Ambient air measurements of six bifunctional carbonyls in a suburban area     

Ricardo Ortiz  Hiroyuki Hagino  Kazuhiko Sekiguchi  Qingyue Wang  Kazuhiko Sakamoto   《Atmospheric Research》2006,82(3-4):709

Low-molecular-weight carbonyl compounds, generated by photochemical reactions in the atmosphere and found in the exhaust of motor vehicles, have recently come to the attention of researchers because some of them are suspected carcinogens or mutagens. Six bifunctional carbonyl compounds were detected and measured in a suburban site 30 km northwest of the Tokyo metropolitan area. Samples were taken on five sunny days between 2 August and 11 August 2003 with a low-volume denuder and three-filter tandem system using O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) as a sorbent. Bifunctional carbonyls were measured by gas chromatography–mass spectrometry after two derivatization processes with PFBHA and N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA). The average total (gas plus particle) concentrations were 162.8 ng m^− 3 for pyruvic acid, 113.7 ng m^− 3 for methylglyoxal, 36.0 ng m^− 3 for glycolaldehyde and 58.6 ng m^− 3 for glyoxal.  相似文献   

Influence of ignimbrite on the chemistry of river water in Shirasu plateau,Japan     

Katsuro Anazawa  Hayao Sakamoto  Takashi Tomiyasu 《Hydrogeology Journal》2007,15(2):409-417

River, rain and spring water samples from a region covered in “Shirasu” ignimbrite were collected on Kyushu Island, Japan. The analytical results were subjected to multivariate statistical analysis and stoichiometric calculation to understand the geographical distribution of chemical components in water and to extract geochemical underlying factors. The multivariate statistical analysis showed that the river-water chemistry is only slightly influenced by hot springs or polluted waters, but is highly controlled by weathering of ignimbrite. On the basis of the stoichiometric calculation based on water–rock interaction, the water chemistry was successfully estimated by a simple equation:\({\left[ {{\text{Si}}} \right]}{\text{ = 2}}{\left[ {{\text{Na}}^{{\text{ + }}} } \right]}{\text{ + }}{\left[ {{\text{Mg}}^{{{\text{2 + }}}} } \right]}\) in the upstream area, complemented by \({\left[ {{\text{Si}}} \right]}{\text{ = }}{\left[ {{\text{Na}}^{{\text{ + }}} } \right]}{\text{ - 3}}{\left[ {{\text{K}}^{{\text{ + }}} } \right]}{\text{ + }}{\left[ {{\text{Mg}}^{{{\text{2 + }}}} } \right]}{\text{ - 2}}{\left[ {{\text{Ca}}^{{{\text{2 + }}}} } \right]}\) in the downstream area.  相似文献   

Basin-scale distribution of NH<Subscript>4</Subscript><Superscript>+</Superscript> and NO<Subscript>2</Subscript><Superscript>−</Superscript> in the Pacific Ocean     

Sayaka Yasunaka  Yukihiro Nojiri  Taketo Hashioka  Chisato Yoshikawa  Taketoshi Kodama  Shin-ichiro Nakaoka  Sanae Chiba  Fuminori Hashihama  Masahide Wakita  Ken Furuya  Daisuke Sasano  Akihiko Murata  Hiroshi Uchida  Michio Aoyama 《Journal of Oceanography》2018,74(1):1-11

We used more than 25,000 nutrient samples to elucidate for the first time basin-scale distributions and seasonal changes of surface ammonium (NH₄ ⁺) and nitrite (NO₂ ^?) concentrations in the Pacific Ocean. The highest NH₄ ⁺, NO₂ ^?, and nitrate (NO₃ ^?) concentrations were observed north of 40°N, in the coastal upwelling region off the coast of Mexico, and in the Tasman Sea. NH₄ ⁺ concentrations were elevated during May–October in the western subarctic North Pacific, May–December in the eastern subarctic North Pacific, and June–September in the subtropical South Pacific. NO₂ ^? concentrations were highest in winter in both hemispheres. The seasonal cycle of NH₄ ⁺ was synchronous with NO₂ ^?, NO₃ ^?, and satellite chlorophyll a concentrations in the western subtropical South Pacific, whereas it was synchronous with chlorophyll-a but out of phase with NO₂ ^? and NO₃ ^? in the subarctic regions.  相似文献   

Effects of large-scale wind on the Kuroshio path south of Japan in a 60-year historical OGCM simulation     

Hiroyuki Tsujino  Shiro Nishikawa  Kei Sakamoto  Norihisa Usui  Hideyuki Nakano  Goro Yamanaka 《Climate Dynamics》2013,41(9-10):2287-2318

The effects of large-scale wind forcing on the bimodality of the Kuroshio path south of Japan, the large meander (LM) and non-large meander (NLM), were studied by using a historical simulation (1948–2007) with a high-resolution Ocean general circulation models (OGCM). The Kuroshio in this simulation spent much time in the NLM state, and reproduced several aspects of its long-term path variability for the first time in historical OGCM simulation, presumably because the eddy kinetic energy was kept at a moderate level. By using the simulated fields, the relationships between wind forcing (or Kuroshio transport) and path variation proposed by past studies were tested, and specific roles of eddies in those variations were investigated. The long-term variation of the simulated net Kuroshio transport south of Japan was largely explained by the linear baroclinic Rossby wave adjustment to wind forcing. In the simulated LM events, a triggering meander originated from the interaction of a wind-induced positive sea surface height (SSH) anomaly with the upstream Kuroshio and was enlarged by cyclonic eddies from the recirculation gyre. The cyclonic eddy of the trigger meander was followed by a sizable anticyclonic eddy on the upstream side. Subsequently, a weak (strong) Kuroshio favored the LM (NLM). The LM tended to be maintained when the Kuroshio transport off southern Japan was small, and increasing Kuroshio transport promoted decay of an existing LM. The supply of disturbances from upstream, which is related to the wind-induced SSH variability at low latitudes, contributed to the maintenance of an existing LM.  相似文献   

Impacts of different diffusion scenarios for mitigation technology options and of model representations regarding renewables intermittency on evaluations of CO2 emissions reductions     

Fuminori Sano  Keigo Akimoto  Kenichi Wada 《Climatic change》2014,123(3-4):665-676

This paper evaluated the impacts of climate change mitigation technology options on CO₂ emission reductions and the effects of model representations regarding renewable intermittency on the assessment of reduction by using a world energy systems model. First, different diffusion scenarios for carbon dioxide capture and storage (CCS), nuclear power, and wind power and solar PV are selected from EMF27 scenarios to analyze their impacts on CO₂ emission reductions. These technologies are important for reducing CO₂ intensity of electricity, and the impacts of their diffusion levels on mitigation costs are significant, according to the analyses. Availability of CCS in particular, among the three kinds of technologies, has a large impact on the marginal CO₂ abatement cost. In order to analyze effects of model representations regarding renewables intermittency, four different representations are assumed within the model. A simplistic model representation that does not take into consideration the intermittency of wind power and solar PV evaluates larger contributions of the energy sources than those evaluated by a model representation that takes intermittency into consideration. Appropriate consideration of renewables intermittency within global energy systems models will be important for realistic evaluations of climate change mitigation scenarios.  相似文献   

The Effect of Wet Grinding on the Oxidation of Titanomagnetites   总被引：1，自引：0，他引：1  

N. Sakamoto  P. I. Ince  W. O'Reilly 《Geophysical Journal International》1968,15(5):509-515

  相似文献   

On measuring settlement by magnetic method at any depth     

Keiichiro Taniguchi  Harushige Kusumi  Tateshi Sakamoto  Koichi Kimura 《Marine Georesources & Geotechnology》2013,31(1):81-98

Abstract

When artificial islands are constructed, they are subject to surface subsidence, which is the resultant sum of the consolidation strata, many of which seem differ in character. When these strata are soft and thick, or heavily loaded, it becomes very difficult to estimate how much settlement will eventually take place, and over how long a period. For the estimate to be accurate, the settlement characteristics of each layer must first be determined.

For this purpose, the authors have investigated a new method of measuring settlement, based on two unique principles. One principle is the application of a permanent magnet as an indicator of settlement, and the other is the exploitation of semiconductor, magneto‐resistance elements for detecting the magnetic fields. In advance of the observation, the magnets are forced into the earth, being pushed out through the bore‐hole casing by the oil jack at suitable depths and intervals. The small‐sized magneto‐resistance element is essential to the practicality and efficiency of this method.

In this study, the principles of this method, measuring procedure, the special characteristics and potential of this system, and the results of field trials are described.  相似文献   

Balloon-Borne Hard X-Ray Spectrometer Using CdTe Detectors     

K. Kobayashi  S. Tsuneta  T. Tamura  K. Kumagai  Y. Katsukawa  M. Kubo  Y. Sakamoto  N. Kohara  T. Yamagami  Y. Saito  K. Mori 《Solar physics》2008,250(2):431-441

Spectroscopic observation of solar flares in the hard X-ray energy range, particularly the 20 ∼ 100 keV region, is an invaluable tool for investigating the flare mechanism. This paper describes the design and performance of a balloon-borne hard X-ray spectrometer using CdTe detectors developed for solar flare observation. The instrument is a small balloon payload (gondola weight 70 kg) with sixteen 10×10×0.5 mm CdTe detectors, designed for a 1-day flight at 41 km altitude. It observes in an energy range of 20−120 keV and has an energy resolution of 3 keV at 60 keV. The second flight on 24 May 2002 succeeded in observing a class M1.1 flare.  相似文献   

Distribution of mixotrophic nanoflagellates along the latitudinal transect of the central North Pacific     

Mitsuhide Sato  Takuhei Shiozaki  Fuminori Hashihama 《Journal of Oceanography》2017,73(2):159-168

To elucidate the ecological importance of mixotrophic nanoflagellates in the open ocean and the environmental factors that regulate their abundance, we surveyed latitudinal distributions of autotrophic, mixotrophic and heterotrophic nanoflagellates in the central North Pacific Ocean along a transect at 170°W. Mixotrophic nanoflagellates significantly contributed (26–64 %) to total bacterivory, as measured by the fluorescently-labeled bacteria method, from the equatorial through the subarctic regions, which reinforces the importance of mixotrophic nanoflagellates as a trophic link in the open ocean. The proportion of mixotrophic to total plastidic nanoflagellates was significantly higher in the nutrient-depleted subtropical gyre than in other regions, sometimes exceeding 10 %. Additionally, the proportion was negatively correlated with soluble reactive phosphorus concentration within the tropical and subtropical waters, suggesting that low nutrient availability could facilitate phagotrophy of plastidic nanoflagellates, which may explain the survival of nano-sized eukaryotic phytoplankton in the ultraoligotrophic water. In the subarctic regions, the proportion exhibited no obvious relationship with any environmental parameter. Conversely, the numerical proportion of mixotrophic nanoflagellates in total phagotrophic nanoflagellates (sum of mixotrophic and heterotrophic nanoflagellates) was positively correlated with nutrient concentrations. In contrast to macronutrient availability, the physical stability of the water column did not appear to affect the contribution of mixotrophic nanoflagellates.  相似文献   

Decomposition of kyanite and solubility of Al2O3 in stishovite at high pressure and high temperature conditions     

Xi Liu  Norimasa Nishiyama  Takeshi Sanehira  Toru Inoue  Yuji Higo  Shizue Sakamoto 《Physics and Chemistry of Minerals》2006,33(10):711-721

In order to constrain the high-pressure behavior of kyanite, multi-anvil experiments have been carried out from 15 to 25 GPa, and 1,350 to 2,500°C. Both forward and reversal approaches to phase equilibria were adopted in these experiments. We find that kyanite breaks down to stishovite + corundum at pressures above ∼15 GPa, and stishovite + corundum should be the stable phase assemblage at the pressure–temperature conditions of the transition zone and the uppermost part of the lower mantle of the Earth, in agreement with previous multi-anvil experimental studies and ab initio calculation results, but in disagreement with some of the diamond-anvil cell experimental studies in the literature. The Al₂O₃ solubility in nominally dry stishovite has been tightly bracketed by forward and reversal experiments; it is slightly but consistently reduced by pressure increase. Its response to temperature increase, however, is more complicated: increases at low temperatures, maximizes at around 2,000°C, and perhaps decreases at higher temperatures. Consequently, the Al₂O₃ solubility in dry stishovite at conditions of high temperature–high pressure is very limited.  相似文献