Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain   总被引：1，自引：0，他引：1  

Elena Giménez Forcada  Ignacio Morell Evangelista 《Hydrogeology Journal》2008,16(3):547-557

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.  相似文献   

Water balance in the playa-lakes of an arid environment,Monegros, NE Spain   总被引：1，自引：0，他引：1  

Carmen Castañeda  Miguel Ángel García-Vera 《Hydrogeology Journal》2008,16(1):87-102

The playa-lakes of the Monegros desert in north-east Spain are saline wetlands in an arid environment, a rare phenomenon in Europe. These extremely valuable habitats are threatened by changes associated with agricultural expansion and incorporation of new irrigated areas. An understanding of the present hydrologic regime will enable changes to be identified, particularly those brought about by flooding and pollution caused by irrigation surplus. This study sets out to show the results of applying a daily water balance in three selected playa-lakes. The balance was in two parts and consisted of: (1) the average balance for all the endorheic basin using the BALAN_11 program, and (2) the water balance in some playa-lakes, applying discharge flows obtained from the previous balance. The resulting volumes of water were converted to water depths and contrasted with reference volumes taken from field and Landsat images. The model was calibrated by applying various hypotheses of function which enabled the results to be adjusted. The proposed balance is an acceptable reproduction of field water measurements during this period, and underlines the consistency of the conceptual model. The methodology used is appropriate for understanding the playa-lakes function and for monitoring them for conservation purposes.  相似文献   

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA     

Mark A. Engle  Fraser Goff  David G. Jewett  Gregory J. Reller  Joel B. Bauman 《Hydrogeology Journal》2008,16(3):559-573

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

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Hydrogeology and hydrochemistry of a shallow alluvial aquifer,western Saudi Arabia   总被引：2，自引：0，他引：2  

Abdulaziz M. Al-Shaibani 《Hydrogeology Journal》2008,16(1):155-165

A hydrogeological and hydrochemical study was conducted on a shallow alluvial aquifer, Wadi Wajj, in western Saudi Arabia to assess the influence of protection measures on groundwater quality. The hydrochemistry was assessed up-gradient and down-gradient from potential contamination sources in the main city in dry and wet seasons prior to and after the installation of major drainage and wastewater facilities. Wadi Wajj is an unconfined aquifer where water is stored and transmitted through fractured and weathered bedrock and the overlying alluvial sediments. Natural recharge to the aquifer is about 5% of rainfall-runoff. Hydrochemistry of the aquifer shows temporal and seasonal changes as influenced by protection measures and rainfall runoff. Both groundwater and runoff showed similar chemical signature, which is mostly of chloride-sulfate-bicarbonate and sodium-calcium type. Groundwater downstream of the city, though of poorer quality than upstream, showed significant improvement after the installation of a concrete runoff tunnel and a wastewater treatment plant. Concentrations of many of the groundwater quality indicators (e.g., TDS, coliform bacteria, and nitrate) exceed US Environmental Protection Agency drinking-water standards. Heavy metal content is, however, within allowable limits by local and international standards. The chemical analyses also suggest the strong influence of stream runoff and sewage water on the groundwater quality.

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Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.

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Résumé Une étude hydrogéologique et géochimique a été menée sur l’aquifère phréatique alluviale Wadi Wajj dans l’Ouest de l’Arabie Saoudite afin d’évaluer l’influence de mesures de protection sur la qualité de l’eau souterraine. L’hydrogéochimie de l’eau a été étudiée en amont et en aval de sources potentielles de contamination dans la ville principale, pendant les saisons sèches et humides, avant et après l’installation de réseaux majeurs de drainage et d’eaux usées. L’aquifère Wadi Wajj est libre, l’eau est stockée et s’écoule dans les sédiments alluviaux et dans le socle fracturé et altéré sous-jacent. La recharge naturelle de l’aquifère représente 5% des eaux de pluie et de ruissellement. L’hydrogéochimie de l’eau de l’aquifère montre que les changements saisonniers et temporaires sont influencés par les mesures de protection et par le ruissellement des eaux pluviales. L’eau souterraine et l’eau de ruissellement ont présenté le même faciès chimique, de type bicarbonatée-sulfatée-chlorée et calco-sodique. En aval de la ville, l’eau souterraine, bien que de moins bonne qualité qu’en amont, a présenté une nette amélioration après l’installation d’un système de récupération et d’une station de traitement des eaux usées. Les concentrations de plusieurs paramètres indicateurs de la qualité de l’eau (tels que la charge totale dissoute, les coliformes, et les nitrates) dépassent les normes de potabilité de l’eau de consommation de l’agence américaine de la protection de l’environnement. Les teneurs en métaux lourds en revanche n’excèdent pas les normes locales et internationales. Les analyses chimiques indiquent aussi l’influence importante de l’écoulement par ruissellement et des eaux usées sur la qualité de l’eau souterraine.

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Resumen Un estudio hidrogeológico e hidroquímico fue hecho en un acuífero somero de Wadi Wajj, en Arabia Saudi oeste para evaluar la influecia de medidas de protección en la calidad del agua subterránea. La hidroquímica fue evaluada gradiente-arriba y gradiente-abajo de las fuentes potenciales de contaminación de la ciudad principal durante las estaciones seca y lluviosa, antes y después de la instalación de sistemas principales de drenaje y aguas servidas. Wadi Wajj es un acuífero no-confinado donde el agua es almacenada y transmitida a través de roca fracturada y meteorizada, y los sedimentos aluviales que le sobreyacen. La recarga natural del acuífero es de cerca del 5% de la precipitación-escorrentía. La hidroquímica del acuífero muestra cambios temporales y estacionales influenciados por las medidas de protección y la escorrentía de precipitación. Ambas, agua subterránea y escorrentía mostraron composición química similar, siendo mayoritariamente de tipos cloruro-sulfato-bicarbonato y sodio-calcio. El agua subterránea aguas arriba de la ciudad, aunque de calidad más pobre que aguas abajo, mostró significante mejoría después de la instalación de un tunel de concreto para escorrentía y una planta de tratamiento de aguas servidas. Las concentraciones de muchos de los indicadores de calidad de agua subterránea (e.g., STD, coliformes, y nitrato) exceden los estándares de la Agencia de Protección Ambiental USA para agua potable. El contenido de metales pesados está, sin embargo, dentro de los límites permisibles de los estándares locales e internacionales. Los análisis químicos también sugieren la fuerte influencia de la escorrentía y aguas residuales en la calidad del agua subterránea.

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Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East   总被引：2，自引：0，他引：2  

A. G. Hughes  M. M. Mansour  N. S. Robins 《Hydrogeology Journal》2008,16(5):845-854

Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments.  相似文献   

In situ estimation of the effective chemical diffusion coefficient of a rock matrix in a fractured aquifer     

Robel A. Gebrekristos  Allen M. Shapiro  Brent H. Usher 《Hydrogeology Journal》2008,16(4):629-639

An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10^?6 m²/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment.  相似文献   

Glacio-lacustrine stratigraphy,aquifer characterization and contaminant transport: a case study in South Lake Tahoe,California, USA     

Craig W. Morgan  Graham M. Kent  Gordon G. Seitz  Michaela Novak 《Hydrogeology Journal》2008,16(5):981-994

A hydrogeologic model that has been used by many researchers and consultants to describe an area of South Lake Tahoe, California, USA impacted by MTBE contamination describes a relatively homogeneous unconfined aquifer comprised of poorly sorted glacial outwash deposits, within which water-supply wells are able to exert significant alteration in natural groundwater flow. A re-examination of the area’s hydrogeology is presented, which supports a layered heterogeneous aquifer system constructed of alternating fine and coarser-grained glacio-lacustrine depositional units. This re-evaluation was accomplished through a review of lithologic logs across an area of approximately 1 km², combined with observations of significant hydraulic head differences and knowledge of the depositional environments controlled by Pleistocene Lake Tahoe high stands. Many of the fine-grained units observed at depths from 6 to 15 m, although relatively thin, are generally continuous and serve as significant barriers to groundwater flow. The vertical migration of contamination across these fine-grained units to deeper groundwaters was facilitated by cross-screened monitoring wells installed as part of site investigation activities. This conclusion highlights the importance of geologic characterization and proper monitoring well construction at contaminated site investigations.

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Electronic supplementary material   The online version of this article (doi:) contains supplementary material, which is available to authorized users.

Michaela NovakEmail:

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Uncertainty as the overlap of alternate conditional distributions     

Olena Babak  Clayton V. Deutsch 《Computational Geosciences》2008,12(4):503-512

An important task in modern geostatistics is the assessment and quantification of resource and reserve uncertainty. This uncertainty is valuable support information for many management decisions. Uncertainty at specific locations and uncertainty in the global resource is of interest. There are many different methods to build models of uncertainty, including Kriging, Cokriging, and Inverse Distance. Each method leads to different results. A method is proposed to combine local uncertainties predicted by different models to obtain a combined measure of uncertainty that combines good features of each alternative. The new estimator is the overlap of alternate conditional distributions.  相似文献   

Numerical simulation of migration–accumulation of oil resources     

Yirang Yuan  Yuji Han 《Computational Geosciences》2008,12(2):153-162

Numerical simulation of oil migration and accumulation is to describe the history of oil migration and accumulation in basin evolution. It is of great value to the evaluation of oil resources and to the determination of the location and amount of oil deposits. This thesis discusses the characteristics of petroleum geology and permeation fluid mechanics. For the three-dimensional problems of Dongying hollow of Shengli Petroleum Oil Field, it puts forward a new model and a kind of modified method of upwind finite difference fractional steps implicit interactive scheme. For the famous hydraulic experiment of secondary migration–accumulation, the numerical simulation test has been done, and both the computational and experimental results are basically identical. For the actual problem of Dongying hollow, the numerical simulation test and the actual conditions are basically coincident. Thus, the well-known problem has been solved.  相似文献   

A continuous/discontinuous Galerkin framework for modeling coupled subsurface and surface water flow     

Clint Dawson 《Computational Geosciences》2008,12(4):451-472

We consider conjunctive surface-subsurface flow modeling, where surface water flow is described by the shallow water equations and ground water flow by Richards’ equation for the vadose zone. Coupling between the models is based on the continuity of flux and water pressure. Numerical approximation of the coupled model using the framework of discontinuous Galerkin (DG) methods is formulated. In the subsurface, the local discontinuous Galerkin (LDG) method is used to approximate ground water velocity and hydraulic head; a DG method is also used to approximate surface water velocity and elevation. This approach allows for a weak coupling of the models and the use of different approximating spaces and/or meshes within each regime. A simplified LDG method based on continuous approximations to water head is also described. Numerical results that investigate physical and numerical aspects of surface–subsurface flow modeling are presented. This work was supported by National Science Foundation grant DMS-0411413.  相似文献