused. With increasing time of exposure from one to six days the threshold value of toxicity is lowered and at the same time the net assimilation is reduced within the range of concentration of 0.1 mg/1. In the ecological optimum of the environmental conditions the toxicity is weaker than under other unfavourable environmental conditions at the same time. Therefore, the photoecologically optimum illumination of 1200 lx is an effective bioprotector against phytotoxic lead ion concentrations, so that at 1200 lx also at a comparatively high load a positive photosynthesis balance can be maintained. In the dark, in the first hour after the application of the lead ions dissimilation is a function of concentration, subsequently the respiration differences decrease very much in the range between 0 and 100 mg/1 lead(II)-ions. Stimulating effects could be demonstrated only by 0.01 mg/1 Pb2+ and only for the carbondioxide assimilation.  相似文献   
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The general relativistic model of Cooperstock and Tieu, which attempts to fit rotation curves of spiral galaxies without invoking dark matter, is tested empirically using observations of the Milky Way. In particular, predictions for the mass density in the solar neighbourhood and the vertical density distribution at the position of the Sun are compared with observations. It is shown that the model of Cooperstock and Tieu, which was so constructed that it gives an excellent fit of the observed rotation curve, singularly fails to reproduce the observed local mass density and the vertical density profile of the Milky Way.  相似文献   
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